Computational methods for fitting statistical distribution models of multi-site binding equilibria

Statistical distribution models of multi-site binding equilibria have potential applicability in the study of acid-base and metal complexation chemistry of humic substances in soils, sediments, and natural waters. A mathematical derivation is presented for the general continuous model for the case of proton binding; computational methods are described for fitting numerically the parameters in such models. Among models considered are those based on nontruncated, truncated, and bimodal (mixed) distributions. Specific emphasis is placed on Gaussian distribution models.     

The importance of energetic particle precipitation on the chemical composition of the middle atmosphere

An assessment is made of the relative contribution of certain classes of energetic particle precipitation to the chemical composition of the middle atmosphere with emphasis placed on the production of odd nitrogen and odd hydrogen species and their subsequent role in the catalytic removal of ozone. Galactic cosmic radiation is an important source of odd nitrogen in the lower stratosphere but since the peak energy deposition occurs below the region where catalytic removal of O₃ is most effective, it is questionable whether this mechanism is important in the overall terrestrial ozone budget. The precipitation of energetic solar protons can periodically produce dramatic enhancement in upper stratospheric NO. The long residence time of NO in this region of the atmosphere, where catalytic interaction with O₃ is also most effective, mandates that this mechanism be included in future modelling of the global distribution of O₃. Throughout the mesosphere the precipitation of energetic electrons from the outer radiation belt (60°70°) can sporadically act as a major local source of odd hydrogen and odd nitrogen leading to observable O₃ depletion. Future satellite studies should be directed at simultaneously measuring the precipitation flux and the concomitant atmosphere modification, and these results should be employed to develop more sophisticated models of this important coupling.     

典型的太阳质子事件峰值流量的一种预报方法

分析了1988~2006年中62个典型的太阳质子事件,发现其归一化后峰值流量变化具有很好的统计规律,根据该规律提出了一种对太阳质子事件峰值流量进行预报的方法.试验预报结果表明,太阳质子事件峰值流量的预报值和实测值都在同一个量级以内,平均相对误差为32％,预报误差在可接受范围内.本文方法对于日常预报业务而言是实用和可行的.     

一种适合定点使用的DTZ型质子旋进磁力仪

系统地介绍了ＤＴＺ系列质子旋进磁力仪的思路和性能特点，通过台站使用认为，ＤＴＺ系列仪器能满足地磁台观测精度的要求，具有实际使用的价值。     

Relationship between global seismicity and solar activities

The relations between sunspot numbers and earthquakes (M≧6), solar 10.7 cm radio flux and earthquakes, solar proton events and earthquakes have been analyzed in this paper. It has been found that: (1) Earthquakes occur frequently around the minimum years of solar activity. Generally, the earthquake activities are relatively less during the peak value years of solar activity, some say, around the period when magnetic polarity in the solar polar regions is reversed. (2) the earthquake frequency in the minimum period of solar activity is closely related to the maximum annual means of sunspot numbers, the maximum annual means of solar 10.7 cm radio flux and solar proton events of a whole solar cycle, and the relation between earthquake and solar proton events is closer than others. (3) As judged by above interrelationship, the period from 1995 to 1997 will be the years while earthquake activities are frequent. In the paper, the simple physical discussion has been carried out. These results supported the exploration and studies of some researchers to a certain extent. This work is supported by Foundation of the Chinese Academy of Sciences (major item).     

Experimental study of the effect of temperature on ion cluster formation using ion mobility spectrometry

Ion mobility spectrometry offers a robust and effective technique to study ion clusters in ambient conditions. Here, we have experimentally studied the influence of temperature on the positive ion cluster formation of 2-propanol vapor in air, along with parallel measurements for n-butyl acetate vapor in air. For both of these low proton affinity compounds in the ppm concentration range, temperatures below 0 °C tend to favor formation of dimers and trimers. The measurements indicate that approximate estimations for the fractions of these n-mers (n > 1) in the ion spectra, can be obtained by classical theory for ion induced nucleation. Presence of natural background vapors however slightly blurs the data, especially for the fraction of monomers, so that accurate prediction of the fractions of n-mers in the spectra would require more accurate information on the gas composition. The findings concerning thermal behavior of ions help to understand better ion phenomena also in field conditions.     

