Experimental partitioning of trace elements into schreibersite with applications to IIG iron meteorites

Some of the defining characteristics of the IIG iron meteorite group are their high bulk P contents and massive, coarse schreibersite, which have been calculated to make up roughly 11–14 wt% of each specimen. In this study, we produced two data sets to investigate the formation of schreibersites in IIG irons: measurements of trace elements in the IIG iron meteorite Twannberg and experimental determinations of trace element partitioning into schreibersite. The schreibersite‐bearing experiments were conducted with schreibersite in equilibrium with a P‐rich melt and with bulk Ni contents ranging from 0 to 40 wt%. The partitioning behavior for the 20 elements measured in this study did not vary with Ni content. Comparison of the Twannberg measurements with the experimental results required a correction factor to account for the fact that the experiments were conducted in a simplified system that did not contain a solid metal phase. Previously determined solid metal/P‐rich melt partition coefficients were applied to infer schreibersite/solid metal partitioning behavior from the experiments, and once this correction was applied, the two data sets showed broad similarities between the schreibersite/solid metal distribution of elements. However, there were also differences noted, in particular between the Ni and P contents of the solid metal relative to the schreibersite inferred from the experiments compared to that measured in the Twannberg sample. These differences support previous interpretations that subsolidus schreibersite evolution has strongly influenced the Ni and P content now present in the solid metal phase of IIG irons. Quantitative attempts to match the IIG solid metal composition to that of late‐stage IIAB irons through subsolidus schreibersite growth were not successful, but qualitatively, this study corroborates the striking similarities between the IIAB and IIG groups, which are highly suggestive of a possible genetic link between the groups as has been previously proposed.     

乌鲁木齐大气混合层厚度和稳定度与大气污染的关系

利用乌鲁木齐市4座10层100 m梯度气象塔2013年6月~2014年4月气象观测资料和7个环境监测站[WTBX]AQI[WTBZ]资料，计算并分析了大气混合层厚度和稳定度特征，探讨了大气混合层厚度和稳定度与污染的关系。结果表明：乌鲁木齐市混合层厚度夏季郊区高、城区低，冬季从南郊—城区—北郊随地势降低依次降低；夏季和冬季分别在1 559～1 772 m和526～1 156 m之间。地面至2 km以上每500 m高度间隔统计混合层厚度，500～1 000 m出现频率最多；月变化为6～9月基本在500 m以上，且每个高度区间其概率均超过10%，10月～次年2月1 500 m以上区间概率明显减小；日变化为中午13:00～16:00达到最高值，下午和傍晚迅速下降。白天较大的感热输送提供充足的热力条件，这也体现出白天以不稳定层结为主，夜间则以稳定层结为主。大气稳定度分类结果，夏季郊区和城区不稳定（A～C类）所占比例差不多，冬季北郊稳定（E、F类）所占比较最大、城区最弱。[WTBX]AQI指数冬季最大，从南郊—城区—北郊依次增大，这与采暖期污染物多、南郊比北郊地势高有利于扩散输送有关。总体来看，乌鲁木齐大气混合层厚度空间分布与气象要素、大气稳定度、地形等密切相关，对AQI[WTBZ]指数分布有重要影响，这对近地层大气污染状况预报有着重要的指导意义。     

Creating an isotopically similar Earth–Moon system with correct angular momentum from a giant impact

The giant impact hypothesis is the dominant theory explaining the formation of our Moon. However, the inability to produce an isotopically similar Earth–Moon system with correct angular momentum has cast a shadow on its validity. Computer-generated impacts have been successful in producing virtual systems that possess many of the observed physical properties. However, addressing the isotopic similarities between the Earth and Moon coupled with correct angular momentum has proven to be challenging. Equilibration and evection resonance have been proposed as means of reconciling the models. In the summer of 2013, the Royal Society called a meeting solely to discuss the formation of the Moon. In this meeting, evection resonance and equilibration were both questioned as viable means of removing the deficiencies from giant impact models. The main concerns were that models were multi-staged and too complex. We present here initial impact conditions that produce an isotopically similar Earth–Moon system with correct angular momentum. This is done in a single-staged simulation. The initial parameters are straightforward and the results evolve solely from the impact. This was accomplished by colliding two roughly half-Earth-sized impactors, rotating in approximately the same plane in a high-energy, off-centered impact, where both impactors spin into the collision.     

