Pb-Pb age of sedimentary phosphorite reworking in Lower Riphean carbonate sediments,the Satka Formation of Southern Urals

The mineral composition and U-Pb and Rb-Sr systematics of phosphorites from the Satka Formation of Lower Riphean carbonates, the Burzyan Group of Southern Urals, are studied. Phosphorites occurring as small lenses between stromatolite layers are composed largely of fluorapatite with admixture of detrital quartz, feldspars, illite, and chlorite. Phosphorite samples have been subjected to stepwise dissolution in 1 N (fraction L-1) and 2 N (fraction L-2) HCl. As is established, the maximum apatite content is characteristic of fraction L-1, while fraction L-2 is enriched in products of dolomite and sulfide dissolution and in elements leached from siliciclastic components. The Sr content in the Satka apatites (280–560 ppm) is substantially lower as compared with that in unaltered marine apatite. The ⁸⁷Sr/⁸⁶Sr “initial ratio in the phosphorites studied (0.71705–0.72484) and host dolomites from the lower part of the Satka Formation is significantly higher than in the Early Riphean seawater that indicates a reset of the Rb-Sr original systems in sediments. The Pb-Pb age of 1340 ± 30 Ma (MSWD = 6.4) estimated based on 7 data points characterizing fractions L-1 and L-2 is younger than the formation time of overlying Burzyan sediments, being consistent, within the error range, with date of the Mashak rifting event recorded at the Early-Middle Riphean boundary. The comparative U-Pb characteristics of two soluble fractions (L-1 and L-2) and silicate residue of phosphorites show that epigenetic redistribution of Pb and U was characteristic of the phosphorite horizon only. The initial Pb isotope composition and μ (²³⁸U/²⁰⁴Pb) estimated according to model by Stacey and Kramers for the early diagenetic fluids in carbonate and phosphate sediments of the Satka Formation suggest that they were in isotopic equilibrium with erosion products of the Taratash crystalline complex.     

New data on Sr-and C-isotopic chemostratigraphy of the Upper Riphean type section (Southern Urals)

New data on Sr-and C-isotopic systematics of carbonate rocks from the Upper Riphean stratotype (Karatau Group of the southern Urals) are obtained for several southwestern sections of the Bashkirian meganticlinorium, which have not been studied before. The results obtained supplement the Sr-and C-isotopic information for the group upper horizons thus detailing chemostratigraphic characterization of the entire succession. Limestone and dolostone samples used to analyze the Sr isotope composition satisfy strict geochemical criteria of the isotopic system retentivity and have been subjected to preliminary treatment in ammonium acetate to remove secondary carbonate phases. Data on 255 samples of carbonate rocks (171 studied for the first time) show that δ¹³C value varies in the Karatau Group succession from ?2.8 to +5.9 ‰ V-PDB with several in-phase excursions from the general trend in all the sections studied in the area 90 × 130 km. The δ¹³C variation trend demarcates several levels in the carbonate succession of the Karatau Group suitable for objectives of regional stratigraphy and for C-isotope chemostratigraphic subdivision of the Upper Riphean. The results of Sr isotopic analysis of 121 samples (51 unstudied before) from the Karatau Group imply that rocks in its lower part (the Katav Formation and basal horizon of the Inzer Formation) experienced considerable secondary alterations, while limestones and dolostones of the overlying interval of the group are frequently unaltered. In the “best” samples satisfying geochemical criteria of the isotopic system retentivity, the ⁸⁷Sr/⁸⁶Sr initial ratio increases from 0.70521–0.70532 in the lower Inzer deposits to 0.70611 in the upper Min’yar carbonates, decreasing to <0.70600 near the top of the latter. Above the regional hiatus separating the Min’yar and Uk formation, this ratio grows from 0.70533 to 0.70605–0.70609 in the limestone succession of the last formation.     

Tappania-bearing association of the Siberian platform: Biodiversity, stratigraphic position and geochronological constraints

A new fossil microbiota yielding eukaryotic Tappania is described from the Mesoproterozoic Kamo Group of the Central Angara Basin, Siberian Craton. The assemblage also includes Valeria, Satka, Lophosphaeridium, Pulvinosphaeridium, Miroedichia, Osculosphaera, Tasmanites, Obruchevella, Glomovertella, as well as branching and anastomosing filamentous microfossils of putative fungal affinities and peculiar short trichomes, that together substantially increase the biodiversity of the Tappania Association. Stratigraphic position and geochronological constraints indicate a relatively young Late Mesoproterozoic age of the Tappania-bearing sediments. There appears to be a continuity between the Tappania Association and the Neoproterozoic microbiota, the latter being firmly rooted in the Late Mesoproterozoic.     

