Foraminiferal biostratigraphy and paleoenvironmental reconstruction at the Yaxcopoil‐1 drill hole,Chicxulub crater,Yucatán Peninsula

Abstract The Yaxcopoil‐1 (Yax‐1) drill hole comprises Cretaceous limestones and calcarenites, the K/P boundary cocktail unit (including impact breccia), and a Danian marly clay layer overlain by calcareous marls. The biostratigraphy, paleobathymetry, and environmental turnover across the K/P interval were inferred after analyzing the planktic and benthic foraminiferal assemblages. The Cretaceous samples only contain a few poorly preserved planktic foraminifera of a middle Campanian to Maastrichtian age, while low‐diversity benthic foraminiferal assemblages suggest a sufficient nutrient supply to the sea floor and a shallow neritic, occasionally stressed environment. The impact breccia and the redeposited suevite are overlain by a 46 cm‐thick dolomitic calcareous sandstone unit that contains scarce, reworked planktic foraminiferal specimens. This unit probably represents the uppermost part of the initial infill of the crater. The uppermost centimeters of this unit are bioturbated, and its top represents a hiatus that spans at least the G. cretacea, Pv. eugubina, and part of the P. pseudobulloides biozones. This unit is overlain by a 3–4 cm‐thick marly clay layer that represents a condensed layer. Benthic foraminiferal assemblages suggest a low food supply to the sea floor and environmental instability during the deposition of the marly clay layer. The increase in diversity of the assemblages indicates that the environmental conditions improved and stabilized from the G. compressa biozone toward the A. uncinata (P2) biozone. The Danian planktic and benthic foraminiferal assemblages indicate a deeper, probably bathyal environment.     

The northern Patagonia Somuncura plateau basalts: a product of slab‐induced,shallow asthenospheric upwelling?

The Meseta de Somuncura forms the largest basaltic plateau (20 000 km²) of southern Argentina (extra-Andean domain). Most of these tholeiitic to alkaline rocks were extruded at ˜ 25 Ma (late Oligocene). The absence of rifting–thinning processes, plume activity, or slab-window phenomena leaves only one major possibility for the generation of Somuncura: asthenospheric ('OIB-like') corner flow leading to a transient thermal anomaly above the subducting plate. It is suggested herein that the intake of hot asthenosphere was forced into a favourable topography (concave-up) of the subducting plate, when a major plate reorganization event (Farallon to Nazca) was taking place in late Oligocene to early Miocene time. The fast and vigorous intake of asthenosphere would have been induced by slab roll-back, leading to decoupling of the subducting plate. The Somuncura volcanic episode can be regarded as a marker of the passage from the extremely oblique subduction of Farallon, to the birth of the Nazca plate and roughly perpendicular convergence between South America and Nazca.     

Formation of the regular satellites of giant planets in an extended gaseous nebula I: subnebula model and accretion of satellites

We model the subnebulae of Jupiter and Saturn wherein satellite accretion took place. We expect each giant planet subnebula to be composed of an optically thick (given gaseous opacity) inner region inside of the planet’s centrifugal radius (where the specific angular momentum of the collapsing giant planet gaseous envelope achieves centrifugal balance, located at rCJ ∼ 15R_J for Jupiter and rCS ∼ 22R_S for Saturn) and an optically thin, extended outer disk out to a fraction of the planet’s Roche-lobe (R_H), which we choose to be ∼R_H/5 (located at ∼150 R_J near the inner irregular satellites for Jupiter, and ∼200R_S near Phoebe for Saturn). This places Titan and Ganymede in the inner disk, Callisto and Iapetus in the outer disk, and Hyperion in the transition region. The inner disk is the leftover of the gas accreted by the protoplanet. The outer disk may result from the nebula gas flowing into the protoplanet during the time of giant planet gap-opening (or cessation of gas accretion). For the sake of specificity, we use a solar composition “minimum mass” model to constrain the gas densities of the inner and outer disks of Jupiter and Saturn (and also Uranus). Our model has Ganymede at a subnebula temperature of ∼250 K and Titan at ∼100 K. The outer disks of Jupiter and Saturn have constant temperatures of 130 and 90 K, respectively.Our model has Callisto forming in a time scale ∼10⁶ years, Iapetus in 10⁶-10⁷ years, Ganymede in 10³-10⁴ years, and Titan in 10⁴-10⁵ years. Callisto takes much longer to form than Ganymede because it draws materials from the extended, low density portion of the disk; its accretion time scale is set by the inward drift times of satellitesimals with sizes 300-500 km from distances ∼100R_J. This accretion history may be consistent with a partially differentiated Callisto with a ∼300-km clean ice outer shell overlying a mixed ice and rock-metal interior as suggested by Anderson et al. (2001), which may explain the Ganymede-Callisto dichotomy without resorting to fine-tuning poorly known model parameters. It is also possible that particulate matter coupled to the high specific angular momentum gas flowing through the gap after giant planet gap-opening, capture of heliocentric planetesimals by the extended gas disk, or ablation of planetesimals passing through the disk contributes to the solid content of the disk and lengthens the time scale for Callisto’s formation. Furthermore, this model has Hyperion forming just outside Saturn’s centrifugal radius, captured into resonance by proto-Titan in the presence of a strong gas density gradient as proposed by Lee and Peale (2000). While Titan may have taken significantly longer to form than Ganymede, it still formed fast enough that we would expect it to be fully differentiated. In this sense, it is more like Ganymede than like Callisto (Saturn’s analog of Callisto, we expect, is Iapetus). An alternative starved disk model whose satellite accretion time scale for all the regular satellites is set by the feeding of planetesimals or gas from the planet’s Roche-lobe after gap-opening is likely to imply a long accretion time scale for Titan with small quantities of NH₃ present, leading to a partially differentiated (Callisto-like) Titan. The Cassini mission may resolve this issue conclusively. We briefly discuss the retention of elements more volatile than H₂O as well as other issues that may help to test our model.     

