Carbon isotope fractionation between graphite and diamond during shock experiments

Abstract— Carbon isotopic compositions were measured for shock‐produced diamond and shocked graphite formed at peak pressures ranging from 37 to 52 GPa. The δ¹³C values of diamonds produced in a sealed container were generally lower than that of the initial graphite. The differences in the carbon isotopic composition between initial graphite and shocked graphite/diamond may reflect kinetic isotopic fractionation during the oxidation of the graphite/diamond and/or analytical artifacts possibly induced by impurities in the samples. The pressure effect on the isotopic fractionations between graphite and diamond can be estimated from the δ¹³C values of impurity‐free diamonds produced using a vented container from which gases, including oxygen, in pore spaces escaped during or after the diamond formation (e.g., 0.039 ± 0.085‰ at a peak pressure of 52 GPa). Any isotopic fractionation induced by shock conversion of graphite to diamond is too small to be detected in natural shock‐induced diamond‐graphite systems related to terrestrial impact cratering processes.     

Abyssal current along the northern periphery of Shikoku Basin

Abyssal currents along the northern periphery of the Shikoku Basin south of Japan were measured by current meters moored off Cape Daio-zaki, Cape Shiono-misaki and Cape Ashizuri-misaki and on the eastern foot of the northernmost part of the Kyushu-Palau Ridge. Total length of observation off Cape Shiono-misaki was about five years including the periods of the Kuroshio large meander and no meander. Analyses of current data show:

1. Mean currents with a magnitude of 5–10 cm sec^?1 were observed during the whole observation period at all of current meters which were set 400 m above the sea bottom that was deeper than 4,500 m. The mean current for each current meter was parallel to the local bottom contour arond each station and was toward a direction looking the Nankai Trough (a trough located along the northern end of the Shikoku Basin) to the left.
2. At each station located above the shelf toe off Cape Daio-zaki and off Cape Shiono-misaki and on the foot of the Kyushu-Palau Ridge, the mean current increases with depth (a bottomward intensification of the mean current), and the vertical extent of the mean current is estimated to be about 2,000 m above the sea bottom.
3. At a station located at 2,600 m depth on the continental slope off Cape Shiono-misaki, no bottom-ward intensification of currents was observed.

These results strongly suggest that a steady abyssal flow exists in the depths deeper than about 3,000 m along the northern and northwestern peripheries of the Shikoku Basin. Existence of the abyssal circulation system is also suggested, at least, in the north of the Shikoku Basin.     

Eduction of hydrodynamical processes from cross-channel electric-potential differences in the Kuroshio area around the Izu Ridge

The paper comprises analysis of telluric electric-potential differences measured across channels west and south of Oshima in the Kuroshio area to the south of Tokyo Bay during one to two years around 1960. The records are shown to involve ionospheric and magnetospheric induction noises, which are at the same or higher energy level compared to signals induced by Oceanic-dynamic processes in a frequency range of the daily and higher cycles. Channel transports estimated from potential records through eliminating the noises are verified, in reference to hydrographic observations as well as cross-channel difference in sea-level observations, to represent well the actual transport not only in the baroclinic geostrophic mode but also in the barotropic geostrophic mode and the mode deviated from geostrophy. The channel transports, which are obtained continuously in time, are proved to reveal especially well the detailed time-varying processes, on illustrating the case of an inverse-current burst happened in the Oshima-West Channel. At the end, results from spectral analyses of potential records in relation to reference quantities are presented.     

Photographic observations of the stalked crinoidMetacrinus rotundus carpenter in Suruga Bay,central Japan

Photographic observations were carried out at depths of the shelf edge at the mouth of Uchiura Inlet, Suruga Bay, central Japan in order to clarify the life style of the isocrinid stalked crinoid,Metacrinus rotundus (Echinodermata). The distribution of the species was found to be restricted to a narrow area where boulders and rock outcrops were locally present. Mean density of the crinoid was 0.05 m^–2, and this value was an order of magnitude smaller than that of the deeper isocrinid,Diplocrinus wyvillethomsoni, reported from the Bay of Biscay.Metacrinus rotundus formed a parabolic filtration fan with its arms recurved into the bottom current, and was thought to be a passive suspension feeder elevating the fan into the water column by its stalk. The distal half of the stalk lay along the hard substratum and about ten groups of cirri grasped the substratum. This mode of attachment was similar to that ofCenocrinus rather than that ofDiplocrinus. Metacrinus rotundus collect food at the layer between 10 and 50 cm above the sea floor, and do not utilize a higher layer even when this layer could be utilized by climbing over a larger boulder. Resuspended benthic materials are thought to be important as a food source forM. rotundus, and the crinoids seek not only locations of stronger currents but also the position where much resuspended matter is available.     

