The alkali element K is moderately volatile and fluid mobile; thus, it can be influenced by both primary processes (evaporation and recondensation) in the solar nebula and secondary processes (thermal and aqueous alteration) in the parent body. Since these primary and secondary processes would induce different isotopic fractionations, K isotopes could become a potential tracer to distinguish them. Using recently developed methods with improved precision (0.05‰, 95% confidence interval), we systematically measured the K isotopic compositions and major/trace elemental compositions of chondritic components (18 chondrules, 3 CAIs, 2 matrices, and 5 bulks) in the carbonaceous chondrite fall Allende. Among all the components analyzed in this study, CAIs, which formed initially under high‐temperature conditions in the solar nebula and were dominated by nominally K‐free refractory minerals, have the highest K2O content (average 0.53 wt%) and have K isotope compositions most enriched in heavy isotopes (δ41K: ?0.30 to ?0.25‰). Such an observation is consistent with previous petrologic studies that show CAIs in Allende have undergone alkali enrichment during metasomatism. In contrast, chondrules contain lower K2O content (0.003–0.17 wt%) and generally lighter K isotope compositions (δ41K: ?0.87‰ to ?0.24‰). The matrix and bulks are nearly identical in K2O content and K isotope compositions (0.02–0.05 wt%; δ41K: ?0.62 to ? 0.46‰), which are, as expected, right in the middle of CAIs and chondrules. This strongly indicates that most of the chondritic components of Allende suffered aqueous alteration and their K isotopic compositions are the ramification of Allende parent‐body processing instead of primary nebular signatures. Nevertheless, we propose the small K isotope fractionations observed (< 1‰) among Allende components are likely similar to the overall range of K isotopic fractionation that occurred in nebular environment. Furthermore, the K isotope compositions seen in the components of Allende in this study are consistent with MC‐ICP‐MS analyses of the components in ordinary chondrites, which also show an absence of large (10‰) isotope fractionations. This is not expected as evaporation experiments in nebular conditions suggest there should be large K isotopic fractionations. Nevertheless, possible nebular processes such as chondrules back exchanging with ambient gas when they formed could explain this lack of large K isotopic variation. 相似文献
The factors affecting permeability change under repeated mining of coal seams are important study aspects that need to be explored. This study combined various stress variation characteristics of protective seam mining and simplified the stress path of repeated mining in protective seam mines. Based on the results from the bespoke gas flow and displacement testing apparatus, seepage tests for simulated repetitive mining were carried out. The results simulated the actual behavior very well. With any drastic increase in the mining influence, the axial deviation stress in the stress path increased, and the greater the difference in coal permeability during the unloading and stress recovery stage, the more substantial the increase in permeability. The change in coal permeability was significantly influenced by the severity of simulated repeated mining cycles. When the mining stress exceeded a critical value, the permeability of the coal sample increased with the increase in the number of loading and unloading cycles, but the reverse was true when the mining stress was lower than the critical value. The effective sensitivity of seepage to the applied stress decreased with an increase in the number of stress cycles. With a decrease in the deviation stress, that is, with lower severity of mining influence, the effective sensitivity of coal seepage to stress gradually decreased.
Natural Resources Research - Identification of geochemical anomalies is of particular importance for tracing the footprints of anomalies. This can be implemented by advanced techniques of... 相似文献
Natural Resources Research - In the past few decades, a variety of data-driven predictive modeling techniques has led to a dramatic advancement in mineral prospectivity mapping (MPM). The random... 相似文献
This paper applied a logistic-based fuzzy logic inference system to integrate critical factors that could control orogenic gold mineralization in part of the Kushaka schist belt, north-central Nigeria to develop a process-based mineral potential mapping (MPM) of the area. The critical factors from geophysical and geological dataset were weighted using logistic functions. The fuzzy logic inference system provides the capability to handle complex geological processes that culminated in orogenic gold mineralization as well as minimizing systemic uncertainties/fuzziness that often plague MPM. The results of this work show that granitic intrusions with fuzzy scores of 0.67–0.90 played a major role in generating high geothermal gradient in the area. Seventy percent of the existing gold mine sites in the area spatially coincide with metasedimentary rocks, having fuzzy scores of 0.7–0.9; this suggests metasedimentary rocks as being responsible for the production of gold fluid and ligands in the area. The evidence of hydrothermal activity, with fuzzy scores of 0.53 and 0.91, confirms the occurrence of mineralization associated with quartz veins and granite rocks. Lithological contacts and faults, having fuzzy scores of 0.60–0.80, presumably contribute to the localization of orogenic gold mineralization in the area. Emerging from the results, favorable zones for primary orogenic gold mineralization in the area occurred predominantly on granite gneiss and quartz veins. The mineral potential map was found consistent with the local geology, structural styles and hydrothermal alteration signatures in the area, and its validation using the existing locations of geochemical anomalies and prediction–area rate curve in the study area showed 75 and 72% agreement, respectively, thus confirming the reliability of the developed mineral potential map for resource management.
Natural Resources Research - This study tested and compared the mineral potential mapping capabilities of the random forest (RF) and maximum entropy (MaxEnt) algorithms using gold deposit... 相似文献