Modelling of meteorological conditions at an urban scale for the PUMA winter campaign

For the winter 2000 campaign of the Pollution of Urban Midlands Atmosphere project, observation and numerical modelling of meteorological conditions over the West Midlands conurbation, UK, was undertaken. Modelling was performed using the regional atmospheric meteorological system (RAMS). This paper presents a comparison of modelled and observed wind and temperature for 25 and 26 January 2000. The RAMS model uses two nested grids with a mesh size of 2 km for the inner grid which is embedded in the outer grid with a mesh size of 8 km. Statistical evaluation of the model results against the observational data of wind speed, direction and temperature at 10 m was conducted. In general, the modelling results are in a reasonable agreement with observation. The statistical evaluation suggests that model performance is poorer for the inner grid than the outer grid as the model uncertainties (mainly mean bias) transfer from the outer to inner one. The low indices of agreement of temperature and wind are mainly associated with the systematic root-mean-square-difference values. For temperature, the systematic bias may also be affected by representation of cloud amount by the model. For wind, the model tends to have a poor performance for calm conditions, as under a stable anti-cyclonic situation local wind patterns associated with topography may develop, although the topography of the region is relatively flat. The results for the inner grid reveal some subtle spatial patterns at a scale smaller than 10 km near hills and valleys with differences in elevation of a few hundred metres.     

Development and testing of numerical methods for two-way nested air pollution modelling

A new 3-D model REGINA (REGIonal high resolutioN Air pollution model) is under development at the National Environmental Research Institute (NERI). The model is based on pieces from several models developed over the last decades at NERI. The aim of the work is to develop a nested model which can operate with very high resolution in both space and time. To fulfill this aim the choice and implementation of accurate numerical methods is crucial. The model will be applied for studying air pollution phenomena (both monitoring, forecasting and scenarios) over Denmark. The present paper is focussed on the modification, implementation and testing of a numerical method for treating the horizontal advection in the model as well as the implementation of two-way nesting techniques. The horizontal transport in the model is solved using an accurate space derivative algorithm. This method is traditionally implemented with periodic boundary conditions, however, this is not an option for nested modelling. A new method for calculating non-periodic boundary conditions has been developed in order to overcome this problem. Extensive testing of the numerical solution of the advection and the coupling of the solution of advection and chemistry in the model using Molenkamp–Crowley rotation tests have been carried out. The results show that the model with the current implementation of numerical methods is suitable for calculating air pollution levels with high resolution.     

塔里木盆地晚泥盆世及石炭纪岩相古地理

塔里木盆地上泥盆统及石炭系包括5个组，自下而上分别为上泥盆统东河塘组和甘木里克组，石炭系巴楚组、卡拉沙依组和小海子组。其中东河塘组和甘木里克组地质时代为晚泥盆世，巴楚组地质时代为早石炭世杜内早中期，卡拉沙依组地质时代为晚杜内中期至巴什基尔期，小海子组地层时代为巴什基尔末期至莫斯科早期。岩石类型有碎屑岩和碳酸盐岩，还有膏盐岩，并夹薄层火山碎屑岩。沉积相主要为海陆过渡相组合，包括河流、三角洲、滨岸、浅海、碳酸盐岩台地、台地边缘6种相和12种亚相及33种微相。晚泥盆世东河塘期至石炭纪发生过4次较大的海侵，海侵范围由下而上逐渐增大，至晚石炭世小海子期海侵规模最大。东河塘期开始海侵，海水由西而东侵入，此时周缘碎屑物质供应充分，主要为无障壁海岸和障壁海岸沉积，西南缘为浅海相沉积。巴楚期晚期，海侵范围进一步扩大，物源向北或北东方向退却，陆源碎屑物质注入急剧减少，形成了一套富含生屑的碳酸盐岩地层，发育了开阔台地和局限台地亚相沉积。卡拉沙依期中期海侵规模比巴楚期更大，海水深度加大，西部为开阔台地亚相沉积，其余地区为局限台地亚相沉积。卡拉沙依期晚期和小海子期海侵达最大，向东扩展，大部分地区为开阔台地亚相沉积，东部地区为局限台地亚相沉积，塔北大部分地区缺失。     

株州市土壤重金属污染的对应分析

株州市土壤重金属污染的主要原因是工厂排放有害气体，或是水体污染物随灌溉进入土壤。采用对应分析方法，将市区土壤重金属污染分析３种类型。靠近人业污染源附近，镉的含量及污染指数高；大部分土壤受多种重金属污染；水稻土主要表现为铅的污染。     

在CTMAB存在下应用苯基萤光酮分光光度法测定岩矿中微量锡

本文研究了在ＣＴＭＡＢ存在下，应用苯基萤光酮分光光度法测定微量锡的条件。该法灵敏度高，操作简便，可用于测定岩矿样品中的微量锡。     

柱撑蛭石吸附去除废水中重金属离子的实验研究

分别利用有机柱化剂十二烷基磺酸钠(SDS)和无机柱化剂聚羟基铝(HA)对蛭石进行柱撑制得十二烷基磺酸钠柱撑蛭石(SDS-V erm icu lite)和聚羟基铝柱撑蛭石(HA-V erm icu lite),并通过XRD、红外光谱、ZETA电位等表征手段对柱撑蛭石进行表征,同时针对柱撑蛭石对Cu2 ,Cd2 ,C r3 3种重金属离子的吸附进行研究,结果表明:吸附去除率受反应时间、重金属离子的初始浓度、pH值等因素的影响,经柱撑后的蛭石对重金属离子吸附的吸附性能比蛭石原矿要强。柱撑蛭石吸附3种重金属离子的动力学吸附过程可用E lov icb方程和双常数方程进行较好的拟合。     

Chlorinated hydrocarbons in gulls from the Baltic south coast

Polychlorinated terphenyls among organochlorine pesticides and polychlorinated biphenyls were detected in some gulls from the Gdańsk Bay, Baltic Sea.