SHRIMP U–Pb ages of diagenetic and hydrothermal xenotime from the Archaean Witwatersrand Supergroup of South Africa

SHRIMP dating of xenotime overgrowths on detrital zircon grains can constrain maximum durations since diagenesis and therefore provide minimum dates of sediment deposition. Thus, xenotime dating has significant economic application to Precambrian sediment-hosted ore deposits, such as Witwatersrand Au–U, for which there are no precise depositional ages. The growth history of xenotime in the Witwatersrand Supergroup is texturally complex, with several phases evident. The oldest authigenic xenotime ²⁰⁷Pb/²⁰⁶Pb age obtained in sandstone underlying the Vaal Reef is 2764 ± 5 Myr (1 σ), and most likely represents a mixture of diagenetic and hydrothermal growth. Nevertheless, this represents the oldest authigenic mineral age yet recorded in the sequence and provides a minimum age of deposition. Other xenotime data record a spread of ages that correspond to numerous post-diagenetic thermotectonic events (including a Ventersdorp event at ≈ 2720 Ma) up to the ≈2020 Ma Vredefort event.     

NORTHERN AND SOUTHERN HEMISPHERIC POLAR LOWS——A COMPARATIVE STUDY

Northern Hemispheric“polar lows”,i.e.maritime,small,but fairly intense cyclonic systems have been studied formore than two decades.Recently researchers have turned their attention towards the occurrence of polar lows and othersmall-scale cyclonic disturbances on the Southern Hemisphere.In this paper a short account of our present knowledgeof Northern Hemispheric polar lows will be given,followed by some preliminary results of an investigation of the natureand occurrence of polar lows on the Southern Hemisphere.     

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Abstract— Jull et al. propose an alternative interpretation of our depth vs. ¹⁴C data measured on a peat core from the central Tunguska impact site (Rasmussen et al., 1999). We find that the proposed alternative is untenable.     

中国稻田甲烷产生和排放研究 Ⅱ.模式研究和减排措施

主要介绍了近 2 0年来稻田甲烷排放的模式研究和排放量的估算以及减少稻田甲烷排放的措施。数值模式是估算稻田甲烷排放量的一条有效途径 ,模式的研究现在正处于发展阶段。介绍了几个主要的模型 ,既有物理过程模型也有经验模型。年排放量的估算范围为 6 79～ 4 1 4Tg ,随着技术的发展和大量实验的进行估算值的精度正得到不断的提高。减排措施是减少稻田甲烷排放的必要手段 ,但是目前的减排技术均处于研究阶段 ,应用还不成熟     

Glaciomarine sedimentation and bottom current activity on the north-western and northern continental margins of Svalbard during the late Quaternary

Palaeo-bottom current strength of the West Spitsbergen Current (WSC) and the influence of the Svalbard-Barents Sea Ice Sheet (SBIS) on the depositional environment along the northern Svalbard margins are poorly known. Two gravity cores from the southern Yermak Plateau and the upper slope north of Nordaustlandet, covering marine isotope stage (MIS) 1 to MIS 5, are investigated. Five lithofacies, based on grain size distribution, silt/clay ratio, content and mean of sortable silt (SS), are distinguished to characterise the contourite-dominated sedimentary environments. In addition, depositional environments are described using total organic carbon (TOC), total sulphur (TS) and calcium carbonate (CaCO₃) contents of sediments. Facies A, containing coarse SS, suggests strong bottom current activity and good bottom water ventilation conditions as inferred from low TOC content. This facies was deposited during the glacial periods MIS 4, MIS 2 and during the late Holocene. Facies B is dominated by fine SS indicating weak bottom current and poor ventilation (cf. high TOC content of 1.2–1.6%), and correlates with the MIS 4/3 and MIS 2/1 transition periods. With an equal amount of clay and sand, fine SS and high content of TOC, facies C indicates reduced bottom current strength for intervals with sediment supply from proximal sources such as icebergs, sea ice or meltwater discharge. This facies was deposited during the last glacial maximum. Facies D represents mass-flow deposits on the northern Svalbard margin attributed to the SBIS advance at or near the shelf edge. Facies E sediments indicating moderate bottom current strength were deposited during MIS 5 and MIS 3, and during parts of MIS 2. This first late Quaternary proxy record of the WSC flow and sedimentation history from the northern Svalbard margin suggests that the oceanographic conditions and ice sheet processes have exerted first-order control on sediment properties.     

Diagenetic disturbances of marine sedimentary records from methane‐influenced environments in the Fram Strait as indications of variation in seep intensity during the last 35 000 years