Wetland hydroperiod classification in the western prairies using multitemporal synthetic aperture radar

Wetlands represent one of the world's most biodiverse and threatened ecosystem types and were diminished globally by about two‐thirds in the 20th century. There is continuing decline in wetland quantity and function due to infilling and other human activities. In addition, with climate change, warmer temperatures and changes in precipitation and evapotranspiration are reducing wetland surface and groundwater supplies, further altering wetland hydrology and vegetation. There is a need to automate inventory and monitoring of wetlands, and as a study system, we investigated the Shepard Slough wetlands complex, which includes numerous wetlands in urban, suburban, and agricultural zones in the prairie pothole region of southern Alberta, Canada. Here, wetlands are generally confined to depressions in the undulating terrain, challenging wetlands inventory and monitoring. This study applied threshold and frequency analysis routines for high‐resolution, single‐polarization (HH) RADARSAT‐2, synthetic aperture radar mapping. This enabled a growing season surface water extent hyroperiod‐based wetland classification, which can support water and wetland resource monitoring. This 3‐year study demonstrated synthetic aperture radar‐derived multitemporal open‐water masks provided an effective index of wetland permanence class, with overall accuracies of 89% to 95% compared with optical validation data, and RMSE between 0.2 and 0.7 m between model and field validation data. This allowed for characterizing the distribution and dynamics of 4 marsh wetlands hydroperiod classes, temporary, seasonal, semipermanent, and permanent, and mapping of the sequential vegetation bands that included emergent, obligate wetland, facultative wetland, and upland plant communities. Hydroperiod variation and surface water extent were found to be influenced by short‐term rainfall events in both wet and dry years. Seasonal hydroperiods in wetlands were particularly variable if there was a decrease in the temporary or semipermanent hydroperiod classes. In years with extreme rain events, the temporary wetlands especially increased relative to longer lasting wetlands (84% in 2015 with significant rainfall events, compared with 42% otherwise).     

Analytical study of ground motion caused by seismic wave propagation across faulted rock masses

Studying seismic wave propagation across rock masses and the induced ground motion is an important topic, which receives considerable attention in design and construction of underground cavern/tunnel constructions and mining activities. The current study investigates wave propagation across a rock mass with one fault and the induced ground motion using a recursive approach. The rocks beside the fault are assumed as viscoelastic media with seismic quality factors, Q_p and Q_s. Two kinds of interactions between stress waves and a discontinuity and between stress waves and a free surface are analyzed, respectively. As the result of the wave superposition, the mathematical expressions for induced ground vibration are deduced. The proposed approach is then compared with the existing analysis for special cases. Finally, parametric studies are carried out, which includes the influences of fault stiffness, incident angle, and frequency of incident waves on the peak particle velocities of the ground motions.     

Factors influencing biodeposit production by the New Zealand freshwater mussel Echyridella menziesii

Laboratory experiments on the New Zealand freshwater mussel Echyridella menziesii were used to investigate the short-term effects (7–8 days) of food type on rates of biodeposition and benthic substrate respiration. Post-feeding biodeposition rates ranged from 0.34 to 1.52?mg?g^?1?h^?1 (mean?=?0.50?mg g^?1?h^?1) and were unaffected by the addition of toxin-producing Microcystis. Addition of suspended sediment (30?mg?L^?1) visibly altered substrate composition, and increased total and inorganic biodeposit production rates by 24–33% compared to mussels fed commercial phytoplankton stock. Biodeposition rates of mussels in lake bed substrates were 38% higher than those in silica sand for identical feeding regimes, suggesting that a significant proportion of material produced in this experiment could have been derived from feeding on organic matter in the lake bed sediments. Respiration rates were higher in treatments with Microcystis but were unaffected by the presence of mussels. This laboratory study suggests that biodeposition by E. menziesii is resilient to short-term exposure to Microcystis, and highlights the ability of mussels to alter benthic substrate composition by incorporating suspended sediment into substrates.     

