Speciation of trace metals in sediments of a tropical estuary

Axial surveys were performed in the two river tributaries of the Cochin estuary, SW India during November 1988. Surficial sediments were subjected to sequential chemical extractions to delineate five metal fractions, namely, exchangeable, carbonate bound, easily reducible, organic/sulfide bound, and residual. The results indicated selective accumulation of Mn and Ni in carbonate bound and organic/sulfide forms, along with marginal amounts of Co in the exchangeable fraction. Large portions of Fe and Cr occurred in the residual fraction, whereas composite fractionation of Zn species was noticed. The exchangeable fractions of Fe and Cr as well as of easily reducible cobalt were below detection limits. The levels of Cr and Zn indicate anthropogenic inputs in this estuary, whereas Co and Ni show regional contamination exceeding natural levels. The analytical speciation procedure helps to deduce the sedimental diagenetic processes in the estuarine environment.     

Characteristics of spectral aerosol optical depths over India during ICARB

Spectral aerosol optical depth (AOD) measurements, carried out regularly from a network of observatories spread over the Indian mainland and adjoining islands in the Bay of Bengal and Arabian Sea, are used to examine the spatio-temporal and spectral variations during the period of ICARB (March to May 2006). The AODs and the derived Ångström parameters showed considerable variations across India during the above period. While at the southern peninsular stations the AODs decreased towards May after a peak in April, in the north Indian regions they increased continuously from March to May. The Ångström coefficients suggested enhanced coarse mode loading in the north Indian regions, compared to southern India. Nevertheless, as months progressed from March to May, the dominance of coarse mode aerosols increased in the columnar aerosol size spectrum over the entire Indian mainland, maintaining the regional distinctiveness. Compared to the above, the island stations showed considerably low AODs, so too the northeastern station Dibrugarh, indicating the prevalence of cleaner environment. Long-range transport of aerosols from tshe adjoining regions leads to remarkable changes in the magnitude of the AODs and their wavelength dependencies during March to May. HYSPLIT back-trajectory analysis shows that enhanced long-range transport of aerosols, particularly from the west Asia and northwest coastal India, contributed significantly to the enhancement of AOD and in the flattening of the spectra over entire regions; if it is the peninsular regions and the island Minicoy are more impacted in April, the north Indian regions including the Indo Gangetic Plain get affected the most during May, with the AODs soaring as high as 1.0 at 500 nm. Over the islands, the Ångström exponent (α) remained significantly lower (～1) over the Arabian Sea compared to Bay of Bengal (BoB) (～1.4) as revealed by the data respectively from Minicoy and Port Blair. Occurrences of higher values of α, showing dominance of accumulation mode aerosols, over BoB are associated well with the advection, above the boundary layer, of fine particles from the east Asian region during March and April. The change in the airmass to marine in May results in a rapid decrease in α over the BoB.     

Aerosol mass loading over the marine environment of Arabian Sea during ICARB: Sea-salt and non-sea-salt components

Mass loading and chemical composition of atmospheric aerosols over the Arabian Sea during the pre-monsoon months of April and May have been studied as a part of the Integrated Campaign for Aerosols, gases and Radiation Budget (ICARB). These investigations show large spatial variabilities in total aerosol mass loading as well as that of individual chemical species. The mass loading is found to vary between 3.5 and 69.2 μg m^?3, with higher loadings near the eastern and northern parts of Arabian Sea, which decreases steadily to reach its minimum value in the mid Arabian Sea. The decrease in mass loading from the coast of India towards west is estimated to have a linear gradient of 1.53 μg m^?3/° longitude and an e^?1 scale distance of ～2300 km. SO ₄ ^2? , Cl^? and Na⁺ are found to be the major ionic species present. Apart from these, other dominating watersoluble components of aerosols are NO ₃ ^? (17%) and Ca²⁺ (6%). Over the marine environment of Arabian Sea, the non-sea-salt component dominates accounting to ～76% of the total aerosol mass. The spatial variations of the various ions are examined in the light of prevailing meteorological conditions and airmass back trajectories.     

