Overview of In - Situ Biodegradation and Enhancement

Microbial degradation technologies have been developed to restore ground water quality in aquifers polluted by organic contaminants effectively in recent years. However, in course of the degradation, the formation of biofilms in ground water remediation technology can be detrimental to the effectiveness of a ground water remediation project. Several alternatives are available to a remedial design engineer, such as Permeable Reactive Barriers (PRBs) and in -situ bioremediation, Hydrogen Releasing Compounds (HRCs) barrier, Oxygen Releasing Compounds (ORCs) barrier etc. which are efficient and cost- effective technologies. Excessive biomass formation renders a barrier ineffective in degrading the contaminants, Efforts are made to develop kinetics models which accurately determine bio - fouling and bio - filn formation and to control excessive biomass formation.     

Spinor: Visible and Infrared Spectro-Polarimetry at the National Solar Observatory

The Spectro-Polarimeter for Infrared and Optical Regions (SPINOR) is a new spectro-polarimeter that will serve as a facility instrument for the Dunn Solar Telescope at the National Solar Observatory. This instrument is capable of achromatic polarimetry over a very broad range of wavelengths, from 430 to 1600 nm, allowing for the simultaneous observation of several visible and infrared spectral regions with full Stokes polarimetry. Another key feature of the design is its flexibility to observe virtually any combination of spectral lines, limited only by practical considerations (e.g., the number of detectors available, space on the optical bench, etc.). Visiting Astronomers, National Solar Observatory, operated by the Association of Universities for Research in Astronomy, Inc. (AURA), under cooperative agreement with the National Science Foundation.     

QUEST on DASI: a South Pole CMB polarization experiment

QUEST on DASI is a ground-based, high-sensitivity, high-resolution (ℓ_max2500) experiment designed to map CMB polarization at 100 and 150 GHz and to measure the power spectra from E-modes, B-modes from lensing of the CMB, and B-modes from primordial gravitational waves. The experiment comprises a 2.6 m Cassegrain optical system, equipped with an array of 62 polarization-sensitive bolometers (PSBs), located at the South Pole. The instrument is designed to minimize systematic effects; features include differencing of pairs of orthogonal PSBs within a single feed, a rotatable achromatic waveplate, and axisymmetric rotatable optics. In addition the South Pole location allows both repeatable and highly controlled observations. QUEST on DASI will commence operation in early 2005.     

Low‐energy helium ion irradiation‐induced amorphization and chemical changes in olivine: Insights for silicate dust evolution in the interstellar medium

Abstract— We present the results of irradiation experiments aimed at understanding the structural and chemical evolution of silicate grains in the interstellar medium. A series of He+ irradiation experiments have been performed on ultra‐thin olivine, (Mg,Fe)₂SiO₄, samples having a high surface/volume (S/V) ratio, comparable to the expected S/V ratio of interstellar dust. The energies and fluences of the helium ions used in this study have been chosen to simulate the irradiation of interstellar dust grains in supernovae shock waves. The samples were mainly studied using analytical transmission electron microscopy. Our results show that olivine is amorphized by low‐energy ion irradiation. Changes in composition are also observed. In particular, irradiation leads to a decrease of the atomic ratios O/Si and Mg/Si as determined by x‐ray photoelectron spectroscopy and by x‐ray energy dispersive spectroscopy. This chemical evolution is due to the differential sputtering of atoms near the surfaces. We also observe a reduction process resulting in the formation of metallic iron. The use of very thin samples emphasizes the role of surface/volume ratio and thus the importance of the particle size in the irradiation‐induced effects. These results allow us to account qualitatively for the observed properties of interstellar grains in different environments, that is, at different stages of their evolution: chemical and structural evolution in the interstellar medium, from olivine to pyroxene‐type and from crystalline to amorphous silicates, porosity of cometary grains as well as the formation of metallic inclusions in silicates.     

Extensional tectonic origin of gneissosity and related structures of the Feiran–Solaf metamorphic belt, Sinai, Egypt

The Feiran–Solaf metamorphic belt consists of low-P high-T amphibolite facies, partly migmatized gneisses, schists, amphibolites and minor calc-silicate rocks of metasedimentary origin. There are also thick concordant synkinematic sheets of diorite, tonalite and granodiorite orthogneiss and foliated granite and pegmatite dykelets. The gneissosity (or schistosity) is referred to as S₁, and is almost everywhere parallel to lithological layering, S₀. This parallelism is not due to transposition. The gneissosity formed during an extensional tectonic event (termed D1), before folding of S₀. S₁ formed by coaxial pure shear flattening strain (Z normal to S₀, i.e. vertical; with X and Y both extensional and lying in S₁). This strain also produced chocolate tablet boudinage of some layers and S₁-concordant sills and veins. S₁ has a strong stretching lineation L₁ with rodding characteristics. Within-plane plastic anisotropy (lower ductility along Y compared to along X) resulted in L₁-parallel extensional ductile shears and melt filled cracks. Continued shortening of these veins, and back-rotation of foliations on the shears produced intrafolial F₁ folds with hinges parallel to the stretching lineation. F₁ fold asymmetry variations do not support previous models involving macroscopic F₁ folds or syn-gneissosity compressional tectonics. The sedimentary protoliths of the Feiran–Solaf gneisses were probably deposited in a pre-800 Ma actively extending intracratonic rift characterizing an early stage of the break-up of Rodinia.     

