An aromatase inhibitor and tamoxifen decrease plasma levels of o,p'-DDT and its metabolites in Nile tilapia (Oreochromis niloticus)

The objective of this study was to determine if tamoxifen or an aromatase inhibitor (4-hydroxyandrostenedione; 4-OHA) affected plasma concentrations of o,p' -DDT and its metabolites, o,p'-DDD and o,p'-DDE, in mature tilapia. Male and female tilapia were injected 6 times intraperitoneally with o,p'-DDT (40 mg/kg) alone or in combination with 4-OHA (2 mg/kg) over a 12 day period. An additional group of male fish was injected with tamoxifen (5 mg/kg) plus o,p'-DDT. At the end of the treatment period, plasma samples were extracted and analyzed by GC/ECD. Females injected only with o,p'-DDT had significantly higher levels of o,p'-DDT compared with males. Interestingly, females and males treated concomitantly with o,p'-DDT and 4-OHA or tamoxifen had significantly lower concentrations of plasma o,p'-DDT (about 50%) compared with fish treated with only o,p'-DDT. These initial results suggest that an interaction between endocrine-active compounds occurs in vivo in tilapia and may involve alterations in metabolism of o,p'-DDT.     

A gravitational kinetic theory for planetesimals

An analytical theory is developed for the velocity evolution of nonaccreting planetesimal populations, based on the Boltzmann and Fokker-Planck equations. Adapting Shkarofsky's calculation of plasma viscosities, the rate of increase in random velocities due to gravitational encounters between planetesimals of equal mass is found to be one-third to one-half Safronov's result. Comparison with Wetherill's numerical experiments suggests that the Fokker-Planck equation underestimates the effectiveness of encounters and that Safronov's value is approximately correct. For populations of nonuniform sizes, the Fokker-Planck equation indicates an efficient redistribution of energy from the largest bodies to the smaller ones. By conserving angular momentum, the rate of radial spreading of orbits is also derived.     

Spectral Simulation and Conditioning to Local Continuity Trends in Geologic Modeling

Spectral simulation has gained application in building geologic models due to the advantage of better honoring the spatial continuity of petrophysical properties, such as reservoir porosity and shale volume. Distinct from sequential simulation methods, spectral simulation is a global algorithm in the sense that a global density spectrum is calculated once and the inverse Fourier transform is performed on the Fourier coefficient also only once to generate a simulation realization. The generated realizations honor the spatial continuity structure globally over the whole field instead of only within a search neighborhood, as with sequential simulation algorithms. However, the disadvantage of global spectral simulation is that it traditionally cannot account for the local information such as the local continuity trends, which are often observed in reservoirs and hence are important to be accounted for in geologic models. This disadvantage has limited wider application of spectral simulation in building geologic models. In this paper, we present ways of conditioning geologic models to the relevant local information. To account for the local continuity trends, we first scale different frequency components of the original model with local-amplitude spectrum ratios that are specific to the local trend. The sum of these scaled frequency components renders a new model that displays the desired local continuity trend. The implementation details of this new method are discussed and examples are provided to illustrate the algorithm.     

Origin of iodine in volcanic fluids: I results from the Central American Volcanic Arc

The largest reservoir of crustal iodine is found in marine sediments, where it is closely associated with organic material. This presence, together with the existence of a long-lived, cosmogenic radioisotope ¹²⁹I (t_1/2 = 15.7 Ma), make this isotopic system well suited for the study of sediment recycling in subduction zones. Reported here are the results of ¹²⁹I/I ratios in volcanic fluids, collected during a comprehensive study of fluids and gases in the Central American Volcanic Arc. ¹²⁹I/I ratios, together with I, Br, and Cl concentrations, were determined in 79 samples from four geothermal centers and a number of crater lakes, fumaroles, hot springs, and surface waters in Costa Rica, Nicaragua, and El Salvador. Geothermal and volcanic fluids were found to have iodine concentrations substantially higher than values in seawater or meteoric waters. ¹²⁹I/I ratios in most of the geothermal fluids are below the preanthropogenic input ratio of 1500 × 10⁻¹⁵, demonstrating that recent anthropogenic additions are largely absent from the volcanic systems. The majority of the ¹²⁹I/I ratios are between 500 and 800 × 10⁻¹⁵. These ratios indicate minimum iodine ages between 25 and 15 Ma, in good agreement with the age of subducted sediments in this region. In all four geothermal systems, however, a few samples were found with iodine ages older than 40 Ma—that is, considerably below the expected age range for subducted sediments from the Cocos Plate. These samples probably reflect the presence of iodine derived from sediments in older accreted oceanic terraines. The iodine ages indicate that the magmatic end member for the volcanic fluids originates in the deeper parts of the subducted sediment column, with small additions from older iodine mobilized from the overlying crust. The high concentrations of iodine in geothermal fluids, combined with the observed iodine ages, demonstrate that remobilization in the main volcanic zone (and probably also in the forearc area) is an important part in the overall marine cycle of iodine and similar elements.     