Microbial Biomass and Organic Nutrients in the Deep-Sea Sediments of the Central Indian Ocean Basin

In order to assess the impact of deep-sea mining on the in situ benthic life, we measured the microbial standing stock and concentration of organic nutrients in the deep-sea sediments of the Central Indian Ocean Basin in the Indian pioneer area. Sediments were collected using box core and grab samples during September 1996. The total bacterial numbers ranged from 10 10 -10 11 cells per g -1 dry weight sediment. There was a marginal decrease in the number of bacteria from surface to 30 cm depth, though the subsurface section registered a higher number than did the surface. The highest numbers were encountered at depths of 4-8 cm. The retrievable number of bacteria were two orders less in comparison with the direct total counts of bacteria. An almost homogeneous distribution of bacteria, total organic carbon, living biomass, and lipids throughout the depth of cores indicates active microbial and benthic processes in the deep sea sediments. On the other hand, a uniform distribution of total counts of bacteria, carbohydrates, and total organic carbon in all the cores indicates their stable nature and suggests that they can serve as useful parameters for long-term monitoring of the area after the benthic disturbance. Further studies on temporal variability in this region would not only verify the observed norms of distribution of these variables but would also help to understand restabilization processes after the simulated benthic disturbance.     

Variability of surface roughness and turbulence intensities at a coastal site in India

Surface-layer features with different prevailing wind directions for two distinct seasons (Southwest Monsoon and Northeast Monsoon) on the west coast of India are studied using data obtained from tower-based sensors at a site located about 500 m from the coast. Only daytime runs have been used for the present analysis. The surface boundary-layer fluxes have been estimated using the eddy correlation method. The surface roughnessz ₀ obtained using the stability-corrected wind profiles (Paulson, 1970) has been found to be low for the Southwest monsson season. For the other season,z ₀ is relatively high. The drag coefficientC _D varies with height in the NE monsoon season but not in the season with lowz ₀. This aspect is reflected in the wind profiles for the two seasons and is discussed in detail. The scaling behaviour of friction velocityu _* and the turbulence intensity of longitudinal, lateral and vertical winds _u, _v and _w, respectively) are further examined to study their dependence on fetch. Our study shows that for the non-dimensional case, _u/u_* and _v/u_* do not show any surface roughness dependence in either season. On the other hand, for _w/u_* for the season with lowz ₀, the values are seen to agree well with that of Panofskyet al. (1977) for homogeneous terrain whereas for the other season with highz ₀, the results seem to conform more to the values observed by Smedman and Högström (1983) for coastal terrain. The results are discussed in the light of observations by other investigators.     

A photochemical model of the martian atmosphere

The factors governing the amounts of CO, O2, and O3 in the martian atmosphere are investigated using a minimally constrained, one-dimensional photochemical model. We find that the incorporation of temperature-dependent CO2 absorption cross sections leads to an enhancement in the water photolysis rate, increasing the abundance of OH radicals to the point where the model CO abundance is smaller than observed. Good agreement between models and observations of CO, O2, O3, and the escape flux of atomic hydrogen can be achieved, using only gas-phase chemistry, by varying the recommended rate constants for the reactions CO + OH and OH + HO2 within their specified uncertainties. Similar revisions have been suggested to resolve discrepancies between models and observations of the terrestrial mesosphere. The oxygen escape flux plays a key role in the oxygen budget on Mars; as inferred from the observed atomic hydrogen escape, it is much larger than recent calculations of the exospheric escape rate for oxygen. Weathering of the surface may account for the imbalance. Quantification of the escape rates of oxygen and hydrogen from Mars is a worthwhile objective for an upcoming martian upper atmospheric mission. We also consider the possibility that HOx radicals may be catalytically destroyed on dust grains suspended in the atmosphere. Good agreement with the observed CO mixing ratio can be achieved via this mechanism, but the resulting ozone column is much higher than the observed quantity. We feel that there is no need at this time to invoke heterogeneous processes to reconcile models and observations.     

