Gated communities of the Moscow green belt: newly segregated landscapes and the suburban Russian environment

The transition from the Soviet to the post-Soviet period in and near Moscow manifested itself in increasing production of segregated space both in the urban core and suburban areas outside of the beltway to accommodate the preferences of the new Russian business and governmental elite. This paper focuses on the residential single-family housing inside old and new settlements, which are frequently gated. Approximately 260 of such suburban communities have been developed within 30 km of the beltway during the past few years, of which a majority have some form of exclusion mechanism in place, typically tall solid fences, gates, closed-circuit video surveillance and guarded entry checkpoints. The difference in exclusivity varies from the most exclusive older communities inside Moscow Serebryany Bor enclave and Rublevskoe highway mansions to less exclusive new developments along Novorizkhskoe and Dmitrovskoe highways. Despite high rates of construction, based on sociological surveys in 2003, only about 11% of Russia’s upper class claimed to live in such new “cottages,” with the rest owning condos and luxury apartments in the inner city or older detached homes in villages and small towns. Therefore, not all the needs have been accommodated and more development is certain to take place. The environmental impact of such developments is profound. Based on preliminary LANDSAT image analysis, almost 22% of suburban “green belt” forested land within 30 km zone has been converted to new construction from 1991 to 2001. New construction is now focusing on the remaining fragments of natural vegetation, which will likely lower air quality and water quality available for the city. Ironically, the new developments advertise themselves as “clean and green” with massive investments in unnatural landscaping (seeded lawns, exotic shrubs, river and lake shore “improvements”). This investment highlights the well-known paradox of development in which people move out of town to live near nature, while destroying the wild nature they come to enjoy. “We left city for the weekend It was raining, saw no stars There were fences everywhere Our chiefs behind the bars.” Gennady Shpalikov     

Olivine in ultramafic lamprophyres: chemistry,crystallisation, and melt sources of Siberian Pre- and post-trap aillikites

We studied olivines from the Devonian pre-trap (the Ilbokich occurrence) and the Triassic post-trap (the Chadobets occurrence) carbonate-rich ultramafic lamprophyres (UMLs) in the southwestern portion of the Siberian craton. On the basis of detailed investigations of major, minor, and trace-element distributions, we have reconstructed the main processes that control the origins of these olivines. These include fractional crystallisation from melt, assimilation, and fractional crystallisation processes with orthopyroxene assimilation, melt-reaction diffusive re-equilibration, alkali enrichment, and CO₂ degassing of the melt. Furthermore, we inferred the composition of the sources of the primary UML melt and their possible correlations with proto-kimberlitic melts, as well as the influence of the Triassic Siberian plume on the composition of the lithospheric mantle. The main differences between olivines from the Ilbokich and the Chadobets aillikites were that the olivines from the former had more magnesium-rich cores (Mg# = 89.2?±?0.2), had Mg- and Cr-rich transition zones (Mg# = 89.7?±?0.2 and 300–500 ppm Cr), had lower Ni (up to 3100 ppm) and Li (1.4–1.5 ppm), and had higher B (0.8–2.6 ppm) contents, all at higher Fo values (90–86), relative to the olivines from the latter (Mg# = 88–75; 200–300 ppm Cr; up to 3400 ppm Ni; 1.4–2.4 ppm Li; 0.4–2.2 ppm B). The Siberian aillikite sources contained a significant amount of metasomatic material. Phlogopite-rich MARID-type veins provided the likely metasomatic component in the pre-trap Devonian Ilbokich aillikite source, whereas the Triassic Chadobets aillikitic post-trap melts were derived from a source with a significant carbonate component. A comparison of UML olivines with olivines from the pre-trap and post-trap Siberian kimberlites shows a striking similarity. This suggests that the carbonate component in the aillikitic source could have been produced by evolved kimberlite melts. The differences in the lithospheric metasomatic component that contributed to pre-trap and post-trap aillikitic melts can be interpreted as reflections of the thermal impact of the Siberian Traps, which reduced phlogopite-bearing metasomes within the southwestern Siberian sub-continental lithospheric mantle.     

Methane in the Sevastopol coastal area, Black Sea

Concentrations of dissolved methane in seawater and bottom sediments, as well as of methane emanating from gas seeps were measured at 18 stations including several small bays in the Sevastopol coastal area (Black Sea) during 2007–2008. Methane concentrations in surface waters ranged from 10 to 2,970 nmol l^?1, and correlated well with values recorded for sediments. Methane concentrations in the water column were influenced by water depth, as well as by air and water temperatures. In the spring and summer of 2008, in situ CH₄ saturation relative to air was in the range of 970–71,900%. Maximum saturation was in summer. CH₄ fluxes to the atmosphere from the Sevastopol coastal area were estimated to vary from 190 to 1,550 μmol m^?2 day^?1. Gas bubbles escaping from the seepages contained about 57 vol% methane. Radiocarbon dating of the methane revealed an age not exceeding 150 years, implying a biogenic origin.     

