Pyrite formation driven by MSW landfill leachate in the Madrid Basin, Spain

The role of municipal solid waste (MSW) landfill leachate on the genesis of minor amounts of pyrite associated with gypsum in an otherwise predominantly evaporitic sequence was studied in geological and geochemical terms. The potential association between landfill leachate and the conditions required for bacterial reduction of sulfate and fixation of H₂S as pyrite were examined. The lithological column was generally found to contain little or no Fe. The δ³⁴S values for sulfates were consistent with previously reported data; however, the measured δ¹⁸O values were slightly higher. Sulfides disseminated in the marl/lutite exhibited higher δ³⁴S values (≈−8‰) than gypsum-coating pyrite crystals (δ³⁴S < −30‰). Dissolution of gypsum to sulfate and the supply of metabolizable organic matter and Fe required for H₂S fixation as sulfides may have originated from landfill leachate. Intermittent availability of leachate, a result of the precipitation regime, can facilitate sulfur disproportionation and lead to fractionations as high as      

Quantitative basin characterisation to refine debris-flow triggering criteria and processes: an example from the Italian Western Alps

This paper investigates rapid channelized debris flow related to rainfalls in small alpine basins. Its goal is to evaluate and correlate different geological and technical aspects with predisposing and triggering factors that can control these phenomena. The study area is the upper part of the Susa Valley where 12 small basins were selected. For each of them, lithological, geomorphological, climatic and technical information were mapped and analysed. Debris-flow triggering conditions, flow and depositional processes were related to physical characteristics of the basin that can be easily measured and quantified. At least three different groups of basins were found: G1) basins with one event each 4–6 years, characterised by massive or blocky calcareous rocks, G2) basins with more than one event per year that show an abundance of layered or sheared fine-grained rocks and G3) basins with recurrence levels exceeding 10 years, activated only by heavy and prolonged rainfalls, marked by massive or blocky coarse-grained igneous rocks. Furthermore, important morphometric differences were found. These considerations are useful in terms of hazard zonation and risk mitigation.     

On the oceanic impact of a data-assimilation method in a coupled ocean-land-atmosphere model

 Based on the Kalman filter theory, a new data-assimilation method has been used to improve the 3-D oceanic temperature field of the Center for Ocean-Land-Atmosphere Studies (COLA) coupled general circulation model. This method is applied to assimilate surface and subsurface temperature of in situ measurements from the Pilot Research Moored Array in the Tropical Atlantic project (PIRATA). The assimilation of the PIRATA data produces an improved representation of the thermal state of the ocean and allows a better estimation of other oceanographic quantities, like meridional heat fluxes and zonal currents. The present paper focuses on the tropical Atlantic and, in particular, it contains new reconstructed temperature profiles. One-month forecast experiments during 1999 were performed and the impact of the assimilation is discussed. Received: 24 April 2001 / Accepted: 8 March 2002     

Linking foraging behavior and diet in a diving seabird

Foraging behavior and diet of breeding seabirds may be analysed simultaneously with the combined use of remote sensing devices and stable isotope analysis. Imperial shag, Phalacrocorax atriceps, breeding at Punta León colony, Argentina, were equipped with global positioning system (GPS) loggers to record foraging trips and blood samples were taken after removal of the devices in order to analyse their nitrogen and carbon stable isotope composition in whole blood and plasma. Whole blood was correlated to plasma isotopic composition for each individual (n = 35), linking diet in the short and medium term. Sexes did not differ in isotopic signatures. The maximum distance reached and the total number of dives that individuals made on two consecutive foraging trips were correlated to their plasma nitrogen isotopic signature. Individuals that went further from the colony and dived fewer times presented more positive signatures, indicative of benthic prey consumption (e.g. Raneya brasiliensis). Diet was predominantly benthic with some individuals incorporating pelagic prey (Engraulis anchoita) and even cephalopods (Octopus tehuelchus). Within breeding pairs (n = 9), different combinations of foraging and prey preferences were observed. Estimated trophic levels of these individuals were similar to those of the same species in other colonies further south along the Patagonian coast.     

Biogeochemical characterization of a Mediterranean shallow lake using stable isotopes: Laguna del Cristo (NW Iberian Peninsula)