The effect of seeping of methane on marine sediment records has been studied in four gravity cores from Vestnesa Ridge, Svalbard margin. The area shows acoustic signs in the form of flares indicating active methane gas seepage. For a better understanding of the timing and variability of the flux of methane in the past and the effects on potential proxies, a detailed study of the diagenetic processes that may affect the composition and structure of both sediments and foraminiferal shells is needed. Here we discuss deep‐sea records from methane‐influenced environments in three cores from an active and very heterogeneous seep‐area (pockmark) and one core from outside the pockmark for background. The results include the distribution and stable isotopes of authigenic carbonates and of benthic and planktonic foraminifera, magnetic susceptibility, AMS‐¹⁴C dates, sedimentary data and biostratigraphy. Extremely low δ¹³C values recorded in both benthic and planktonic foraminifera during the Bølling‐Allerød interstadials indicate possible increased methane flux beginning at late Heinrich event H1. The recorded low values are mainly a result of diagenetic overprint by methane‐derived authigenic carbonates. The δ¹⁸O signals of authigenic carbonates are close to those of foraminiferal calcite and thus the δ¹⁸O records remain a valid stratigraphical tool in methane seep sites, except in the case of severely encrusted samples. In addition, the records from the active pockmark show nearly constant values of low magnetic susceptibility in contrast to higher and more variable magnetic susceptibility values from the control station and other published records from normal sediments west of Svalbard. This phenomenon is probably caused by dissolution of magnetic minerals in the reducing environmental conditions of methane seep sediments, associated with anaerobic oxidation of methane and formation of paramagnetic minerals (pyrite). This process enables magnetic susceptibility to be used as a common diagnostic tool for identifying methane‐related palaeo‐reductive environments.     

SHRIMP U–Pb geochronology of authigenic xenotime and its potential for dating sedimentary basins

SHRIMP (Sensitive High‐Resolution Ion MicroProbe) analytical procedures have been developed to enable dating of the small, early diagenetic xenotime overgrowths that commonly occur on zircons in siliciclastic sedimentary rocks. The method will be particularly useful in Precambrian terranes, where diagenetic xenotime dating could play a role equivalent to biostratigraphic dating in the Phanerozoic. Reliable ²⁰⁷Pb/²⁰⁶Pb data are more readily obtained than ²⁰⁶Pb/²³⁸U, which also favours application to the Precambrian. However, it is demonstrated that ²⁰⁶Pb/²³⁸U dating of larger overgrowths (>10 μm) is also viable and applicable to Phanerozoic samples. SHRIMP Pb/Pb geochronology of authigenic xenotime in an unmetamorphosed Palaeoproterozoic sandstone in the Kimberley Basin has constrained diagenesis to a precision of ± 7 Ma. In contrast, greenschist‐facies metasediments of the Archaean Witwatersrand Basin, South Africa, contain both authigenic and alteration xenotime that record a complex history of growth from early diagenesis to the last major thermal event to affect the basin.     

Evaluation of risk concepts in partial duration series

Conventional design practice aims at obtaining optimal estimates of floods with specified exceedance probabilities. Such estimates are, however, known on the average to be exceeded more frequently than expected. Alternatively, methods focusing on the expected exceedance probability can be used. Two different methods are considered here; the first is based on the sample distribution of true exceedance probabilities. The second is a Bayesian analogue using the likelihood function and a noninformative prior to describe the variability of exceedance probabilities. Appropriate analytical solutions are presented in both cases using the partial duration series approach.     

Tropospheric methane in the mid-latitudes of the Southern Hemisphere

Results of more than 800 new measurements of methane (CH₄) concentrations in the Southern Hemisphere troposphere (34–41° S, 130–150° E) are reported. These were obtained between September 1980 and March 1983 from the surface at Cape Grim, Tasmania, through the middle (3.5–5.5 km) to the upper troposphere (7–10 km). The concentration of CH₄ increased throughout the entire troposphere over the measurement period, adding further support to the view that CH₄ concentrations are currently increasing on a global scale. For data averaged vertically through the troposphere the rate of increase found was 20 ppbv/yr or 1.3%/yr at December 1981. In the surface CH₄ data a seasonal cycle with a peak to peak amplitude of approximately 28 ppbv is seen, with the minimum concentration occurring in March and the maximum in September–October. A cycle with the same phase as that seen at the surface, but with a significantly decreased amplitude, is apparent in the mid troposphere but no cycle is detected in the upper tropospheric data. The phase and amplitude of the cycle are qualitatively in agreement with the concept that the major sink for methane is oxidation by hydroxyl radicals. Also presented is evidence of a positive vertical gradient in methane, with a suggestion that the magnitude of this gradient has changed over the period of measurements.     

The global distribution of methane in the troposphere

Methane has been measured in air samples collected at approximately weekly intervals at 23 globally distributed sites in the NOAA/GMCC cooperative flask sampling network. Sites range in latitude from 90° S to 76° N, and at most of these we report 2 years of data beginning in early 1983. All measurements have been made by gas chromatography with a flame ionization detector at the NOAA/GMCC laboratory in Boulder, Colorado. All air samples have been referenced to a single secondary standard of methane-in-air, ensuring a high degree of internal consistency in the data. The precision of measurements is estimated from replicate determinations on each sample as 0.2%. The latitudinal distribution of methane and the seasonal variation of this distribution in the marine boundary layer has been defined in great detail, including a remarkable uniformity in background levels of methane in the Southern Hemisphere. We report for the first time the observation of a complete seasonal cycle of methane at the South Pole. A significant vertical gradient is observed between a sea level and a high altitude site in Hawaii. Globally averaged background concentrations in the marine boundary layer have been calculated for the 2 year-period May 1983–April 1985 inclusive, from which we find an average increase of 12.8 ppb per year, or 0.78% per year when referenced to the globally averaged concentration (1625 ppb) at the mid-point of this period. We present evidence that there has been a slowing down in the methane growth rate.Presented at the Conference on the Scientific Application of Baseline Observations of Atmospheric Composition (SABOAC), Aspendale, Australia, 7–9 November 1984.