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排序方式: 共有93条查询结果,搜索用时 468 毫秒
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Qian Y Engel MH Macko SA Carpenter S Deming JW 《Geochimica et cosmochimica acta》1993,57(14):3281-3293
Dipeptide hydrolysis and amino acid decomposition appear to follow a first-order rate law. The hydrolysis rate increases exponentially with increasing temperature in aqueous solution at both 265 atm and water steam pressures over the temperature range of 100 to 220 degrees C. Dipeptide hydrolysis has a lower apparent activation energy at 265 atm (44.1 KJ/mol) than at water steam pressure (98.9 KJ/mol). At lower temperatures (<200-220 degrees C), the rate of peptide bond hydrolysis is faster at 265 atm than at water steam pressure. At higher temperatures (>200-220 degrees C), however, peptide bond hydrolysis is slower at 265 atm than at water steam pressure. In aqueous solution, amino acid decomposition rates also increase exponentially with increasing temperature. Amino acid decomposition rates are much higher at 265 atm than at water steam pressure over the entire temperature range investigated. 相似文献
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内蒙古喀喇沁早白垩世橄辉云煌岩岩筒 总被引:2,自引:0,他引:2
探寻地幔物质上涌的通道口,是大陆岩石圈研究所感兴趣的,它将为人们提供更多的岩石圈深部信息。本文报道的是在内蒙古喀喇沁黑龙潭火山颈中发现的橄辉云煌岩,其K-Ar同位素年龄为124Ma。火山活动明显受到中生代构造活动控制。火山岩的元素地球化学特征反映岩浆来自富集地幔,在源区存在陆壳的混染作用。 相似文献
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对于具有限混溶或原子有序分布的简单二元固溶体来说,已结合其自由能曲线来预测一种体系的相关系和出溶机理。有序过程的特征影响着出溶机理的适用性.如果有序化作用是二步(较高)有序时,则整个过程以连续机理占优势,而所描述的一种“条件旋节分解”(“Conditional spinodal”)(Allen 和 Cahni 1976)只有对序与无序端员组分之间起着决定作用.对于一步有序来说,有序相仅能经成核与生长来沉淀无序相.用透射电子显微镜所观察到的绿辉石徼细结构包括出溶页片和反相晶畴,并且在所选择的样品中它们之间的关系已用于解释地质条件下起控制作用的出溶机理。绝大多数绿辉石几乎都经历了阳离子的有序过程,然后保持均一体,或通过旋节分解作用出溶一种无序辉石。连续出溶机理占优势已用来说明 C2/c→P2/n 转换可以是二步(较高)有序的.现已提供了一种硬玉——普通辉石的可能相图,它是以这种理论为基础的,即在低温下无序端员组分之间应该是有限混溶的,而中间成分(绿辉石)的阳离子是有序的,两者迭加在一条溶相线上。这就完全解释了观察到的许多微细结构,并与在含杂质硬玉和绿辉石之间、绿辉石和钠辉石之间存在宽阔二相区的岩相学证据相符合。加入锥辉石所产生的影响类似于增温效应,所以,也就能够预测硬玉——锥辉石——普通辉石的相关系。 相似文献
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An index of biotic integrity based on the summer polyhaline zooplankton community of the Chesapeake Bay 总被引:1,自引:0,他引:1
A zooplankton index of biotic integrity was developed for the polyhaline waters of the Chesapeake Bay using data from a long-term environmental assessment program in which both zooplankton and water quality were regularly monitored. Summer (July to September) sampling events were classified as either coming from impaired or reference (least-impaired) conditions based on water quality conditions. Seventeen zooplankton community metrics were evaluated under these criteria and nine were chosen for a composite index. These were the Simpson diversity index, and abundance of barnacle larvae, rotifers, cladocerans, copepods, total mesozooplankton, and predators. The composite index of biotic integrity correctly classified about 94% of the impaired samples and about 82% of the reference samples. Average classification efficiency was 88%. This index appears to be an effective measure of eutrophication for the summer polyhaline waters of the Chesapeake Bay ecosystem. 相似文献