Shock metamorphism of plagioclase and amphibole (Experimental data)

The shock metamorphism of plagioclase and amphibole of various chemical compositions from amphibolite and granulite facies schists was studied in experiments with shock wave loading of samples in steel recovery ampoules of plane geometry. A maximum shock pressure was reached after a few circulations of waves in the sample (stepwise shock wave compression) and varied within 26–52 GPa. The recovered samples were examined by the methods of scanning electron microscopy and microprobe and X-ray phase analysis. It is established that an increase in the F, Ti, and K concentrations in amphibole and a decrease in the Ca concentration in plagioclase make these minerals more stable with respect to shock waves. It is shown that the migration of some chemical elements, starting already at the solid phase stage of transformation in plagioclase and amphibole, is intensified at the stage of melting. It is established that isotropization of plagioclase occurs through two different mechanisms. At relatively low pressures, it is caused by the fragmentation of substance at the microlevel and is accompanied by the formation of maskelynite, a typical mineral of meteorites and astrobleme rocks. At higher pressures, isotropization is associated with melting-induced amorphization.     

Structural evolution of the Ural–Tian Shan junction: A view from Karatau ridge,South Kazakhstan

The deformation history of the Late Palaeozoic Ural–Tian Shan junction is discussed for the example of the Karatau ridge in southern Kazakhstan. Three deformation events are recognized. The Late Carboniferous D1 event is characterized by Laramide-style thrust-and-fold structures on the southern margin of Kazakhstan with shortening in a NE–SW direction. The Latest Permian and Triassic D2 event is controlled by compression in an east–west direction, which reflects collisional deformation in the Urals. The main structures are submeridional folds and north–west-striking sinistral strike–slip faults. The Triassic D3 event with shortening in a north–south direction reflects collision of the Turan microcontinent against the southern margin of Kazakhstan. The main structures are north–west-striking dextral strike–slip faults. Our new data provides important clues for the reconstruction of pre-Cretaceous structures between the Urals and the Tian Shan.     

Rock transformations in spherically converging shock waves: Newly obtained experimental results

The paper presents a concise review of results obtained by studying shock metamorphism of polymineralic rocks with the application of spherical hermetically sealed recovery devices. Such experiments are proved to be able to reproduce principally important features of transformations detected in rocks from natural meteoritic craters (astroblemes). The experimental samples show subspherical concentric zones with different rock transformations, which are generally analogous to zones in natural astroblemes (listed in order from the centers of the spherical samples to their margins): fracturing, diaplectic transformations, selective and then complete melting, and finally, evaporation. However, the laboratory scale of the experiments and the absence of younger overprinted processes, which can obliterate impact transformations of rocks in nature, enable the researcher to reveal distinctive compositional, textural, and phase features of transformations induced in the rocks at increasing isentropic shock wave-induced loading. Data on the mobility of major elements in the course of impact metamorphism show that the type and certain features of the crystal structures of minerals are of paramount importance for the amorphization of the minerals or their shock wave-induced thermal decomposition. The crystal chemical control of mineral transformations was proved to be exerted at a number of levels. High-pressure phases identified in experiments with shock wave loading were determined to crystallize from melt or via a phase transition associated with the migration of elements.     

Phase transformations of enstatite in spherical shock waves

The analysis of available theoretical evaluations and experimental data reveals discrepancies and makes it possible to formulate the goals for the comprehensive study of the behavior of enstatite MgSiO₃ in shock isentropic waves of various scale and intensity. The paper presents the layout and results of an explosion experiment on the compression of an enstatite sphere with spherical shock waves and the subsequent recovery of the experimental material and its examination in discrete zones (along the sphere radius) that were produced by shock waves in the material. The latter were examined with the application of scanning electron microscopy, Raman spectroscopy, and X-ray diffraction analysis. The comparison of the systematic variations in the texture, chemistry, and phase composition of enstatite along the sphere radius with calculated pressure P(R, t) and temperature T(R, t) values led us to the following conclusions: enstatite starts melting on an isentrope upon pressure relief after shock wave compression at ?? _xx ?? 80 GPa and melts on the front of the spherically converging shock wave at ?? _xx ?? 160 GPa and T ?? 6300 K. Our laboratory experiments with shock waves were the world??s first in which enstatite was loaded with spherical converging shock isentropic waves and which provided evidence that shock wave-loaded MgSiO₃ shows certain morphological and mineralogical features never before detected in this mineral loaded with plane shock wave of smaller amplitude and duration. Goals are formulated for the further studying of shock wave-loaded materials, and the necessity is discussed for conducting an explosion experiment with a five to seven times greater spherical system in order to increase the duration of the shock wave loading impulse.     