Influence of temperature,composition, silica activity and oxygen fugacity on the H<Subscript>2</Subscript>O storage capacity of olivine at 8 GPa

Olivine crystals were grown in the presence of a hydrous silicate fluid during multi-anvil experiments at 8 GPa and 1,000–1,600°C. Experiments were conducted both in a simple system (FeO–MgO–SiO₂–H₂O) and in a more complex system containing additional elements (CaO–Na₂O–Al₂O₃–Cr₂O₃–TiO₂–FeO–MgO–SiO₂–H₂O). Silica activity was buffered by the presence of either pyroxene (high a _SiO2) or ferropericlase (low a _SiO2), and was buffered by the presence of Ni + NiO or Fe + FeO, or constrained by the presence of Fe₂O₃. Raman spectroscopy was used to identify pyroxene polymorphs in the run products. Clinoenstatite was present in the 1,000°C experiment, and enstatite in experiments at 1,400–1,520°C. The H₂O content of olivine was measured using secondary ion mass spectroscopy, and infrared spectroscopy was used to investigate the nature of hydrous defects. The H₂O storage capacity of olivine decreases with increasing temperature at 8 GPa. In contrast to previous experimental results at ≤2 GPa, no significant effect of varying oxygen fugacity is evident, but H₂O storage capacity is enhanced under conditions of low silica activity. No significant growth of low wavenumber (<3,400 cm⁻¹) peaks, generally associated with high at low pressure, was observed in the FTIR spectra of olivine from the high experiments. Our experiments show that previous high pressure H₂O storage capacity measurements for olivine synthesized under more oxidizing conditions than the Earth’s mantle are not likely to be compromised by the of the experiments. However, the considerable effect of temperature on H₂O storage capacity in olivine must be taken into account to avoid overestimation of the bulk upper mantle H₂O storage capacity.     

Isotopic studies of leaf water. Part 1: A physically based two-dimensional model for pine needles

Understanding of isotopic variations in leaf water is important for reconstruction of paleoclimate and assessment of global biochemical processes. We report here a study of isotopic distributions within a single needle of two pine species, Pinus resinosa Ait and Pinus strobes L., with the objective of understanding how isotopic compositions of leaf water are controlled by environmental and physiological variables. A 2D model was developed to simulate along-leaf isotopic variations and bulk leaf water isotopic compositions. In addition to variables common to all leaf water isotopic models, this 2D model also takes into account the specific geometry and dimensions of pine needles and the isotopic transport in xylem and mesophyll. The model can successfully simulate oxygen isotopic variations along a single needle and averaged over a leaf (bulk leaf water). The simulations suggest that isotopic composition of the bulk leaf water does not always depend only upon the average transpiration rate, which in turn raises questions about using leaf water isotopic values to estimate transpiration rates. An unsuccessful attempt to simulate along-needle hydrogen isotopic variations suggests that certain unknown biological process(es) may not have been incorporated into our 2D model, and if so, it calls for a reevaluation of all other models for hydrogen isotopic simulations of leaf water since they too lack these processes.Existing leaf water isotopic models are reviewed in this work. In particular, we evaluate the most frequently used model, the stomatal boundary layer model (also referred to as the Craig-Gordon model). We point out that discrepancy between the boundary layer model and the measured bulk leaf water seems to depend upon relative humidity. Using our 2D model, we show that this humidity dependency is a result of an interplay between environmental and physiological conditions: if the transpiration rate of plant leaves decreases with increasing relative humidity, our 2D model can reproduce the pattern of isotopic discrepancy between boundary layer model predictions and observations, enabling us to understand better the reason behind this discrepancy.     

The presence of anomalous trace element levels in present day Jamaican soils and the geochemistry of Late-Miocene or Pliocene phosphorites

High levels of Cd and Zn in Jamaican soils observed in geochemical surveys are related to the presence of phosphorites of possible Late-Miocene or Pliocene age. The trace element and REE geochemistry of the phosphorites, together with SEM studies, indicate a guano origin for the phosphorites. No specific host minerals for Cd could be identified in the fossiliferous phosphorite which is characterized by uniquely high levels of Cd, Zn, Ag, Be, U and Y. However, in the soil Cd is present in lithiophorite and a complex history of pedological development is preserved in the aluminous–goethite present in the soil. The unique guano signature is preserved in the soil despite the fact that guanos themselves have either not been observed or have been destroyed by continuing karst and soil development. The phosphorite geochemical signature can be traced in the data of a 1988 island-wide soil geochemical survey, identifying areas where the Palaeo-environment that supported bird ‘rookeries’ existed in the Late-Miocene or Pliocene.