Isotope fractionation of neon during stepheating extraction?: a comment on ‘Re‐interpretation of the existence of a primitive plume under Australia based on neon isotope fractionation during step heating’ by Gautheron and Moreira (2003)

Using a Rayleigh distillation fractionation model, we calculate that the maximum isotope fractionation potentially achievable is less than 5% during the early stages of gas release from a sample. Our calculation corrects the erroneous conclusions of Gautheron and Moreira (2003), who re‐interpreted the plume‐like neon isotopic compositions found in metasomatic apatite from a south‐eastern Australian xenolith (Matsumoto et al., 1997) to be the result of Rayleigh‐type isotope fractionation of originally MORB‐type neon during stepheating gas extraction. We stress that the modelling of neon isotopic fractionation by Gautheron and Moreira (2003) is incorrect, and that the finding of a plume‐like neon isotopic composition in the apatite by Matsumoto et al. (1997) remains a quite valid and robust conclusion.     

SHRIMP U–Pb ages of diagenetic and hydrothermal xenotime from the Archaean Witwatersrand Supergroup of South Africa

SHRIMP dating of xenotime overgrowths on detrital zircon grains can constrain maximum durations since diagenesis and therefore provide minimum dates of sediment deposition. Thus, xenotime dating has significant economic application to Precambrian sediment-hosted ore deposits, such as Witwatersrand Au–U, for which there are no precise depositional ages. The growth history of xenotime in the Witwatersrand Supergroup is texturally complex, with several phases evident. The oldest authigenic xenotime ²⁰⁷Pb/²⁰⁶Pb age obtained in sandstone underlying the Vaal Reef is 2764 ± 5 Myr (1 σ), and most likely represents a mixture of diagenetic and hydrothermal growth. Nevertheless, this represents the oldest authigenic mineral age yet recorded in the sequence and provides a minimum age of deposition. Other xenotime data record a spread of ages that correspond to numerous post-diagenetic thermotectonic events (including a Ventersdorp event at ≈ 2720 Ma) up to the ≈2020 Ma Vredefort event.     

Late Holocene great earthquakes and relative sea‐level change at Kenai,southern Alaska

Kenai, located on the west coast of the Kenai Peninsula, Alaska, subsided during the great earthquake of AD 1964. Regional land subsidence is recorded within the estuarine stratigraphy as peat overlain by tidal silt and clay. Reconstructions using quantitative diatom transfer functions estimate co‐seismic subsidence (relative sea‐level rise) between 0.28±0.28 m and 0.70±0.28 m followed by rapid post‐seismic recovery. Stratigraphy records an earlier co‐seismic event as a second peat‐silt couplet, dated to ～1500–1400 cal. yr BP with 1.14±0.28 m subsidence. Two decimetre‐scale relative sea‐level rises are more likely the result of glacio‐isostatic responses to late Holocene and Little Ice Age glacier expansions rather than to co‐seismic subsidence during great earthquakes. Comparison with other sites around Cook Inlet, at Girdwood and Ocean View, helps in constructing regional patterns of land‐level change associated with three great earthquakes, AD 1964, ～950–850 cal. yr BP and ～1500–1400 cal. yr BP. Each earthquake has a different spatial pattern of co‐seismic subsidence which indicates that assessment of seismic hazard in southern Alaska requires an understanding of multiple great earthquakes, not only the most recent. All three earthquakes show a pre‐seismic phase of gradual land subsidence that marked the end of relative land uplift caused by inter‐seismic strain accumulation. Copyright © 2005 John Wiley & Sons, Ltd.     