Mössbauer characteristics,mineralogy and isotopic age (Rb-Sr,K-Ar) of Upper Riphean glauconites from the UK Formation,the southern Urals

Comprehensive mineralogical analysis, Mössbauer spectroscopy and isotopic-geochronological study have been carried out for globular phyllosilicates (GPS) of glauconite group from the Uk Formation, the second one below the top of the Upper Riphean stratotype in the southern Urals. Glauconites have been sampled in the Kurtaza and Kulmas sections remote from each other in the Alatau anticlinorium that corresponds to western facies zone of the Bashkirian meganticlinorium. As is shown, size and density monomineral fractions of globules are represented by Al-glauconite according to established structural formula. The isotopic (Rb-Sr and K-Ar) dating of glauconites from the Uk Formation is performed for the first time along with computer simulation of cation arrangements in their crystal lattice and comparison of the results obtained with data of Mössbauer spectroscopy. It has been assumed by simulation that origin and transformation of the Rb-Sr and K-Ar systems in glauconite are concurrent to stages in structural evolution of this mineral, which have been controlled by geological and geochemical events in the history of sedimentary successions. The approach has been aimed at recognition of stratigraphically meaningful isotopic dates corresponding to the glauconite formation at the stage of the early diagenesis close to sedimentation time and the “rejuvenated” dates characterizing ages of subsequent geological events. The comparison of simulated cation arrangements with data of Mössbauer spectroscopy shows that the Rb-Sr (663 ± 9 Ma) and K-Ar (669 ± 16 Ma) dates established for glauconites correspond to the time of early diagenesis in their host sediments, being suitable for age assessment of the Uk Formation. The dates obtained are of interregional and wider significance, as they must be taken into consideration when constructing the general curve of Sr isotope variations in the Late Riphean oceans.     

用Y／Ho比值指示俄罗斯乌拉尔南部晶质菱镁矿矿床的成因

乌拉尔省南部赋存有两种类型的晶质菱镁矿:1)白云岩地层中的层状矿体;2)白云质灰岩中的透镜状矿体。晶质菱镁矿矿体位于Riphean系列中下层的白云岩中,而在上层的白云岩单元中缺失。这两种类型的菱镁矿可通过矿体形态、晶体大小、石英和白云石含量不同来进行区分。第一种类型的菱镁矿储量巨大,菱镁矿呈粗粒结构,晶体粒径>10mm(最大达150mm);一般来说,矿体与白云岩围岩界限清楚,这种类型矿床以产在Riphean序列下部为特征。第二种类型的菱镁矿由于菱镁矿矿体穿插进入到白云岩围岩中,矿体很不规则,菱镁矿晶体也相对较小(1-5mm),这种类型的矿体主要产在Riphean中部层位中。这两种矿体都显示了交代成因的特征。但这两种菱镁矿矿石在一些主量元素和稀土元素的分布上具有不同的特征:与第二种类型相比,第一种菱镁矿具有较低的FeO,CaO和SiO2含量,与白云岩围岩(La／Lu>1)相比,具La／Lu<1的轻稀土亏损特征。第二种菱镁矿稀土分馏度较低,在稀土分配方面与白云岩围岩有差别。本文还特别讨论了Y／Ho值的重要性,因为该比值在菱镁矿和围岩中的类似性使得划分菱镁矿形成中的热液和成岩交代过程成为可能。因此我们认为,第一种类型菱镁矿,如具有高Y／Ho比值的Satka和Bakal矿床的形成属于沉积盆地发育过程中的早期成岩阶段;第     

New Riphean microbiotas of the Billyakh Group,the north Anabar region (Fomich River basin): To Riphean biostratigraphy of the Siberian platform

