A community-wide intercomparison exercise for the determination of dissolved iron in seawater

The first large-scale international intercomparison of analytical methods for the determination of dissolved iron in seawater was carried out between October 2000 and December 2002. The exercise was conducted as a rigorously “blind” comparison of 7 analytical techniques by 24 international laboratories. The comparison was based on a large volume (700 L), filtered surface seawater sample collected from the South Atlantic Ocean (the “IRONAGES” sample), which was acidified, mixed and bottled at sea. Two 1-L sample bottles were sent to each participant. Integrity and blindness were achieved by having the experiment designed and carried out by a small team, and overseen by an independent data manager. Storage, homogeneity and time-series stability experiments conducted over 2.5 years showed that inter-bottle variability of the IRONAGES sample was good (< 7%), although there was a decrease in iron concentration in the bottles over time (0.8–0.5 nM) before a stable value was observed. This raises questions over the suitability of sample acidification and storage.     

努力提高三维地震勘探精度，为西部煤炭工业做出新贡献

以国家重大产业技术开发专项“西部煤炭资源高精度三维地震勘探技术”项目的由来、意义和总体研究目标为引,概括的介绍了项目依托工程中各个专项技术研究完成情况,并对非均匀介质成像技术、高精度三维地震静校正技术、高密度采集技术、特观技术、岩性反演技术、属性体解释技术等六项重大关键技术取得的突破性进展进行了重点说明。指出随着我国煤炭生产重点的逐步西移,应加强诸如叠前、叠后深度偏移技术的研究,以解决复杂山区三维地震面元内地震反射波散射问题,提高其三维地震勘探精度,为西部煤炭工业做出新贡献!     

三维地震小面元采集技术在晋城矿区的应用

依托“西部煤炭资源高精度三维地震勘探技术”工程,对晋城矿区进行了旨在提高小断层,小陷落柱探测能力的高密度三维地震勘探。根据面元选择因素及该区地质任务,采用5m×5m网格进行野外数据采集;考虑炮检距、方位角、覆盖次数、排列片横纵比及煤层埋深（350～500m）等因素,采用中点放炮、60道接收,24次覆盖（横向4次,纵向6次）的8线16炮束状观测系统,基岩中激发。原始资料经同一处理流程后,获得5m×5m×1ms、5m×10m×1ms、10m×10m×1ms及2.5m×2.5m×1ms不同单元的三维数据体多个,通过对比可以发现小断层,小陷落柱在其小面元叠加时间剖面、顺层切片及相干切片都有清晰的反映。实例说明,小面元采集技术可以提高对小构造的纵、横向分辨能力,满足山区对三维地震精确勘探的要求。     

Semi-analytical solutions of a contaminant transport equation with nonlinear sorption in 1D

A new method to determine semi-analytical solutions of one-dimensional contaminant transport problem with nonlinear sorption is described. This method is based on operator splitting approach where the convective transport is solved exactly and the diffusive transport by finite volume method. The exact solutions for all sorption isotherms of Freundlich and Langmuir type are presented for the case of piecewise constant initial profile and zero diffusion. Very precise numerical results for transport with small diffusion can be obtained even for larger time steps (e.g., when the Courant-Friedrichs-Lewy (CFL) condition failed).     

离散裂隙渗流方法与裂隙化渗透介质建模

流体渗流模拟的连续介质方法通常适用于多孔地质体，并不一定适用于裂隙岩体，由于裂隙分布及其特征与孔隙差异较大。若流体渗流主要受裂隙的控制，对于一定尺寸的裂隙岩体，多孔介质假设则较难刻划裂隙岩体的渗流特征。离散裂隙渗流方法不但可直接用于模拟裂隙岩体非均质性和各向异性等渗流特征，而且可用其确定所研究的裂隙岩体典型单元体及其水力传导（渗透）张量大小。主要讨论了以下问题：（1）饱和裂隙介质中一般的离散流体渗流模拟；（2）裂隙岩体中的REV（典型单元体）及其水力传导（渗透）张量的确定；（3）利用离散裂隙网络流体渗流模型研究裂隙方向几何参数对水力传导系数和REV的影响；（4）在二维和三维离散裂隙流体渗流模型中对区域大裂隙和局部小裂隙的处理方法。调查结果显示离散裂隙流体渗流数学模型可用来评价不同尺度上的裂隙岩体的水力特征，以及裂隙方向对裂隙化岩体的水力特征有着不可忽视的影响。同时，局部小裂隙、区域大裂隙应当区别对待，以便据其所起的作用及水力特征，建立裂隙化岩体相应的流体渗流模型。     