The present multi-isotopic study (δ¹⁸O–δD_water, δ³⁴S–δ¹⁸O_{dissolved-sulphate}, δ¹³C_{dissolved-inorganic-carbon}, δ¹³C–δ¹⁸O_{shells-modern-gastropods}, δ¹³C_plants, and δ¹³C_{sedimentary-organic-matter}) is aimed at assessing the hydrogeochemical changes and biogeochemical dynamics in a Mediterranean shallow lake fed by a Quaternary–Tertiary aquifer, the “Laguna del Cristo” (NW Iberian Peninsula), a system sensitive to climate fluctuations, between 2010 and 2011. Lake water is of the bicarbonate type, and there are no major pollutants. δ¹⁸O-δD_water values plot on a local evaporation line (δD=5.29δ¹⁸O–12.29) indicating that evaporative enrichment had a significant impact on lake water isotopic features. Periods of high water levels are characterized by lower δ³⁴S–δ¹⁸O_{dissolved-sulphate} and δ¹³C_{dissolved-inorganic-carbon} values and suggest sulphate derived from weathering of sulphides in the catchment area, delivered to the lake by surface run-off or via groundwater, and in situ decay of organic matter. During lower water levels, sulphate reduction and enhanced primary productivity lead to higher δ³⁴S_{dissolved-sulphate} and δ¹³C_{dissolved-inorganic-carbon} values. Evaporation induced enrichment in ¹⁸O_sulphate, ¹³C_{dissolved-inorganic-carbon} and ¹³C–¹⁸O_{shells-Galba-Gyraulus}. δ¹³C_plant confirms the C3 photosynthetic pathway. Enrichment in ¹³C submerged aquatic plants indicates that HCO₃^? is the main carbon source, except for ¹³C-depleted Potamogeton. The TOC, δ¹³C_org values, and TC/TN ratios in sediments all confirm the autochthonous character of organic matter contribution. This study provides a baseline for isotopic research into shallow, flow-through lakes fed by siliciclastic aquifers, and stresses the importance of evaporation and refilling (direct precipitation and groundwater discharge) in controlling the solute chemistry and stable isotopic composition in temperate regions with contrasting seasonal climates. The results also provide a snapshot of modern lake isotope variability that can be applied to paleoenvironmental reconstructions.     

Spatial assessment of groundwater use potential for irrigation in Teesta Barrage Project in Bangladesh

In Bangladesh, development of the groundwater resource for irrigation is a vital component of the government’s agricultural strategy to attain food self-sufficiency. Amidst reports of falling groundwater levels in many parts of Bangladesh, the potential of groundwater use has been investigated in the Teesta Barrage Project (TBP) in which large-scale groundwater development for dry-season irrigation has taken place in the recent past. Several techniques and tools have been applied such as the combination of analysis of groundwater hydrographs and mathematical modelling to derive key hydrogeological variables, calculation of net irrigation requirement and the use of geographical information systems. The results show that the economically attractive high-yielding variety (HYV) Boro (dry season) rice cultivation during the groundwater irrigation season may not be sustained in large parts of the project area if the current trends in abstraction are continued. However, due to spatial variation in abstraction, nine thanas (sub-districts)—out of a total of 21 in the project area—may still be able to expand groundwater-irrigated cropland and a groundwater-use potential of 40 mm/year may be created if deep-set shallow tubewells are used by the farmers to abstract groundwater. A structured approach, based on zoning of potential areas, is recommended for groundwater development and use.

---

Resumen En Bangladesh, el desarrollo de las aguas subterráneas para riego es un componente vital del la estrategia agrícola del Gobierno para obtener la auto-suficiencia alimentaria. Un informe intermedio evidencia un descenso de los niveles de aguas subterráneas en muchas partes de Bangladesh, el uso potencial de aguas subterránea ha sido investigado en el Proyecto Tessta Barrage (TBP) en el cual ha tenido lugar el desarrollo de las aguas subterráneas a gran escala para el riego en la estación seca en un pasado reciente. Se ha aplicado algunas técnicas y herramientas, como la combinación del análisis de datos gráficos de aguas subterráneas y modelización matemática para obtener variables hidrogeológicas clave, el cálculo de la necesidad neta de riego y el uso de Sistemas de Información Geográfica. El resultado muestra que el cultivo, económicamente atractivo, de arroz HYV Boro (estación seca) durante la estación de riego con aguas subterráneas puede no ser sostenible en gran parte del área del proyecto si continúan las tendencias actuales en las extracciones. Sin embargo, debido a la variación espacial en la extracción, nueve thanas (subdistritos)—de un total de 21 en el área del Proyecto—pueden todavía sufrir un aumento de la tierra cultivable regada con aguas subterráneas y que se puede asumir un uso potencial de agua subterránea de 40 mm/estación si los granjeros utilizan sondeos someros instalados en fosas para la extracción. Se recomienda una aproximación estructurada para el desarrollo y uso de las aguas subterráneas, basada en la zonificación de áreas potenciales.

---

Résumé Au Bangladesh, l’exploitation des ressources en eau souterraines pour l’irrigation est une composante vitale de la stratégie agricole gouvernementale pour atteindre l’auto-suffisance alimentaire. Parmi les baisses de niveaux piézométriques rapportées sur de nombreuses régions du Bangladesh, le potentiel d’utilisation des eaux souterraines a été étudié sur le Projet de Barrage de Teesta (TBP), où, dans un passé récent, les eaux souterraines ont été massivement exploitées pour l’irrigation en saison sèche. De nombreux outils et techniques ont été utilisés, comme l’analyse combinée des chroniques piézométriques et des modèles mathématiques pour dégager les variables hydrogéologiques clés, le calcul des besoins nets pour l’irrigation, et l’utilisation des systèmes d’information géographique. Les résultats démontrent que la culture en saison d’irrigation de la variété de riz HYV Boro (saison sèche), économiquement attrayante, n’est potentiellement pas viable sur de nombreux secteurs de la zone étudiée si les prélèvements perdurent selon la tendance actuelle. Cependant, du fait de la variation spatiale des prélèvements, neuf thanas (sous-districts)—sur un total de 21 sur le secteur d’étude—pourraient encore augmenter les surfaces irriguées, et une disponibilité en eau de 40 mm/saison pourrait être générée si les agriculteurs utilisaient des puits peu profonds pour exploiter les ressources souterraines. Une approche structurée, basée sur le zonage des secteurs potentiels, est recommandée pour l’exploitation et l’utilisation des eaux souterraines.