Archeological evidence of Pacific salmon distribution in northern Japan and implications for future global warming

Archeological evidence of Pacific salmon in Hokkaido is reviewed and compared with results from western North America. Salmon remains have been found at 24 sites in Hokkaido from the Early Jomon Period to the Ainu Period (6000–100 years ago). Fish remains at three archeological sites in the Kushiro River basin indicated that Pacific salmon (Oncorhynchus spp.) were distributed and utilized from 6000 years ago. The present Kushiro Wetland was formerly covered with seawater and called the Paleo Kushiro Bay 5000–6000 years ago. Based on the molluscan fossil fauna, seawater temperature at Paleo Kushiro Bay was about 5°C warmer than at present. Warmer conditions for salmon in Kushiro 5000–6000 years ago corresponded with the poor conditions for salmon in the Columbia River basin 6000–7000 years ago. If the future global warming is similar to the conditions that prevailed 5000–6000 years ago, the southern limit of salmon distribution will shift northwards and the salmon production will decrease. However, they will not disappear from either Hokkaido or southwestern North America.     

Hydrographic structure in association with deep boundary current in the north of the Shikoku Basin

High quality CTD data were collected in the north of the Shikoku Basin where an abyssal boundary current has been observed through direct current measurements. Analyses of hydrographic data showed:

1. Colder and saltier water (heavier water) compared to surrounding waters is found above the continental shelf-toe and the eastern flank of the Kyushu-Palau Ridge where the existence of the abyssal boundary current has been expected. The heavier water has a horizontal extent of about 50 km.
2. The heavier water has the vertical scale of 2000 m from the sea bottom, and is associated with a thermal wind shear which enhances a component of the flow toward a direction looking the Nankai Trough (a trough located along the northern end of the Shikoku Basin) to the left in the abyss. The assumed “level of no motion” at about 2500 m depth gives the geostrophically estimated current in a good agreement with the directly measured current.

A volume transport associated with the colder and higher salinity water is estimated to be about 2 Sv off Cape Shiono-misaki which may include a recirculation above the Nankai Trough. This is about twice of the transport estimated in the interior of the Shikoku Basin through a vorticity balance between the stretching term and latitudinal variation of the planetary vorticity.     

硫酸皮肤素寡糖的分离与制备

利用软骨素酶 ABC (Chondroitinase ABC,EC4 .2 .2 .4 )对硫酸皮肤素 (Dermatan Sul-fate,DS)进行控制降解。对得到的混合寡糖首先采用低压凝胶渗透色谱 (L PGPC)进行分级 ,然后对每一组分再利用强阴离子交换高压液相色谱 (SAX- HPL C)进行分离 ,最终制备出聚合度为 2 ,4 ,6 ,8,10 ,12的寡糖纯品。寡糖纯度采用 SAX- HPL C,毛细管电泳 (CE)以及聚丙烯酰胺凝胶电泳(PAGE)进行检验 ,结构采用电喷雾离子化质谱 (ESI- MS)以及核磁共振波谱 (NMR)技术确定     

The delineation of dyanmical characteristics of circulations and their changes in the surface,subsurface, mid-depth and deep layers of the westernmost part of the North Pacific

Configurational structure of ocean circulation in the westernmost part of the North Pacific and its time-vayring processes are revealted through the combination of various means of measurements, that is, the measurements of cross-channel voltage, velocity profile, deep-water velocity, water characteristics together with hydrographic observations. The layered structure of circulation and current bursts of 10 to 20 days are clearly shown as well as the departure of the Kuroshio velocity-field from geostrophy. As a major process which modify the density structure of circulation, an intensified generation of internal tides over the Izu Ridge is also treated.Special lecture presented by the recipient of the prize of the Ocenographic Society of Japan for 7 April 1995.     

Estimation of sea-bed conductivity and its influence upon velocity measurements with towed electrodes

A formula to determine an effective electric conductivity of channel-bed from measurements of water velocity, cross-channel potential difference and electric current-density is presented. The effective conductivity defined in this paper is the conductivity averaged over depth from channel-bed surface to a depth of the order comparable to a breadth of the channel. Effective conductivities for the Izu Island region and the Straits of Tsugaru are estimated as 2.2×10^–2 mhos/m and 6.0×10^–2 mhos/m, which are considerably large and very large, respectively, in comparison to most of those determined for several regions near England. High conductivities for these regions are consistent with the distribution of underground conductivity anomaly deduced from that of geomagnetic field anomaly observed at the earth's surface in Japan. An influence of underground conductivity upon measurements of sea surface water velocity with towed electrodes is estimated for the regions.     

Density,biomass and community structure of demersal fishes off the Pacific coast of northeastern Japan

Demersal fish communities were studied on the lower continental shelf and the upper continental slope along the Pacific coast of northeastern Japan. Species composition, number and weight of each species were examined based on otter trawl samples at 45 stations. Mean density and biomass of demersal fishes were 131 ha^–1 and 21 kg ha^–1, respectively. The ten most abundant species comprised of about 95% of total number and weight of overall catch indicating simple species composition. Gadiform fishesTheragra chalcogramma, Gadus macrocephalus andPhysiculus maximowiczi were the most important species by number, weight and frequency of occurrences, and three main community types represented by the three key species were recognized.Theragra-dominant community showed higher density and biomass, and lower diversity thanPhysiculus-dominant community did. Species diversity of demersal fish community was negatively correlated to density and biomass. Density and biomass of demersal fish community were high on the uppermost slope, and the high abundance resulted from low-diversity communities dominated byT. chalcogramma andG. macrocephalus.