体绘制技术在地学3D GIS 可视化中的应用研究

体绘制技术是目前科学计算可视化研究的一个重要组成部分，对地质体内部属性分布的可视化有重要意义。该文针对地学研究中几何建模和属性建模同样重要的特点，基于一种矢栅一体化的混合数据模型，对地质体表面采用三角面片描述几何形状，对地质体内部采用基于八叉树的自适应网格剖分技术描述内部属性特征。对网格剖分后的体数据，采用体元投射的体绘制技术进行地质体内部属性可视化，显示出很好的效果，具有实际应用意义。     

新版建筑工程建筑面积计算规范应用探讨

GB/T 50353-2013建筑工程建筑面积计算规范于2014年7月1日开始实施,该规范是在总结原有规范基础上进行修订的,目前,新规范实施已经一年多了,依据新规范审批的建设工程陆续进入验收阶段,因此,在建筑面积测量中如何正确用好新规范显得尤为重要。本文就新规范的技术要点进行分析,以便于技术人员和管理人员正确使用新规范。     

Characterisation of tobelite (NH4)Al2[AlSi3O10](OH)2 and ND4-tobelite (ND4)Al2[AlSi3O10](OD)2 using IR spectroscopy and Rietveld refinement of XRD spectra

Tobelite (NH₄) Al₂ [AlSi₃O₁₀] (OH)₂, the ammonium analogue of muscovite, and its deuterated form ND₄-tobelite (ND₄) Al₂ [AlSi₃O₁₀] (OD)₂ have been synthesised at 600?°C and 200 and 500 Mpa using a well homogenised, stoichiometric SiO₂-Al₂O₃ oxide mix with Al₂O₃ in excess of 5 mol% and a 25% NH₃ solution whose relative abundance was such that the amount of NH₄ ⁺ stoichiometrically available was in excess of 50%. Characterisation of both tobelite and ND₄-tobelite using IR-spectroscopy, Rietveld refinement of X-ray powder diffraction data, and electron microprobe analysis indicate that, similar to K⁺ in muscovite, the NH₄ ⁺ or ND₄ ⁺ molecule occupies the interlayer site. IR absorption bands caused by NH₄ ⁺ and ND₄ ⁺ can be explained, to a very good approximation, on the basis of T_d symmetry. Nevertheless, substantial line broadening and the occurrence of shoulders indicate a deviation from ideal T_d symmetry. However, even at 77?K, no discrete splitting of the degenerate states could be confirmed. The OH stretching frequencies observed for synthetic tobelite are quite similar to those for muscovite, indicating that the replacement of K⁺ by NH₄ ⁺ has no effect. The low FWHH of the OH bands indicate that the hydroxyl groups are well ordered within the structure. Rietveld refinement of tobelite and ND₄-tobelite indicates that all samples synthesised consist of the 3 different mica polytypes which are typical of muscovite – namely 1M (C2/m), 2M ₁ (C2/c) and 2M ₂ (C2/c). Tobelite and ND₄-tobelite synthesised at 500 Mpa principally contain the 1M polytype, whereas the principle polytype for ND₄-tobelite synthesised at 200 Mpa, is 2M ₂. Rietveld refinement of X-ray diffraction spectra for tobelite synthesised at 200 Mpa was problematic due to the very broad FWHH of the X-ray peaks indicating poor crystallinity. In comparision to synthetic muscovite, the cell dimensions observed for tobelite and its deuterated analogue are quite similar except for the lattice constant c. Due to the larger radius of NH₄ ⁺ or ND₄ ⁺ compared to K⁺ cation, the c-direction is expanded form 10.275 Å in muscovite to approximately 10.540 Å in tobelite and ND₄-tobelite.     