The Kaidun meteorite: Composition and origin of inclusions in the metal of an enstatite chondrite clast

Abstract— Metal nodules are one of the major textural components of Kaidun sample #01.3.06 EH3-4. In terms of structure, the nodules are of three types: (1) globular, (2) zoned with a massive core and globular mantle, and (3) nodules with no internal structure. The size and composition of the globules in the nodules and grains of metal of the matrix are almost identical: no greater than 20 μm and Ni, 5.95; Si, 3.33 wt%. The nodules contain small (usually <5 μm) inclusions of SiO₂; albitic glass; enstatite; roedderite; and a mixture of SiO₂ and Na₂S₂. This is the first reported occurrence of a simple sulfide of an alkaline metal in nature. The formation of the inclusions appears to be related to condensation of material onto the surfaces of metal grains. The nodules appear to have formed by aggregation of separate grains (globules) of metal, with conservation of condensates on the grain surfaces as inclusions. The inclusions probably condensed over a significant temperature range from 1400 to 600 K. The aggregation of metal grains and formation of the nodules probably occurred simultaneously with condensation.     

Kimberlite age in the Arkhangelsk Province,Russia: Isotopic geochronologic Rb–Sr and <Superscript>40</Superscript>Ar/<Superscript>39</Superscript>Ar and mineralogical data on phlogopite

The paper reports detailed data on phlogopite from kimberlite of three facies types in the Arkhangelsk Diamondiferous Province (ADP): (i) massive magmatic kimberlite (Ermakovskaya-7 Pipe), (ii) transitional type between massive volcaniclastic and magmatic kimberlite (Grib Pipe), and (iii) volcanic kimberlite (Karpinskii-1 and Karpinskii-2 pipes). Kimberlite from the Ermakovskaya-7 Pipe contains only groundmass phlogopite. Kimberlite from the Grib Pipe contains a number of phlogopite populations: megacrysts, macrocrysts, matrix phlogopite, and this mineral in xenoliths. Phlogopite macrocrysts and matrix phlogopite define a single compositional trend reflecting the evolution of the kimberlite melt. The composition points of phlogopite from the xenoliths lie on a single crystallization trend, i.e., the mineral also crystallized from kimberlite melt, which likely actively metasomatized the host rocks from which the xenoliths were captured. Phlogopite from volcaniclastic kimberlite from the Karpinskii-1 and Karpinskii-2 pipes does not show either any clearly distinct petrographic setting or compositional differentiation. The kimberlite was dated by the Rb–Sr technique on phlogopite and additionally by the ⁴⁰Ar/³⁹Ar method. Because it is highly probable that phlogopite from all pipes crystallized from kimberlite melt, the crystallization age of the kimberlite can be defined as 376 ± 3 Ma for the Grib Pipe, 380 ± 2 Ma for the Karpinskii-1 pipe, 375 ± 2 Ma for the Karpinskii-2 Pipe, and 377 ± 0.4 Ma for the Ermakovskaya-7 Pipe. The age of the pipes coincides within the error and suggests that the melts of the pipes were emplaced almost simultaneously. Our geochronologic data on kimberlite emplacement in ADP lie within the range of 380 ± 2 to 375 ± Ma and coincide with most age values for Devonian alkaline–ultramafic complexes in the Kola Province: 379 ± 5 Ma; Arzamastsev and Wu, 2014). These data indicate that the kimberlite was formed during the early evolution of the Kola Province, when alkaline–ultramafic complexes (including those with carbonatite) were emplaced.     

Devonian ultramafic lamprophyre in the Irkineeva–Chadobets trough in the southwest of the Siberian Platform: Age,composition, and implications for diamond potential prediction

The results of geochronological, mineralogical, petrographical, and geochemical study of the Ilbokich ultramafic lamprophyre are reported. The specific features in the mineral and chemical compositions of the studied ultramafic lamprophyre indicate that it can be regarded as a variety similar to aillikite, while other differences dominated by K-feldspar can be referred to damtjernite. According to Rb–Sr analysis, ultramafic lamprophyre dikes intruded at the turn of the Early and Middle Devonian, about 392 Ma ago. This directly proves the existence of Early Paleozoic alkali–ultramafic magmatism in the northern part of the southwest Siberian Platform. A finding of Devonian alkali–ultramafic lamprophyre is of dual predictive importance. On the one hand, it is indicative of the low probability of finding large diamond-bearing deposits in close association with aillikite. On the other hand, it can be indicative of a possible large Devonian diamond province in the studied territory, where diamondiferous kimberlite is structurally separated from aillikite.