Low-cost volcano surveillance from space: case studies from Etna, Krafla, Cerro Negro, Fogo, Lascar and Erebus

 Satellite data offer a means of supplementing ground-based monitoring during volcanic eruptions, especially at times or locations where ground-based monitoring is difficult. Being directly and freely available several times a day, data from the advanced very high resolution radiometer (AVHRR) offers great potential for near real-time monitoring of all volcanoes across large (3000×3000 km) areas. Herein we describe techniques to detect and locate activity; estimate lava area, thermal flux, effusion rates and cumulative volume; and distinguish types of activity. Application is demonstrated using data for active lavas at Krafla, Etna, Fogo, Cerro Negro and Erebus; a pyroclastic flow at Lascar; and open vent systems at Etna and Stromboli. Automated near real-time analysis of AVHRR data could be achieved at existing, or cheap to install, receiving stations, offering a supplement to conventional monitoring methods. Received: 21 January 1997 / Accepted: 3 April 1997     

A laboratory test of the soil chemical submodels of two models of catchment acidification

Parameters for ion exchange selectivity and aluminium hydroxide dissolution in the soil chemical submodels used in applications of the Birkenes model and of MAGIC are compared and several discrepancies identified for organic soils. A laboratory column simulation of the soil chemical submodels is proposed and applied to soils from the Loch Dee area in Galloway. Experimental results were well predicted by a simplified version of MAGIC, with ion exchange selectivity parameters similar to those used in a previous simulation of one subcatchment of Loch Dee. The aluminium hydroxide dissolution parameter used previously was found to be too low for the organic soil materials, where a value of 106 predicted the experimental results more closely. The model developed also included a simple silicate weathering reaction to release base cations into the system. It is concluded that such simple laboratory simulations are useful for independent calibration of the soil chemical submodel of catchment models.     

Quaternary stratigraphy of the buried valleys of the lower Red Deer River,Alberta, Canada

The Quaternary fills of the buried valleys of southern Alberta and Saskatchewan have provided a wealth of information for the reconstruction of the glacial-interglacial record of the western plains of Canada, and this paper reports on the previously unstudied stratigraphy of the buried Calgary Valley and its former tributaries in the lower Red Deer River area. We attempt to differentiate Empress Group sediments, which potentially relate to pre-glacial, interglacial/ interstadial and post-glacial lake and river deposition, using sedimentology, stratigraphy and palaeoecology. Twenty-nine stratigraphical logs indicate that Empress Group sediments have infilled a considerably large area of badlands and tributary coulees that once drained into the Calgary Valley, located 15 km to the north of Dinosaur Provincial Park. Radiocarbon dates of 52.4 ka, 27.4 ka and > 42.4 ka and glacially modified quartz grains suggest that at least some of the valley fills date to interglacial or interstadial periods and may be mid-Wisconsinan in age. However, outcrops of an older till overlying other valley fills suggest that the buried valleys were only partially excavated during interglacials/interstadials and that older (even pre-glacial) sediments could have survived. Subglacial channels, recognisable on air photographs, largely coincide with buried valley positions due to the preferential excavation of the Quaternary sediment by meltwater and are filled with post-glacial lake sediment from which a radiocarbon date of 16 ka BP was obtained. Pre-glacial and glacial/post-glacial Empress Group sediments are lithologically indistinct but cover a large time span in southern Alberta.     

Analysis of a “flickering” Geminid fireball

Abstract— In the early morning hours of December 13, 2002, a bright Geminid fireball with an absolute magnitude of ?9.2 ± 0.5 was observed from Southern Saskatchewan, Canada. The fireball displayed distinct small‐scale oscillations in brightness, or flickering, indicative of the parent meteoroid being both non‐spherical and rotating. Using the light curve derived from a calibrated radiometer, we determine a photometric mass of 0.429 ± 0.15 kg for the meteoroid, and we estimate from its initial rotation rate of some 6 Hz that the meteoroid was ejected from the parent body (3200) Phaethon some 2500 ± 500 years ago. We find that 70% of Geminid fireballs brighter than magnitude ?3 display distinct flickering effects, a value that is in stark contrast to the 18% flickering rate exhibited by sporadic fireballs. The high coincidence of flickering and the deep atmospheric penetration of Geminid fireballs are suggestive of Geminid meteoroids having a highly resilient structure, a consequence, we suggest, of their having suffered a high degree of thermal processing. The possibility of Gemind material surviving atmospheric ablation and being sampled is briefly discussed, but the likelihood of collecting and identifying any such material is admittedly very small.