Crystal chemistry of tremolite–tschermakite solid solutions

Tremolite–tschermakite solid solutions have been synthesized between 700 and 850 °C and 200 and 2000 MPa. The starting materials were oxide–hydroxide mixtures and an additional 0.1–1.8 molal CaBr₂ solution. The run products were characterized using SEM, HRTEM, EMP, XRD and FTIR. The synthesized Al tremolites formed needles and lath-shaped crystals of up to 300 × 20 μm. HRTEM investigations showed that the majority of the amphiboles were well ordered. The EMP analysis revealed that the Al tremolites were solid solutions in the ternary tremolite–tschermakite–cummingtonite. The highest observed Al content was close to the composition of magnesiohornblende (X_ts=0.54). Different cummingtonite concentrations (X_cum=0.00–0.18) were observed, which generally increased with Al content. Rietveld refinements of the lattice constants showed a linear decrease of the cell parameters a and b with increasing Al content, whereas c and β increased. Small deviations from the linear behaviour were caused by variable amounts of the cummingtonite component. For pure tschermakite lattice parameters of a=9.7438(11) Å, b=17.936(14) Å, c=5.2995(3) Å, β=105.68(9)° and V=891.7 ± 1.4 ų were extrapolated by least-squares regression. Using the a and β lattice parameters for tremolite, tschermakite and cummingtonite, it was possible to derive amphibole compositions using powder XRD. IR spectra of the Al tremolites showed a total of 12 individual bands. The FWHMs of all bands increased with increasing Al content. According to their FWHMs, these bands were grouped into three band systems at 3664–3676 cm^?1 (I), 3633–3664 cm^?1 (II) and 3526–3633 cm^?1 (III). Assuming ^[6]Al substitution at M2 and/or M3 and ^[4]Al at T1, three principal different configurational groups could be assigned as local environments for the proton. I: only Si⁴⁺ at T1 and one or two Al³⁺ at M2 and/or M3_far, II: one Al³⁺ at T1 and one to three Al³⁺ at M2 and/or at M3_far, III: either Al³⁺ on M3_near and/or two Al³⁺ on T1 and additional one to four Al³⁺ at M2. It is assumed that these three configurational groups correspond to the three groups of observed bands. This was quantitativly supported by Monte-Carlo simulations. A model with random distribution at M2 and M3 including Al avoidance at tetrahedral and octahedral sites yielded the best agreement with the spectroscopical results.     

Improving the efficiency of ant algorithms using adaptive refinement: Application to storm water network design

The ant algorithm is a new evolutionary optimization method proposed for the solution of discrete combinatorial optimization problems. Many engineering optimization problems involve decision variables of continuous nature. Application of the ant algorithm to the optimization of these continuous problems requires discretization of the continuous search space, thereby reducing the underlying continuous problem to a discrete optimization problem. The level of discretization of the continuous search space, however, could present some problems. Generally, coarse discretization of the continuous design variables could adversely affect the quality of the final solution while finer discretization would enlarge the scale of the problem leading to higher computation cost and, occasionally, to low quality solutions. An adaptive refinement procedure is introduced in this paper as a remedy for the problem just outlined. The method is based on the idea of limiting the originally wide search space to a smaller one once a locally converged solution is obtained. The smaller search space is designed to contain the locally optimum solution at its center. The resulting search space is discretized and a completely new search is conducted to find a better solution. The procedure is continued until no improvement can be made by further refinement. The method is applied to a benchmark problem in storm water network design discipline and the results are compared with those of existing methods. The method is shown to be very effective and efficient regarding the optimality of the solution, and the convergence characteristics of the resulting ant algorithm. Furthermore, the method proves itself capable of finding an optimal, or near-optimal solution, independent of the discretization level and the size of the colony used.     

临沭县国土资源局信息化建设的几点做法

开创国土资源管理事业新局面和带出一支高素质的干部队伍成为国土资源管理工作面前的重大课题。临沭县国土资源局以满足经济社会发展和国土资源管理需要为宗旨,以国土资源业务管理为主线,以促进高效管理、科学决策和依法行政为目标,突出现代化、精细化管理特点,走出了一条以信息化建设推进精细化管理的新思路。     

基于移动式监测的道路PM2.5浓度精细化时空模拟

作为主要的大气污染指标,PM_2.5浓度常来源于固定环境监测站点的监测与遥感影像数据,但时空精度普遍不足,难以揭示微尺度下城市内部PM_2.5时空分布情况。本文利用移动式监测方法,选择典型工作日(2017年11月27日),对广州市主城区道路以1 s和1 m为时空粒度进行PM_2.5浓度数据采集,并以早、晚出行高峰时段为对象,通过机器学习方法模拟道路PM_2.5精细化时空分布格局。结果表明,主城区早高峰道路PM_2.5浓度值相近的平均范围为24 m,晚高峰为15 m,PM_2.5浓度存在微尺度的时空异质性。利用多层感知器(MLP)构建的早、晚高峰PM_2.5浓度模型,拟合度分别达到0.70和0.68,明显优于传统的普通最小二乘法(OLS)线性回归模型。模型揭示出早高峰主城区全路网PM_2.5平均浓度为30.19μg/m3,晚高峰达到44.55μg/m3,部分高达94.82μg/m3,且“西高东低”的分布特征显著。本文提出的PM     