     

Search for strange attractors in magnetic field data: An example from a tertiary volcanic area near Bonn, Germany

Spatial variations of the magnetic field, measured at the Earth's surface, are mainly due to geological inhomogeneities within the crust. The present state of the crust, in turn, reflects its past dynamical processes and evolution. We analyzed the magnetic field intensity along a few but densely sampled profiles in a Tertiary volcanic province near Bonn, Germany. The aim was to find out whether the variation of the magnetic intensity can be related to a deterministic, although chaotic, generating system or to a stochastic one. In the former case, the geodynamical history would depend on a few degrees of freedom, whereas in the latter case, the parameters to take into account were so many that a statistic approach appears to be more suitable. Since strange attractors do not emerge from the analyzed data, we exclude the presence of a chaos generating system. Autocorrelation functions and a rescaled-range analysis, on the other hand, reveal and quantify a certain degree of correlation among successive data points and allow calculation of a range of spectral exponents in log-log diagrams, which are clearly distinct from those of white noise and Brownian motion. Only one of the profiles exhibits similarity to uncorrelated or white noise. In this case, the signal variations do not result from the local geology but from a buried gas pipe-line, aligned subparallel to that profile. If self-organized crustal evolution generally produces signatures that can be described as correlated noise, within a limited bandwidth of spectral exponents, erraneous or disturbed data could eventually be discriminated from records containing purely natural data by applying analysis tools of the dynamic system theory together with autocorrelation tests.     

Clinopyroxenes from mantle-related xenocrysts in alkaline basalts from Hannuoba (China): augite–pigeonite exsolutions and their thermal significance

Optically homogeneous augite xenocrysts, closely associated with spinel–peridotite nodules, occur in alkali basalts from Hannuoba (Hebei province, China). They were studied by electron and X-ray diffraction to define the occurrence and significance of pigeonite exsolution microtextures. Sub-calcic augite (Wo₃₄) exsolved into En_62–62Fs_25–21Wo_13–17 pigeonite and En_46–45Fs_14–14Wo_40–42 augite, as revealed by TEM through diffuse coarser (001) lamellae (100–300 Å) and only incipient (100) thinner ones (<70 Å). C2/c augite and P2₁/c pigeonite lattices, measured by CCD-XRD, relate through a(Aug)?a(Pgt), b(Aug)?b(Pgt), c(Aug)≠c(Pgt) [5.278(1) vs 5.189(1)Å] and β(Aug)≠β(Pgt) [106.55(1) vs 108.55(2)°]. Cell and site volumes strongly support the hypothesis that the augite xenocrysts crystallised at mantle depth from alkaline melts. After the augite xenocrysts entered the magma, (001) lamellae first formed by spinodal decomposition at a T_min of about 1,100 °C, and coarsened during very rapid transport to the surface; in a later phase, possibly on cooling, incipient (100) lamellae then formed.     

Observing Entrainment Processes Using a Small Unmanned Aerial Vehicle: A Feasibility Study

Measurement flights with the meteorological mini aerial vehicle (M $^2$ AV) were performed in spring 2011 to assess the capability of an unmanned aerial vehicle (UAV) to measure the structure of the transition zone between the convective boundary layer and the stably stratified free atmosphere. The campaign took place at the Meteorological Observatory Lindenberg/Richard-Aßmann-Observatory of the German Meteorological Service. Besides the M $^2$ AV flights, observations were made from a 12-m and a 99-m tower, a sodar, two ceilometers, radiosondes, and a tethered balloon with sensor packages at six different levels. M $^2$ AV measurements were intentionally combined with remote sensing systems. The height range of the entrainment zone as well as its diurnal cycle were provided by the remote sensing instruments. The UAV provided the high-resolution in situ data of temperature and wind for the study of turbulent processes. It is shown that the M $^2$ AV is able to maintain constant altitude with very small deviations—a pre-requisite to study processes inside the often quite thin entrainment zone and that M $^2$ AV high-resolution wind and temperature measurements allow for very detailed studies of the fine structure of the atmosphere and thus for the identification of quite local and/or short-duration processes such as overshooting thermals or downward intrusions of warm air. Spatial series measured by the M $^2$ AV during horizontal flights show turbulent exchange of heat in short turbulent bursts at heights close to and within the entrainment zone. Scaled vertical profiles of vertical velocity, potential temperature variance, and sensible heat flux confirm the general shape found by previous measurements and numerical studies.