Speciation of adsorbed yttrium and rare earth elements on oxide surfaces

The distribution of yttrium and the rare earth elements (YREE) between natural waters and oxide mineral surfaces depends on adsorption reactions, which in turn depend on the specific way in which YREE are coordinated to mineral surfaces. Recent X-ray studies have established that Y³⁺ is adsorbed to the rutile (1 1 0) surface as a distinctive tetranuclear species. However, the hydrolysis state of the adsorbed cation is not known from experiment. Previous surface complexation models of YREE adsorption have suggested two to four cation hydrolysis states coexisting on oxide surfaces. In the present study, we investigate the applicability of the X-ray results to rare earth elements and to several oxides in addition to rutile using the extended triple-layer surface complexation model. The reaction producing a hydrolyzed tetranuclear surface species

     

Second-order wave loading on a horizontal rectangular cylinder of substantial draught

Approximate first- and second-order analytical solutions of wave diffraction of a semi-submerged horizontal cylinder of rectangular cross-section are presented. The solutions are based on the assumption that the pressure in the fluid domain underneath the cylinder is linearly dependent on the horizontal space coordinate. Basically, this approach is valid when the clearance between the bottom of the cylinder and the sea bottom is small in comparison with the wave length and is recommended for a cylinder of substantial draught where due to the small clearance other methods are difficult to apply. Boundary conditions are satisfied by a choice of a proper form of the potential functions and by making use of the properties of matching conditions. Theoretical results reveal that the magnitude of the vertical second-order time-dependent loads could be significant and even exceed the corresponding first-order quantities. This phenomenon, which occurs even at moderate steepnesses, as well as the assumption of a linear pressure distribution, are confirmed by experiments performed in a wave tank.     

A Holocene high-resolution record of aquatic productivity,seasonal anoxia and meromixis from varved sediments of Lake Łazduny,North-Eastern Poland: insight from a novel multi-proxy approach

Anthropogenic eutrophication and spreading anoxia in freshwater systems is a global concern. Little is known about anoxia in earlier historic times under weaker human impact, or under prehistoric natural conditions with different trophic, land cover and climatic regimes. We use a novel approach that combines high-resolution hyperspectral imaging with µ-XRF and HPLC-pigment data, which allows us to assess chloropigments (productivity) and bacteriopigments (anoxia) at seasonal subvarve-scale resolution. Our ~9700 cal a bp varved sediment record from NE Poland suggests that productivity increased stepwise from oligotrophic Early Holocene conditions (until ~9200 cal a bp ) to mesotrophic conditions in the Mid- and Late Holocene. Natural eutrophication was mainly a function of progressing landscape evolution with intense weathering under dense forest and warm-moist climatic conditions. Generally, anoxia increased with increasing productivity. Seasonal anoxia and some multi-decadal periods of meromixis were the common mixing patterns throughout the Holocene except for a period of persisting meromixis between ~5200 and 2000 cal a bp. Anthropogenic deforestation around 400 cal a bp resulted in substantially better lake oxygenation despite high productivity. In this small lake, aquatic productivity and lakeshore forest cover (wind shield) were more important factors controlling oxic/anoxic conditions than Holocene temperature variability.     

A reconstruction of the palaeohydrological conditions of a flood‐plain: a multi‐proxy study from the Grabia River valley mire,central Poland

This study investigated the Grabia River valley mire in central Poland to reconstruct its palaeoenvironmental conditions from the Younger Dryas to the present. We analysed sedimentological, biological and geochemical data from the palaeo‐oxbow lake and valley mire to identify the principal hydrological trends, especially episodes of high water level. During the Lateglacial and Holocene, the Grabia River had a meandering channel, and its hydraulic parameters and the channel dimensions changed in response to climatic oscillations and vegetation development. We identified phases of high flood intensity and high groundwater level that correlate with regional and supraregional climatic events. The frequency and timing of palaeohydroclimatic oscillations show strong similarities to records from other sites in Poland and the rest of Europe. We show that various analytical methods, namely, pollen, plant macrofossils, Cladocera, Chironomidae, sedimentological, geochemical and radiocarbon data, can be effective tools for reconstructing past hydroclimatic changes in palaeo‐oxbow lakes and investigating the effects of past climate changes on river environments. The high sensitivity of the biota, especially Cladocera, to changes in water level permits the reconstruction of palaeoecological changes, especially flood episodes that occurred in the river valley. In particular, the increase in the proportion of sediment‐associated Cladocera and pelagic taxa was closely correlated with floods. Through comparisons with the palaeobiological data, geochemical data allowed the identification of humid phases within the fen associated with a rising groundwater table, direct fluvial activity (floods) and alluvial deposition. We also discuss the limitations of palaeohydrological reconstructions based on these proxies, especially on fossil aquatic invertebrates.     