Reliability assessment of granular filters in embankment dams

Empirical criteria have been used successfully to design filters of most embankment large dam projects throughout the world. However, these empirical rules are only applicable to a particular range of soils tested in laboratory and do not take into account the variability of the base material and filter particle sizes. In addition, it is widely accepted that the safety of fill dams is mainly dependent on the reliability of their filter performance. The work herein presented consists in a new general method for assessing the probability of fulfilling any empirical filter design criteria accounting for base and filter heterogeneity by means of first‐order reliability methods (FORM), so that reliability indexes and probabilities of fulfilling any particular criteria are obtained. This method will allow engineers to estimate the safety of existing filters in terms of probability of fulfilling their design criteria and might also be used as a decision tool on sampling needs and material size tolerances during construction. In addition, sensitivity analysis makes possible to analyse how reliabilities are influenced by different sources of input data. Finally, in case of a portfolio risk assessment, this method will allow engineers to compare the safety of several existing dams in order to prioritize safety investments and it is expected to be a very useful tool to evaluate probabilities of failure due to internal erosion. Copyright © 2006 John Wiley & Sons, Ltd.     

Ultra-Deep Optical Spectroscopy with PMAS. Using the Nod-and-Shuffle Technique

PMAS, the Potsdam Multi-Aperture Spectrophotometer, is a new integral field spectrograph in the optical, which is optimized for good transmission and high image quality from 350 nm to 1 μm. We present our plan to implement a CCD charge-shuffle mode to allow for beam switching with a very high degree of sky subtraction accuracy for faint object 3-D spectroscopy. This revised version was published online in July 2006 with corrections to the Cover Date.     

Using bright ellipticals as dark energy cosmic clocks

The age of the Universe has been increasingly constrained by different techniques, such as the observations of type Ia supernovae (SNIa) at high redshift or dating the stellar populations of globular clusters. In this paper, we present a complementary approach using the colours of the brightest elliptical galaxies in clusters over a wide redshift range  ( z ≲ 1)  . We put new and independent bounds on the dark energy equation of state parametrized by a constant pressure-to-density ratio   w _Q  and by a parameter (ξ) which determines the scaling between the matter and dark energy densities. We find that accurate estimates of the metallicities of the stellar populations in moderate and high-redshift cluster galaxies can pose stringent constraints on the parameters that describe dark energy. Our results are in good agreement with the analysis of dark energy models using SNIa data as a constraint. Accurate estimates of the metallicities of stellar populations in cluster galaxies at   z ≲ 2  will make this approach a powerful complement to studies of cosmological parameters using high-redshift SNIa.     

Oxidation and metal-insertion in molybdenite surfaces: evaluation of charge-transfer mechanisms and dynamics

Molybdenum disulfide (MoS₂), a layered transition-metal dichalcogenide, has been of special importance to the research community of geochemistry, materials and environmental chemistry, and geotechnical engineering. Understanding the oxidation behavior and charge-transfer mechanisms in MoS₂ is important to gain better insight into the degradation of this mineral in the environment. In addition, understanding the insertion of metals into molybdenite and evaluation of charge-transfer mechanism and dynamics is important to utilize these minerals in technological applications. Furthermore, a detailed investigation of thermal oxidation behavior and metal-insertion will provide a basis to further explore and model the mechanism of adsorption of metal ions onto geomedia.     

Contributions of boron isotopes to understanding the hydrogeochemistry of the coastal detritic aquifer of Castellón Plain,Spain

The Castellón Plain alluvial aquifer, Spain, is intensively exploited to meet the demand for agricultural irrigation and industrial water supply. The geochemistry of its groundwater shows complex salinization in the northern and southern parts of the aquifer, with significant pollution from human origin in the central portion. Boron content and B isotope geochemistry are useful for distinguishing between various sources of pollution and their relative importance in different parts of this aquifer. Boron concentrations in the groundwater vary between 0.01 and 0.85 mg/L. In the more saline groundwaters, found at the northern and southern ends of the study area, the presence of B is linked to inputs from seawater and water with a calcium-magnesium sulphate facies, which feed the aquifer and clearly influence the chemistry of its waters. Evidence of B adsorption processes in some samples is shown by the low B/Cl ratios and the high values of δ¹¹B. In the central portion of the aquifer, the high B/Cl ratios and the strongly negative δ¹¹B are related to pollution of human origin.