Excellently preserved organic-walled and silicified microfossils are first found in the Lower Riphean Ust-Il’ya and Kotuikan formations of the Billyakh Group in the northern slope of the Anabar Uplift (the Fomich River basin). Similar assemblages were previously known only from sections located southward in the Kotuikan River basin, and taxonomic composition of organic-walled microbiotas from the Ust-Il’ya and Kotuikan formations became a corner stone in competitive microphytological models that are based on different approaches. In their composition and general appearance, microbiotas from the Kotuikan and Ust-Il’ya formations in the Fomich River basin are similar to microbiotas reported from the Kotuikan River basin, although northern sections of the above formations characterize deeper sedimentation settings than in localities known before. The Ust-Il’ya and Kotuikan assemblages of organic-walled microfossils include sphaeromorphic Chuaria circularis and Leiosphaeridia, two-layer vesicles the genus Simia, filamentous Plicatidium and Taenitrichoides, and some others. The silicified microbiota from the lower Kotuikan Subformation is largely composed of akinetes of Anabaena-like cyanobacteria Archaeoellipsoides, spherical Myxococcoides grandis, and short trichomes Filiconstrictosus and Orculiphycus representing initial germination stages of Anabaena-like cyanobacterial spores. Acanthomorphic acritarchs known from lithology-similar Lower and Middle Riphean (Mesoproterozoic) formations of Australia and China have not been observed in the Ust-Il’ya and Kotuikan microbiotas, which are probably of older age. The found microbiotas outline substantially wider distribution area of organic-walled and silicified microfossils, supplement microphytological characteristics of Riphean sediments in the Anabar Uplift, provide information on taxonomic composition of microbiotas from a wider spectrum of facies, and specify relationships between Early and Middle Riphean assemblages of microorganisms from different continents.     

New paleomagnetic data on the Anabar Uplift and the Uchur-Maya region and their implications for the paleogeography and geological correlation of the Riphean of the Siberian Platform

The results of paleomagnetic studies of the reference sections of the Riphean and Late Proterozoic intrusive bodies of two remote areas of the Siberian Platform are presented. Within the limits of the Uchur-Maya region the sedimentary rocks of the Gonam, Omakhta, Ennin and Konder formations were studied; and the Riphean sedimentary rocks of the Burdur and Kotuykan formations on the northern and western slopes of the Anabar Uplift and, also, the Late Proterozoic intrusive complexes, located in the basins of the Fomich, Magan, Dzhogdzho and Kotuykan Rivers were studied. The paleomagnetic poles obtained in the course of this work and the present-day geochronological data give grounds to assume that: (1) the accumulation of the Riphean of the Anabar Uplift occurred after the formation of the Uchurskaya series of the Uchur-Maya region and was completed in approximately 1.5 Ga; (2) the Konder layers, compared according to the correlation pattern accepted at the present time [Semikhatov and Serebryakov, 1983] with the bottoms of the Totta formation, can be related to the appreciably more ancient stratigraphic level; (3) the intrusion of the studied intrusive bodies of the northern and western slopes of the Anabar Uplift occurred nonsimultaneously, although within close time intervals of approximately 1.5 Ga. The estimates of the kinematic parameters of the drift of the Siberian Platform within an interval of 1.7–1.0 Ga is carried out.     

Neoproterozoic microfossils from the margin of the East European Platform and the search for a biostratigraphic model of lower Ediacaran rocks

A ca. 600 m thick siliciclastic succession in northern Russia contains abundant and diverse microfossils that document early to middle Ediacaran deposition along the northeastern margin of the East European Platform. The Vychegda Formation is poorly exposed but is well documented by a core drilled in the Timan trough region (Kel’tminskaya-1 borehole). Vychegda siliciclastics lie unconformably above Tonian to lower Cryogenian strata and below equivalents of the late Ediacaran Redkino succession that is widely distributed across the platform. The basal 10 m of the formation preserve acritarchs and fragments of problematic macrofossils known elsewhere only from pre-Sturtian successions. In contrast, the upper, nearly 400 m of the succession contains abundant and diverse large acanthomorphic acritarchs attributable to the Ediacaran Complex Acanthomorph Palynoflora (ECAP). This distinctive set of taxa is known elsewhere only from lower, but not lowermost, Ediacaran rocks. In between lies an additional assemblage of relatively simple filaments and stratigraphically long ranging sphaeromorphic acritarchs interpreted as early Ediacaran in age. Bearing in mind that knowledge of late Cryogenian (post-Strurtian/pre-Marinoan) microfossils is sparse, the Vychegda record is consistent with data from Australia and China which suggest that diverse ECAP microfossil assemblages appeared well into the Ediacaran Period. Accumulating paleontological observations underscore both the promise and challenges for the biostratigraphic characterization of the early Ediacaran Period.