Detection of high-energy solar neutrons and protons by ground level detectors on April 15, 2001

In association with the large solar flare of April 15, 2001, the Chacaltaya neutron monitor observed a 3.6σ enhancement of the counting rate between 13:51 and 14:15 UT. Since the enhancement was observed beginning 11 min before the GLE, solar neutrons must be involved in this enhancement. The integral energy spectrum of solar neutrons can be expressed by a simple power law in energy with the index γ=-3.0±1.0. On the other hand, an integral energy spectrum of solar protons has been obtained in the energy range between 650 MeV and 12 GeV. The spectrum can also be expressed by a power law with the power index γ=-2.75±0.15. The flux of solar protons observed at Chacaltaya (at 12 GeV) was already one order less than the flux of the galactic cosmic rays. It may be the first simultaneous observation of the energy spectra of both high-energy protons and neutrons. Comparing the Yohkoh soft X-ray telescope images with the observed particle time profiles, an interesting picture of the particle acceleration mechanism has been deduced.     

多晶冰蠕变机制的研究进展

与绝大多数材料遵循基于位错攀移的指数蠕变机制不同,多晶冰遵循基于位错滑移的指数蠕变机制,这种机制引起了冰川学家极大的兴趣.以前人的研究为基础,综述了冰中质子无序及质子点缺陷的形成过程,质子点缺陷对位错滑移影响的微观机理,以及多晶冰蠕变的微观机制.研究表明:冰晶体中的氢原子(质子)无序使得位错在滑移过程中形成质子点缺陷(D、L、H₃O⁺和OH^-缺陷),从而降低了位错的滑移速率.质子点缺陷的形成需要氢原子(质子)跃迁,其激活能大于水分子自扩散所需的激活能.同时,多晶冰的蠕变激活能与质子跃迁的激活能相当,而大于水分子自扩散所需的激活能,因此多晶冰的蠕变控制机制是位错滑移,而不是位错攀移.     

Measuring proton energies and fluxes using EIT (SOHO) CCD areas outside the solar disk images

An indirect proton flux measuring tool based on discrimination of the energy deposited by protons in 128 × 128 pixel EIT CCD areas outside the solar disk images is presented. Single pixel intensity events are converted into proton incident energy flux using modeled energy deposition curves for angles of incidence ±60° in four EIT spatial areas with different proton stopping power. The extracted proton flux is corrected for both the loss of one‐pixel events in the range of angles of incidence as well as for the contribution to the single pixel events resulting from scattered middle‐energy protons (low‐energy or high‐energy particles are stopped by the EIT components or pass through them, accordingly). A simple geometrical approach was found and applied to correct for a non‐unique relation between the proton‐associated CCD output signal and the incident proton energy. With this geometrical approximation four unique proton incident energy ranges were determined as 45–49, 145–154, 297–335, and 390–440 MeV. The indirect proton flux measuring tool has been tested by comparing Solar Energetic Particles (SEP) flux temporal profiles extracted from the EIT CCD frames and downloaded from the GOES database for the Bastille Day (BD) of 2000 July 14 and the more recent 2005 January 20 events. The SEP flux temporal profiles and proton spectra extracted from the EIT in the relatively narrow energy ranges between 45 and 440 MeV reported here are consistent with the related GOES profiles. The four additional EIT extracted ranges provide higher energy resolution of the SEP data. (© 2006 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)     

分量质子旋进磁力仪定向方法的研究

根据分量质子旋进磁力仪补偿线圈电流允许误差 ,补偿线圈轴定向应满足的关系式和给出的允许误差 ,研究并给出了实现分量质子旋进磁力仪各定向标准的实用方法。