Targeting carbon dioxide removal in the European Union

In principle, many climate policymakers have accepted that large-scale carbon dioxide removal (CDR) is necessary to meet the Paris Agreement’s mitigation targets, but they have avoided proposing by whom CDR might be delivered. Given its role in international climate policy, the European Union (EU) might be expected to lead the way. But among EU climate policymakers so far there is little talk on CDR, let alone action. Here we assess how best to ‘target’ CDR to motivate EU policymakers exploring which CDR target strategy may work best to start dealing with CDR on a meaningful scale. A comprehensive CDR approach would focus on delivering the CDR volumes required from the EU by 2100, approximately at least 50 Gigatonnes (Gt) CO₂, according to global model simulations aiming to keep warming below 2°C. A limited CDR approach would focus on an intermediate target to deliver the CDR needed to reach ‘net zero emissions’ (i.e. the gross negative emissions needed to offset residual positive emissions that are too expensive or even impossible to mitigate). We argue that a comprehensive CDR approach may be too intimidating for EU policymakers. A limited CDR approach that only addresses the necessary steps to reach the (intermediate) target of ‘net zero emissions’ is arguably more achievable, since it is a better match to the existing policy paradigm and would allow for a pragmatic phase-in of CDR while avoiding outright resistance by environmental NGOs and the broader public.

Key policy insights

• Making CDR an integral part of EU climate policy has the potential to significantly reshape the policy landscape.

• Burden sharing considerations would probably play a major role, with comprehensive CDR prolonging the disparity and tensions between progressives and laggards.

• Introducing limited CDR in the context of ‘net zero’ pathways would retain a visible primary focus on decarbonization but acknowledge the need for a significant enhancement of removals via ‘natural’ and/or ‘engineered’ sinks.

• A decarbonization approach that intends to lead to a low level of ‘residual emissions’ (to be tackled by a pragmatic phase-in of CDR) should be the priority of EU climate policy.

     

Refining accretionary orogen models for the Tasmanides of eastern Australia

The well-known southwest-to-northeast younging of stratigraphy over a present-day cross strike distance of >1500 km in the southern Tasmanides of eastern Australia has been used to argue for models of accretionary orogenesis behind a continually eastwards-rolling paleo-Pacific plate. However, these accretionary models need modification, since the oldest (ca 530 Ma) outcrops of Cambrian supra-subduction zone rocks occur in the outboard New England Orogen, now ～900 km east of the next oldest (520–510 Ma) supra-subduction zone rocks. This is not consistent with simple, continuous easterly rollback. Instead, the southern Tasmanides contain an early history characterised by a westwards-migrating margin between ca 530 and ca 520 Ma, followed by rapid eastwards rollback of the paleo-Pacific plate from 520 to 502 Ma that opened a vast backarc basin ～2000 km across that has never been closed. From the Ordovician through to the end of the Carboniferous, the almost vertical stacking of continental margin arcs (within a hundred kilometres of each other) in the New England Orogen indicates a constant west-dipping plate boundary in a Gondwana reference frame. Although the actual position of the boundary is inferred to have undergone contraction-related advances and extension-related retreats, these movements are estimated to be ～250 km or less. Rollback in the early Permian was never completely reversed, so that late Permian–Triassic to Cretaceous arcs lie farther east, in the very eastern part of eastern Australia, with rifted fragments occurring in the Lord Howe Rise and in New Zealand. The northern Tasmanides are even more anomalous, since they missed out on the middle Cambrian plate boundary retreat seen in the south. As a result, their Cambrian-to-Devonian history is concentrated in a ～300 km wide strip immediately west of Precambrian cratonic Australia and above Precambrian basement. The presence in this narrow region of Ordovician to Carboniferous continental margin arcs and backarc basins also implies a virtually stationary plate boundary in a Gondwana frame of reference. This bipolar character of the Tasmanides suggests the presence of a segmented paleo-Pacific Plate, with major transform faults propagating into the Tasmanides as tear faults that were favourably oriented for the formation of local supra-subduction zone systems and for subsequent intraplate north–south shortening. In this interpretation of the Tasmanides, Lower–Middle Ordovician quartz-rich turbidites accumulated as submarine fan sequences, and do not represent multiple subduction complexes developed above subduction zones lying behind the plate boundary. Indeed, the Tasmanides are characterised by the general absence of material accreted from the paleo-Pacific plate and by the dominance of craton-derived, recycled sedimentary rocks.     