Estimating average shock pressures recorded by impactite samples based on universal stage investigations of planar deformation features in quartz—Sources of error and recommendations

Planar deformation features (PDFs) in quartz are the most widely used indicator of shock metamorphism in terrestrial rocks. They can also be used for estimating average shock pressures that quartz-bearing rocks have been subjected to. Here we report on a number of observations and problems that we have encountered when performing universal stage measurements and crystallographically indexing of PDF orientations in quartz. These include a comparison between manual and automated methods of indexing PDFs, an evaluation of the new stereographic projection template, and observations regarding the PDF statistics related to the c-axis position and rhombohedral plane symmetry. We further discuss the implications that our findings have for shock barometry studies. Our study shows that the currently used stereographic projection template for indexing PDFs in quartz might induce an overestimation of rhombohedral planes with low Miller–Bravais indices. We suggest, based on a comparison of different shock barometry methods, that a unified method of assigning shock pressures to samples based on PDFs in quartz is necessary to allow comparison of data sets. This method needs to take into account not only the average number of PDF sets/grain but also the number of high Miller–Bravais index planes, both of which are important factors according to our study. Finally, we present a suggestion for such a method (which is valid for nonporous quartz-bearing rock types), which consists of assigning quartz grains into types (A–E) based on the PDF orientation pattern, and then calculation of a mean shock pressure for each sample.     

Projectile preservation during oblique hypervelocity impacts

Impact angle plays a significant role in determining the fate of the projectile. In this study, we use a suite of hypervelocity impact experiments to reveal how impact angle affects the preservation, distribution, and physical state of projectile residues in impact craters. Diverse types of projectiles, including amorphous silicates, crystalline silicates, and aluminum, in two sizes (6.35 and 12.7 mm), were launched into blocks of copper or 6061 aluminum at speeds between 1.9 and 5.7 km s⁻¹. Crater interiors preserve projectile residues in all cases, including conditions relevant to the asteroid belt. These residues consist of projectile fragments or projectile-rich glasses, depending on impact conditions. During oblique impacts at 30° and 45°, the uprange crater wall preserves crystalline fragments of the projectile. The fragments of water-rich projectiles such as antigorite remain hydrated. Several factors contribute to enhanced preservation on the uprange wall, including a weaker shock uprange, uprange acceleration as the shock reflects off the back of the projectile, and rapid quenching of melts along the projectile–target interface. These findings have two broader implications. First, the results suggest a new collection strategy for flyby sample return missions. Second, these results predict that the M-type asteroid Psyche should bear exogenic, impactor-derived debris.     

Estimating Model Parameters from Self-Potential Anomaly of 2D Inclined Sheet Using Whale Optimization Algorithm: Applications to Mineral Exploration and Tracing Shear Zones

The use of spontaneous potential (SP) anomalies is well known in the geophysical literatures because of its effectiveness and significance in solving many complex problems in mineral exploration. The inverse problem of self-potential data interpretation is generally ill-posed and nonlinear. Methods based on derivative analysis usually fail to reach the optimal solution (global minimum) and trapped in a local minimum. A new simple heuristic solution to SP anomalies due to 2D inclined sheet of infinite horizontal length is investigated in this study to solve these problems. This method is based on utilizing whale optimization algorithm (WOA) as an effective heuristic solution to the inverse problem of self-potential field due to a 2D inclined sheet. In this context, the WOA was applied first to synthetic example, where the effect of the random noise was examined and the method revealed good results using proper MATLAB code. The technique was then applied on several real field profiles from different localities aiming to determine the parameters of mineralized zones or the associated shear zones. The inversion parameters revealed that WOA detected accurately the unknown parameters and showed a good validation when compared with the published inversion methods.