Late Pleistocene-Holocene Paleoclimatic History of the Southern Kerala Basin, Southwest India

The South Kerala Sedimentary Basin (SKSB) constitutes one of the most significant landward extensions of the southwest offshore sedimentary basins of India, and is situated between 8^o45^' and 10^o15^' N latitudes. With a maximum width of about 20 km and incorporating a 700 m thick sedimentary succession ranging in age from Early Miocene to Holocene, this belt lies almost entirely under water or alluvium-covered coastal plains. In this study, we use two continuously cored bore holes at Eruva (7.25m deep) and Muthukulam (3m deep) separated by a distance of about 7km to investigate the depositional environment as well as paleo ecology of the depocentre and climatic aspects during the Late Pleistocene and Holocene. Results from C¹⁴ dating of shell fragments from Eruva (depth zone: 2.10–6.64m) yielded ages in the range of 36.2 to 42.5 kyBP corresponding to the late Pleistocene. Wood fragments in the Muthukulam core sample (depth zone: 1.27–3.00m) gave C¹⁴ ages in the range of 3.7 to 7.2 kyBP indicating a Holocene history. The lower half of the Eruva bore hole indicates a marginal marine environment with an abundant supply of terrestrial carbonaceous debris probably corresponding to a period of abnormally high rainfall recorded in many parts of the globe covered by the Asian summer monsoon. The sediments in the upper part of this bore hole indicate a continuation of this environment but with much less input of terrestrial organic carbon. The lower part of the bore hole from this locality, corresponding to the Holocene transgression, is similar to the lower part of Eruva bore hole in the case of TOC. Deposition took place in water bodies with considerable marine influence but receiving high amounts of terrestrial plant debris-mostly in the form of finely divided particles mixed with mud. This transgressive sequence was also deposited during a time when the Asian summer monsoon was abnormally high in intensity as indicated by many examples in India, Africa, Madagascar and elsewhere. It is significant that during the deposition of this part, the sea level was probably the same as present or higher suggesting possible lowering of the stream velocities and resultant deposition of only muddy sediments laden with terrestrial organic material along the coast. The upper part of the section shows a progressively reduced rainfall pattern culminating in a period of very low precipitation with the development of a paleosol, which is traceable all over the SKSB where Late Holocene sediments are available. This period also witnessed aeolian activity modifying the sand ridges in the ridge-runnel systems formed by the Holocene regression.     

Estimation of near surface soil moisture in a sloping terrain of a Himalayan watershed using ENVISAT ASAR multi‐incidence angle alternate polarisation data

Soil moisture is one of the important input variables in hydrological and water erosion models. The extraction of information on near surface soil moisture from synthetic aperture radar (SAR) is well established mostly for flat terrain and using low incidence angle single polarisation data. The ENVISAT advanced SAR (ASAR) data available in multiple incidence angles and alternate polarisation modes were investigated in this study for soil moisture estimation in sloping terrain. The test site was Sitla Rao watershed in the Lesser Himalayas of northern India. Empirical models were developed to estimate near surface soil moisture in bare agricultural fields using alternate polarisation ASAR data. Both soil moisture and surface roughness field measurements were performed during the satellite passes. Backscatter from medium incidence angle (IS‐4) and vertical‐vertical (VV) polarisation signal is correlated better with volumetric soil moisture content compared to other incidence angles. The model parameters were further improved, and soil moisture estimation was refined by combining medium incidence angle (IS4) vertical‐horizontal polarisation response as another variable along with VV polarisation response. The effect of slope on the radar backscatter was minimized by incorporating local incidence angles derived from an ASTER DEM. Copyright © 2012 John Wiley & Sons, Ltd.