Characterization of fluid inclusions from mineralized pegmatites of the Damara Belt,Namibia: insight into late-stage fluid evolution and implications for mineralization

Mineralogy and Petrology - Mineralized NYF and LCT pegmatites occur throughout the northeast-trending Neoproterozoic Damara Belt, Namibia. Mineralization in the pegmatites varies geographically,...     

Mg-enriched erythrite from Bou Azzer,Anti-Atlas Mountains,Morocco: geochemical and spectroscopic characteristics

Mineralogy and Petrology - Supergene Mg-enriched erythrite, with an average composition (Co2.25Mg0.58Ni0.14Fe0.04Mn0.02 Zn0.02) (As1.97P<0.01O8)·8H2O, accompanied by skutterudite,...     

The response of slope and channel systems to various types of extreme rainfall: A comparison between the temperate zone and humid tropics

The mountain slopes and river channels of the temperate zone and of the humid tropics are modelled by various types of extreme rainfall. In the Flysch Carpathians the leading role is played by continuous rains causing floods and landslides, rainy seasons (wet years) mobilizing deep landslides and, to a smaller degree by local downpours. In the Darjeeling Himalaya with young relief and uplift tendency, the main influence on modelling the mountain slopes and river channels have been the extreme continuous rains separated by several decades of normal rainy season, playing the preparatory or relaxation role with simultaneous transformation of slopes and river channels. In both cases human impact has caused the acceleration of runoff and mobilization of sediment. The higher extremes of precipitation and steep slopes in the humid tropics are balanced (to some extent) in temperate zones by the lower infiltration rates and lower thresholds of mass mobility on the gentle slopes originated in the periglacial environment.     

Fast-changing processes in a medium subject to loading as detected by resistivity measurements

Making measurements of electric resistivity at 16 s intervals, the authors noticed fast changes of this parameter prior to the occurrence of the main fracture. The changes are superposed on bay pulsations of increasing amplitude and decreasing period. This finding opens prospects for a wider use of an electric resistivity method and proves the high quality of automatic instruments, in particular their high resolution. It also gives evidence for the occurrence of short-period precursors in the fracture zone while the main fracture is being formed.     

Polish forest ecosystems: The influence of changes in the economic system on the carbon balance

In order to study the effects of a change in the economic system on carbon balance at a national scale, a balance of the carbon influx and effluxes was prepared for forest ecosystems in Poland for 1988, and was repeated for 1990. The year 1988 was the first year of drastic economic changes (and severe crises) in Poland. Two entirely different approaches were used to estimate the carbon influx into a forest ecosystem. The forest inventory approach was based on data from conventional measurements of merchantable timber in forests, whereas the carbon flux and allocation approach was based on the estimate of net photosynthetic productivity of forest ecosystems to calculate the carbon influx. Results from both approaches were within the range 1.17 to 5.77t C/ha/yr which most likely defined lower and upper limits for the carbon influx into forest ecosystems in Poland. On the national scale, the carbon influx into Polish forest ecosystems was estimated by the forest inventory approach to be about 12.8 Mt C/yr. This result was similar for both years. Efflux of carbon from Polish forest ecosystems resulted almost entirely from the decay of logging residues. The efflux in 1990 (3.82 Mt C/yr) was about 26% lower than that in 1988. Storage of the carbon in Polish forest ecosystems (including an estimate of the carbon pool in forest soils) was 1.8% greater in 1990 (2518 Mt C) than in 1988, when it equalled 2473 Mt C.     

Seismicity before and after the two great Sumatra earthquakes of 2004 and 2005

The Harvard CMT catalogue contains 481 shallow earthquakes that occurred between 1 January 1977 and 30 November 2005 within a broad region defined by the geographical latitude from 3°S to 14°N and by the longitude from 91°E to 102°E. There are 230 events that occurred before the great earthquake of 26 December 2004. Their surface distribution is not uniform and the source area of the 2004 great event appears as an area of seismic quiescence with a radius of about 100 km. There are 186 events that occurred between the two great earthquakes of 26 December 2004 and 28 March 2005. Practically all of them are located to the northwest from the great earthquake of 2005, that in turn was followed by 63 events, mostly located to the southeast. The cumulative seismic moment from earthquakes before the occurrence of the great event of 2004 increased rather regularly with time, with sudden increase about twenty years and two years before the occurrence of the great event. The seismic moment of earthquakes between the two great events increased rapidly during the first ten-fifteen days, then flattened out and increased slowly with time. After the great event of 2005 the seismic moment shows quiet increase during some 115 days, then sudden jump, followed by very small activity till the end of our observations. From the spatial distribution of seismic moment of earthquakes that occurred before the great event of 2004 it follows that its largest release appeared to the southeast from the great event, around the rupture area of the great earthquake of 2005. The largest release of seismic moment from earthquakes between the two great events is observed in the vicinity of the 2004 event and further up to the north. The seismic moment from earthquakes that occurred after the great event of 2005 was mostly released in its vicinity and further down to the south.