地理国情水系要素的自动提取

在地表覆盖水系图斑采集的基础上,利用Rosenfeld细化算法实现地理国情水系要素中心线的自动提取。首先兼顾提取质量确定图像由矢量转换为栅格的最佳像素值,然后根据内存访问效率和图像块大小的关系选择图像分块处理技术。此外,采用图像形态学的膨胀与腐蚀算法、线段长度条件约束和曲线节点抽稀等技术确保中心线提取质量。试验结果表明,本文提出的方法准确、高效,在生产实践中具有一定的应用价值。     

Schorlomite: a discussion of the crystal chemistry, formula, and inter-species boundaries

Examination of schorlomite from ijolite at Magnet Cove (USA) and silicocarbonatite at Afrikanda (Russia), using electron-microprobe and hydrogen analyses, X-ray diffraction and Mössbauer spectroscopy, shows the complexity of substitution mechanisms operating in Ti-rich garnets. These substitutions involve incorporation of Na in the eightfold-coordinated X site, Fe²⁺ and Mg in the octahedrally coordinated Y site, and Fe³⁺, Al and Fe²⁺ in the tetrahedrally coordinated Z site. Substitutions Ti⁴⁺Fe³⁺Fe³⁺_–1Si_–1 and Ti⁴⁺Al³⁺Fe³⁺_–1Si_–1 are of major significance to the crystal chemistry of schorlomite, whereas Fe²⁺ enters the Z site in relatively minor quantities (<3% Fe). There is no evidence (either structural or indirect, such as discrepancies between the measured and calculated Fe²⁺ contents) for the presence of ^[6]Ti³⁺ or ^[4]Ti⁴⁺ in schorlomite. The simplified general formula of schorlomite can be written as Ca₃Ti⁴⁺₂[Si_3-x(Fe³⁺,Al,Fe²⁺)_xO₁₂], keeping in mind that the notion of end-member composition is inapplicable to this mineral. In the published analyses of schorlomite with low to moderate Zr contents, x ranges from 0.6 to 1.0, i.e. Ti⁴⁺ in the Y site is <2 and accompanied by appreciable amounts of lower-charged cations (in particular, Fe³⁺, Fe²⁺ and Mg). For classification purposes, the mole percentage of schorlomite can be determined as the amount of ^[6]Ti⁴⁺, balanced by substitutions in the Z site, relative to the total occupancy in the Y site: (^[6]Ti⁴⁺–^[6]Fe²⁺–^[6]Mg²⁺– ^[8]Na⁺)/2. In addition to the predominant schorlomite component, the crystals examined in this work contain significant (>15 mol.%) proportions of andradite (Ca₃Fe³⁺₂Si₃O₁₂), morimotoite (Ca₃Fe²⁺TiSi₃O₁₂), and Ca₃MgTiSi₃O₁₂. The importance of accurate quantitative determination and assignment of Fe, Ti and other cations to the crystallographic sites for petrogenetic studies is discussed.

Synthesis, crystal structure and crystal chemistry of ferri-clinoholmquistite, ?Li 2Mg 3Fe 3+ 2Si 8O 22(OH) 2

This work reports the synthesis of ferri-clinoholmquistite, nominally _Li2(Mg₃Fe³⁺₂)Si₈O₂₂(OH)₂, at varying f_O2 conditions. Amphibole compositions were characterized by X-ray (powder and single-crystal) diffraction, microchemical (EMPA) and spectroscopic (FTIR, Mössbauer and Raman) techniques. Under reducing conditions ( NNO+1, where NNO = Nickel–Nickel oxide buffer), the amphibole yield is very high (>90%), but its composition, and in particular the FeO/Fe₂O₃ ratio, departs significantly from the nominal one. Under oxidizing conditions ( NNO+1.5), the amphibole yield is much lower (<60%, with Li-pyroxene abundant), but its composition is close to the ideal stoichiometry. The exchange vector of relevance for the studied system is ^M2(Mg,Fe²⁺) ^M4(Mg,Fe²⁺) ^M2Fe³⁺_–1 ^M4Li_–1, which is still rather unexplored in natural systems. Amphibole crystals of suitable size for structure refinement were obtained only at 800 °C, 0.4 GPa and NNO conditions (sample 152), and have C2/m symmetry. The X-ray powder patterns for all other samples were indexed in the same symmetry; the amphibole closest to ideal composition has a = 9.428(1) Å, b = 17.878(3) Å, c = 5.282(1) Å, = 102.06(2)°, V = 870.8(3) ų. Mössbauer spectra show that Fe³⁺ is strongly ordered at M2 in all samples, whereas Fe²⁺ is disordered over the B and C sites. FTIR analysis shows that the amount of ^CFe²⁺ increases for increasingly reducing conditions. FTIR data also provide strong evidence for slight but significant amounts of Li at the A sites.