Solid bitumens: an assessment of their characteristics, genesis, and role in geological processes

Familiar since antiquity, and subject in contemporary times to various characterization schemes, the exact nature of solid bitumen is not yet fully known. Bitumens have ‘random polymer-like’ molecular structures, are mobile as highly viscous fluids or were once fluids but have since turned into solids. Solid bitumens consist mainly of large moieties, of polyclyclic aromatic hydrocarbons, occasionally with finely admixed, fine-grained cryptocrystalline graphite. Solid bitumens are distinguished from kerogen, which is the syngenetic and generally finely dispersed particulate organic matter in sedimentary rock that virtually does not migrate following its deposition. Occurrences of solid bitumens are relevant to petroleum exploration as well as the search for, and evaluation of, a variety of metallic mineral deposits. Genesis of bitumen is in many cases linked to the thermal and hydrothermal history of organic matter in sedimentary rock. Apparently bitumen, or more specifically organic acids generated along with bitumen during diagenesis, may alter porosity of reservoir rocks or otherwise prepare the ground for ore deposition. Bitumen is also relatively sensitive to alteration processes, some of which, such as oxidative weathering, water leaching, biodegradation (contact) metamorphism and ionizing radiation may likewise affect its nature. Elemental composition of bitumen commonly reflects the nature of mineral deposits. Is is possible that in petroleum exploration, trace metal abundances of bitumen may eventually allow prediction of crude oil types and volumes anticipated from a given source rock? Beside transition elements, notably Ni and V, highly anomalous concentrations of U, Pt and Au occur in some solid bitumens. During the generation of petroleum from kerogen, the trend in δ¹³C is toward lighter values. The opposite seems to occur when liquid petroleum is subjected to thermal cracking (and /or related processes) yielding solid bitumen enriched in ¹³C, and isotopically light methane. In fact, except for deasphalting and possibly some irradiation processes, the result of thermal cracking, oxidation, water leaching, inspissation (drying) and bacterial degradation of crude oil is that lower molecular weight hydrocarbons are removed leaving bitumen residues enriched in aromatic hydrocarbons, heteroatomic compounds (NSO) and ¹³C. Such phenomena are relevant to bitumen paragenesis in petroleum reservoir rocks, to certain Phanerozoic occurrences of multiple generations of bitumens, and to bitumens in mineral deposits.     

High-temperature geothermal reservoir possibilities in Hungary

Theoretical studies have shown the possibility of high-temperature ('high enthalpy') geothermal reservoirs in the pre-Tertiary rocks at 4–5 km depth range within the Pannonian Basin. This expectation was proven by the hotwater/steam blowout of Fábiánsebestyén-4 borehole (16.12.85–31.1.86). Exploration efforts carried out during 1987–88 in the broad vicinity of the borehole proved that reservoirs of this type can be found with the combination of seismic reflection, silica-thermometry and magnetotelluric sounding methods. Deliberate prospection should be continued in all suitable areas within the basin, since high enthalpy reservoirs promise profitable operation of geothermal power stations.     

Radon variations in a Hungarian village

 A steady radon exhalation is assumed in most publications. In a village of North-East Hungary, however, high radon concentrations have been measured, differing strongly in neighbouring houses and varying in time, due to the interplay of geochemical phenomena. Received: 20 November 1995 · Accepted: 18 June 1996     

Effect of diffusion-thermal processes on the high-latitude topside ionosphere

We have studied the extent to which diffusion-thermal heat flow affects H⁺ temperatures in the high-latitude topside ionosphere. Such a heat flow occurs whenever there are H⁺?O⁺ relative drifts. From our study we have found that at high-latitudes, where H⁺ flows up and out of the topside ionosphere, diffusion-thermal heat flow acts to reduce H⁺ temperatures by 500–600 K at altitudes above about 900 km.     

The Distribution of Redox Sensitive Elements (U, As, Sb, V and Mo) along a River-Wetland-Lake System (Balaton Region, Hungary)

The distribution of redox sensitive elements (U, As,Sb, Mo and V) has been investigated in Lake Balatonand two man-made reservoirs (Lake Kis-Balaton-1 andKis-Balaton-2) built along the River Zala, the mainriver discharging into it. These elements underwentremoval in Lake Kis Balaton-2 (KB-2) during anoxicconditions (May and September).Similarities were found between the distributions ofdissolved As and Sb. Both elements had elevateddissolved concentrations in Lake Kis-Balaton-1 (KB-1)and in Lake Balaton in September. This increasedmobility could be due to a change of speciation (viareduction and the formation of methylated species).Such changes in speciation are well documented in theliterature and are generally enhanced during periodsof warmth and high primary productivity.Dissolved V and Mo distributions also showedsimilarities with higher concentrations in LakeBalaton than in other parts of the system.Although removal is not clearly detected from thedissolved concentrations, U, As, Sb and Mo aresignificantly enriched in the organic-rich sedimentsof Lake KB-1, while V is mainly associated with thealumino-silicate fraction. In Lake KB-1, theconcentrations of all elements in SPM (suspendedparticulate matter) are lower than in the depositedsediments (except for As) suggesting that enrichmentprocesses are occuring in the deposited sediments.Additionnally the cycling of As and Mo can be alsopartly controlled by uptake and scavenging processesin the water column, as suggested by the elevated Asand Mo concentrations observed in SPM seasonnally forAs in Lake KB-1 and at Z.mouth-1 station and for Mo atZ.mouth-1 station and Lake Balaton.     

COMPUTATIONAL GEOMETRY AND GEOGRAPHY *

New developments in computational geometry are applicable to geographic data processing. Computationally efficient procedures incorporating logarithmic searches over appropriate data structures, and other shortcuts, can yield important savings in computation time and data storage space. There are “fast”methods for two-dimensional problems such as point inclusion, nearest-neighbor and two-nearest-neighbors determination, and grid overlay. Worst-case analysis of algorithms provides useful performance bounds for the developers of geographic production software.     

A crustal suture and lineament in North Africa

A possible suture between an old craton in West Africa and the Arabian—Nubian shield is marked by a persistent zone of Phanerozoic weakness. This zone extends between the Nile and Niger deltas and passes through the Qattara embayment, along the Bahariya fault, through the Kufra basin, between the Tibesti and Jabal al Uwaynat massifs, through the Bahr el Ghazal and Lake Chad areas, and along the Benoue trough.     

Direct gravity formula for the Geodetic Reference System 1967

A Direct Gravity Formula, polynomial in latitude, has been obtained from the series expansion of the closed gravity formula of Somigliana by a telescoping procedure. The use of the 7 coefficient formula gives a result as accurate as the closed expression. With 6 coefficients it gives an order of magnitude better accuracy than that of the widely used Chebyshev approximation and with 5 coefficients a result that is accurate to better than that of the conventional form of computing theoretical gravity. The derived approximation is not only simpler than other forms, but also at least 11 and 17 times faster on the CDC CYBER 74 computer than the Chebyshev approximation and the closed gravity formula respectively. Contribution from the Earth Physics Branch N^o 720.