Size Scaling of Cross Correlation Between Multiple Variables

Reservoir models have large uncertainty because of spatial variability and limited sample data. The ultimate aim is to use simultaneously all available data sources to reduce uncertainty and provide reliable reservoir models for resource assessment and flow simulation. Seismic impedance or some other attribute provides a key source of data for reservoir modeling. These seismic data are at a coarser scale than the hard well data and it not an exact measurement of facies proportions or porosity. A requirement for data integration is the cross-covariance between the well and seismic data.The size-scaling behavior of the cross correlation for different measurement scales was nvestigated. The size-scaling relationship is derived theoretically and validated by numerical studies (including an example with real data). The limit properties of the cross-correlation coefficient when the averaging volume becomes large is shown. After some averaging volume, the volume-dependent cross-correlation coefficient reaches a limit value. This plateau value is controlled mainly by the large-scale behavior of the cross and direct variograms.The cross correlation can increase or decrease with volume support depending on the relative importance of long- and short-scale covariance structures. If the direct and cross variograms are proportional, there is no change in the cross correlation as the averaging volume changes. Our study shows that the volume-dependent cross-correlation coefficient is sensitive to the shape of the cross variogram and differences between the direct variograms of the well data and seismic data.     

流体地质作用的构造效应

许多事实证明，在地壳及地球深部存在着大量的流体，它们以气体、液体、熔融体等形式存在于地球内部不同深度处。这些流体的活动在地壳及岩石圈运动演化过程中扮演着十分重要的角色，其作用贯穿于地壳与岩石圈运动演化的全过程，地球表面形成的各种构造与流体作用的参与有着密切的联系。     

Influence of gas production induced volumetric strain on permeability of coal

Summary The gas permeability of a coalbed, unlike that of conventional gas reservoirs, is influenced during gas production not only by the simultaneous changes in effective stress and gas slippage, but also by the volumetric strain of the coal matrix that is associated with gas desorption. A technique for conducting laboratory experiments to separate these effects and estimate their individual contribution is presented in this paper. The results show that for a pressure decrease from 6.2 to 0.7 MPa, the total permeability of the coal sample increased by more than 17 times. A factor of 12 is due to the volumetric strain effect, and a factor of 5 due to the gas slippage effect. Changes in permeability and porosity with gas depletion were also estimated using the measured volumetric strain and the matchstick reservoir model geometry for flow of gas in coalbeds. The resulting variations were compared with results obtained experimentally. Furthermore, the results show that when gas pressure is above 1.7 MPa, the effect of volumetric strain due to matrix shrinkage dominates. As gas pressure falls below 1.7 MPa, both the gas slippage and matrix shrinkage effects play important roles in influencing the permeability. Finally, the change in permeability associated with matrix shrinkage was found to be linearly proportional to the volumetric strain. Since volumetric strain is linearly proportional to the amount of gas desorbed, the change in permeability is a linear function of the amount of desorbing gas.     

Estimating coefficients of volume compressibility from compression of strata and piezometric changes in a multiaquifer system in west Taiwan

This paper estimates the coefficients of volume compressibility from variation in compressible layer thickness and changes in piezometric heads by using detail ground surface surveys and a multilayer monitoring well at a selected site (Shigang) within the Choshui River alluvial fan in west Taiwan. The paper integrates various types of in situ monitoring tools, including leveling surveys, continuous global position system (GPS) stations, multilevel layer compression and groundwater pressure head-monitoring wells, to investigate the situation and progress of the subsidence problem in the region. The results from the cross-analyses of the measured data show that surface settlement caused by the compression of strata is between the depths of 60 and 210 m where the clayey stratum within 120-180 m was most pronounced and contributes up to 53% of the total compression. The results indicate that the clayey stratum is under normal consolidation. The results also reflect the fact that 20% of settlement contribution comes from the sandy stratum within 90-120 m; the elasto-plastic behavior of this sandy stratum is clear. The coefficients of volume compressibility of the clayey and sandy stratum analysed from the stratum's compression records; they were 6.38×10⁻⁸ and 5.71×10⁻⁹ m²/N, respectively. Ultimately, this parameter estimation would permit to control and predict land subsidence based on change in pressure head which are related to groundwater extraction.     

A Finite Volume Scheme for the Transport of Radionucleides in Porous Media

The COUPLEX1 Test case (Bourgeat et al., 2003) is devoted to the comparison of numerical schemes on a convection–diffusion–reaction problem. We first show that the results of the simulation can be mainly predicted by a simple analysis of the data. A finite volume scheme, with three different treatments of the convective term, is then shown to deliver accurate and stable results under a low computational cost.