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A whole-core injection method was used to determine depth-related rates of microbial mineralization of (14)C-phenanthrene added to both contaminated and clean marine sediments of Puget Sound, WA. For 26-day incubations under micro-aerobic conditions, conversions of (14)C-phenanthrene to (14)CO(2) in heavily PAH-contaminated sediments from two sites in Eagle Harbor were much higher (up to 30%) than those in clean sediments from nearby Blakely Harbor (<3%). The averaged (14)C-phenanthrene degradation rates in the surface sediment horizons (0-3 cm) were more rapid (2-3 times) than in the deeper sediment horizons examined (>6 cm), especially in the most PAH polluted EH9 site. Differences in mineralization were associated with properties of the sediments as a function of sediment depth, including grain-size distribution, PAH concentration, total organic matter and total bacterial abundance. When strictly anaerobic incubations (in N(2)/H(2)/CO(2) atmosphere) were used, the phenanthrene biodegradation rates at all sediment depths were two times slower than under micro-aerobic conditions, with methanogenesis observed after 24 days. The main rate-limiting factor for phenanthrene degradation under anaerobic conditions appeared to be the availability of suitable electron acceptors. Addition of calcium sulfate enhanced the first order rate coefficient (k(1) increased from 0.003 to 0.006 day(-1)), whereas addition of soluble nitrate, even at very low concentration (<0.5 mM), inhibited mineralization. Long-term storage of heavily polluted Eagle Harbor sediment as intact cores under micro-aerobic conditions also appeared to enhance anaerobic biodegradation rates (k(1) up to 0.11 day(-1)). 相似文献
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在过去的82年(1931—2013)中,共出现了39个成因术语。在这39个术语中,只有10个是真正沉积成因的(例如浊积岩),其他29个术语都是比较草率地提出的(just jargons;例如地震岩、海啸岩等)。“地震岩”(seismites)这一成因术语是赛拉赫(Seilacher,1969)提出的,它指沉积记录中的古地震。这是一个误用的(misnomer)术语。赛拉赫仅仅根据美国加利福尼亚州的中新统蒙特雷组(Miocene Montery Formation)10,m厚的露头观察,就匆忙地提出这个术语。他并未对这个露头进行认真的科学研究。最根本的问题是,地震是一个触动因素①,并不是一个沉积作用。在古代的沉积记录中,鉴别不出各种触动因素(trigger)②,因为自然界不能保留触动因素曾经存在过的证据。“软沉积物变形构造”(soft-sediment deformation structures,可简称为SSDS),通常被人们用来作为地震岩的鉴别标志,其实它是“液化作用”(liquefacation)的结果。液化作用可以由21种触动因素中的任何一种引起,其中包括地震(earthquake)、陨石冲击(meteorite impact)、海啸(tsunami)、沉积负载(sediment loading)等。在死海盆地中的角砾碎屑,所谓典型的由地震引起的沉积,实际上是常见的同沉积作用的碎屑流的产物,与地震没有关系。其他类型的SSDS,例如 “双向叠层构造”(duplex-like structures)和碎屑注入体(clastic injections),也可以说是同沉积作用的产物,与地震没有关系。世界上广泛分布的砂岩储油层,包括墨西哥湾、北海、挪威海、尼日利亚、赤道几内亚、加逢、孟加拉湾,都表明这些地区的SSDS的第一起因(primary cause)是沉积负载,其证据是可以观察到的和令人信服的。海啸及陨石冲击,都可以形成大量的沉积,例如SSDS的侧向延伸(lateral extent of SSDS),但这些沉积都不能当作地震的鉴别标志。位于印度东部大陆边缘的Krishna-Godavari(KG)盆地中的SSDS,是多种触动因素①引起的沉积物的失控和液化作用的结果,即多成因的SSDS。由于这些原因,“地震岩”这个成因术语确实没有什么科学价值,应当废弃。 相似文献