Crustal structure of the Ordovician Macquarie Arc,Eastern Lachlan Orogen,based on seismic‐reflection profiling

In the Eastern Lachlan Orogen, the mineralised Molong and Junee‐Narromine Volcanic Belts are two structural belts that once formed part of the Ordovician Macquarie Arc, but are now separated by younger Silurian‐Devonian strata as well as by Ordovician quartz‐rich turbidites. Interpretation of deep seismic reflection and refraction data across and along these belts provides answers to some of the key questions in understanding the evolution of the Eastern Lachlan Orogen—the relationship between coeval Ordovician volcanics and quartz‐rich turbidites, and the relationship between separate belts of Ordovician volcanics and the intervening strata. In particular, the data provide evidence for major thrust juxtaposition of the arc rocks and Ordovician quartz‐rich turbidites, with Wagga Belt rocks thrust eastward over the arc rocks of the Junee‐Narromine Volcanic Belt, and the Adaminaby Group thrust north over arc rocks in the southern part of the Molong Volcanic Belt. The seismic data also provide evidence for regional contraction, especially for crustal‐scale deformation in the western part of the Junee‐Narromine Volcanic Belt. The data further suggest that this belt and the Ordovician quartz‐rich turbidites to the east (Kirribilli Formation) were together thrust over ?Cambrian‐Ordovician rocks of the Jindalee Group and associated rocks along west‐dipping inferred faults that belong to a set that characterises the middle crust of the Eastern Lachlan Orogen. The Macquarie Arc was subsequently rifted apart in the Silurian‐Devonian, with Ordovician volcanics preserved under the younger troughs and shelves (e.g. Hill End Trough). The Molong Volcanic Belt, in particular, was reworked by major down‐to‐the‐east normal faults that were thrust‐reactivated with younger‐on‐older geometries in the late Early ‐ Middle Devonian and again in the Carboniferous.     

A method for constructing toxic waste site histories from old airphotos of coastal regions

Archive aerial photos have been used to create a skeletal history for several toxic waste sites currently under investigation in the United States. Because many of the sites are very small in area, and the majority of the historical aerial photography is not large scale, specialized methods have, through experience, been developed to do this work. The result of the work is a series of standard format film stereograms and a detailed report. The report includes several unique methods for presenting the airphoto findings.     

Experimental determination of the chromium-aluminum mixing parameter in garnet

The equilibrium Grossular + Quartz = Anorthite + 2 Wollastonite was used to obtain the mixing properties of Cr and Al in grossular-uvarovite solid solutions by determining displacement of the univariant boundary curve for measured values of $\text{x}{}_{\mathrm{gross}}{}^{\mathrm{gt}}$. Experiments were performed in a piston cylinder apparatus with initial garnet compositions Gr₁₀₀, Gr₈₀Uv₅₀, Gr₅₀Uv₅₀, and Gr₂₀Uv₈₀. Reversals were obtained in the temperature range 1040°C–1320°C and corrected pressure range 10–17 kbar. Results indicate that grossular-uvarovite solutions can be modeled as nearly ideal two-site solid solutions. W_G^Cr,Al of +200 to + 1000 cal/mole is consistent with our experimental results.     

Lead in corals: reconstruction of historical industrial fluxes to the surface ocean

Twentieth century environmental lead chronologies for the western North Atlantic, Pacific, and Indian Oceans have been reconstructed from annually-banded scleractinian corals. Measurements of lattice-bound Pb in sequential coral bands reveal temporal changes in surface water Pb concentrations and Pb isotopic distributions. Perturbations are observable in all specimens studied, attesting to global augmentation of environmental Pb by industrialization.In the western North Atlantic, Pb perturbations have occurred in direct response to the American industrial revolution and the subsequent introduction and phasing-out of alkyl Pb additives in gasoline. Surface ocean conditions near Bermuda may be reliably reconstructed from the coral data via a lead distribution coefficient of 2.3 for the species,Diploria strigosa. Based on²¹⁰Pb measurements, a similar distribution coefficient may be characteristic of corals in general. Surface Pb concentrations in the pre-industrial Sargasso Sea were about 15–20 pM. Concentrations rose to near 90 pM by 1923 as a result of metals manufacture and fossil fuel combustion. Beginning in the late 1940's, increased utilization of leaded gasoline eventually led to a peak concentration of 240 pM in 1971, representing an approximate 15-fold increase over background. Surface ocean concentrations are presently declining rapidly (128 pM in 1984) as a result of curtailed alkyl Pb usage. Lead isotopic shifts parallel the concentration record indicating that characteristic industrial and alkyl Pb source signatures have not changed appreciably in time. Industrial releases recorded in the Florida Keys reflect a weaker source and evidence of recirculated Pb (5–6 years old) from the North Atlantic subtropical gyre. An inferred background concentration of 38 pM suggests influence of shelf and/or resuspended inputs of Pb to these coastal waters.In remote areas of the South Pacific and Indian Oceans, industrial signals are fainter and the corals studied much younger than their Atlantic counterparts. Contemporary Pb concentrations implied by coral measurements (assumingK_D = 2.3) are 40–50 pM for surface waters near Tutuila and Galapagos in the South Pacific, and 25–29 pM near Mauritius in the Indian Ocean. A single coral band from Fiji (1920 ± 5yr) implies a pre-industrial surface water concentration of 16–19 pM Pb for the South Pacific. In view of reported surface water measurements and the North Atlantic coral data, the Pacific coral extrapolations may be slightly high. This could be a result of small variations inK_D among different coral genera, or incorporation of diagenetic Pb by corals sampled in coastal environments.