Exposure dating and reinterpretation of coarse debris accumulations (‘rock glaciers’) in the Cairngorm Mountains,Scotland

Relict rock glaciers have considerable potential for contributing to palaeoclimatic reconstruction, but this potential is often undermined by lack of dating control and problems of interpretation. Here we reinvestigate and date four proposed ‘rock glaciers’ in the Cairngorm Mountains and show that the morphology of only one of these appears consistent with that of a true rock glacier produced by creep of underlying ice or ice‐rich sediment. All four features comprise rockslide or rock avalanche runout debris, and the possibility that all four represent unmodified runout accumulations cannot be discounted. Surface exposure dating of the four debris accumulations using cosmogenic ¹⁰Be produced uncertainty‐weighted mean ages of 15.4 ± 0.8 ka, 16.2 ± 1.0 ka, 12.1 ± 0.6 ka and 12.7 ± 0.8 ka. All four ages imply emplacement under cold stadial conditions, two prior to the Windermere Interstade of ca. 14.5–12.9 cal. ka BP and two during the Loch Lomond Stade of ca. 12.9–11.5 cal. ka BP. The above ages indicate that paraglacial rock‐slope failure on granite rockwalls occurred within a few millennia after deglaciation. The mean exposure ages obtained for runout debris at two sites – Strath Nethy (16.2 ± 1.0 ka) and Lairig Ghru (15.4 ± 0.8 ka) – are consistent with basal radiocarbon ages from Loch Etteridge, 22 km to the southwest (mean = 15.6 ± 0.3 cal. ka BP) and imply widespread deglaciation of the Cairngorms and adjacent valleys before 15 ka and possibly 16 ka. Copyright © 2008 John Wiley & Sons, Ltd.     

The palaeoenvironment associated with a partial Iguanodon skeleton from the Upper Weald Clay (Barremian, Early Cretaceous) at Smokejacks Brickworks (Ockley, Surrey, UK), based on palynomorphs and ostracods

In 2001 a partial skeleton of an Iguanodon was discovered in the Upper Weald Clay (Barremian, Early Cretaceous) at Smokejacks Brickworks near Ockley, Surrey, UK. When the dinosaur was excavated, a detailed stratigraphic section was logged and 25 samples taken for palynological and micropalaeontological (ostracod and megaspore) analysis, including a detailed sample set of the dinosaur bed itself. Qualitative and quantitative analysis of the palynoflora revealed rich and well-preserved non-marine assemblages of pollen and spores, including early angiosperms, and freshwater green algae. Four types of angiosperm pollen are described and assigned to the genus Retimonocolpites Pierce, 1961, but left in open nomenclature. Some marine elements such as dinoflagellate cysts are identified as the result of reworking of Middle and Upper Jurassic sediments. The pollen/spore assemblages depict a vegetational change from principally gymnosperm-dominated assemblages at the base to principally pteridophyte-dominated assemblages at the top of the section. The dinosaur bed shows a pteridophyte-dominated assemblage, with a significantly high amount of the freshwater green alga Scenedesmus novilunaris He Cheng-quan et al., 1992. Samples close to the dinosaur bed yielded the first useful ostracod finds from Smokejacks Brickworks: well-preserved assemblages containing Cypridea clavata (Anderson, 1939), Damonella cf. pygmaea (Anderson, 1941), Stenestroemia cf. cressida Anderson, 1971 and Stenestroemia sp. A, and fragments and damaged valves of a thin-shelled ostracod, possibly belonging to Mantelliana Anderson, 1966. Those identified as Cypridea clavata show a wide range of morphological variety and in opposition to Anderson's (1967, 1985) taxonomic scheme, which would assign them to up to five different taxa, they are considered to be intraspecific variants of a single species. The possibilities and limitations of age determination of the Wealden sediments using palynomorphs and ostracods are discussed; distinct forms of early angiosperm pollen, together with the ostracod fauna, are consistent with an early Barremian age. Pollen and spores are discussed in terms of their parent plants and the reconstruction of vegetation and palaeoclimate. Palynology and ostracods give evidence for temporary freshwater conditions at the time when the Iguanodon died and the carcase was buried.     

Palynofacies and sea-level changes in the Upper Cretaceous of the Vocontian Basin, southeast France

Upper Cretaceous platform carbonates of the Vocontian Basin (southeastern France) have been investigated in a cross-section from the proximal deposits exposed in the lower Rhône Valley to the distal part of the basin in the Southern Subalpine Ranges north of Nice. The stratigraphic interval studied in detail spans the uppermost Turonian and Coniacian.Palynofacies patterns were used to detect eustatic signals at a third-order scale and are the tool for correlation of proximal and distal platform deposits. The organic constituents observed in the studied samples have been grouped into a continental fraction, including higher plant debris (phytoclasts) and sporomorphs, and a marine fraction with dinoflagellate cysts, acritarchs, prasinophytes, and foraminiferal test linings. The main factors influencing the stratigraphic and spatial distribution of land-derived, allochthonous, and marine, relatively autochthonous, organic particles are the proximity of land, the organic productivity, the degree of biodegradation and the hydrodynamic conditions of the depositional system. Palynofacies parameters used for the sequence stratigraphic interpretation are: (1) the ratio of continental to marine constituents (CONT/MAR ratio); (2) the ratio of opaque to translucent phytoclasts (OP/TR ratio); (3) the phytoclast particle size and shape; and (4) the relative proportion and species diversity of marine plankton. Ternary diagrams illustrating significant proximality changes were used to decipher transgressive-regressive trends within the succession.High amounts of translucent phytoclasts and decreasing values of the CONT/MAR ratio occur during the phase of relative sea-level rise in the upper Turonian. The stratigraphic interval of maximum flooding around the Turonian/Coniacian boundary is marked by the highest abundance and species diversity of dinoflagellate cysts, and by high percentages of opaque, equidimensional particles within the phytoclast group. The OP/TR ratio is still high within the lower Coniacian representing the early highstand deposits, whereas the relative abundance of marine constituents is again decreasing. Sedimentary organic matter of the upper Coniacian is dominated by large, blade-shaped, mainly opaque phytoclasts, which are a characteristic palynofacies signature of late highstand deposits.The present study demonstrates the high potential of palynofacies analysis in high-resolution stratigraphy and correlation of sedimentary series of shallow epeiric seas.     

Development of fouling communities on vertical structures in the Baltic Sea

The pillars of the bridge connecting the Island of Öland with the Swedish mainland were rebuilt between 1990 and 2000. The renovation produced pristine vertical concrete substrates, which became submerged in known years and seasons. The fouling communities on the pillars were examined in 2001 to determine whether the community structure could be explained in terms of either orderly successional development or of seasonal variation in the settlement of benthic organisms. As well, the communities on the pillars were compared to communities on the vertical surfaces of boulders in the area. The results indicated that an annual species composition is the final stage in the succession on the observed, vertical constructions. The few perennial species add to the variation between pillars as they increase in biomass (Polysiphonia fucoides) or become out-competed (Balanus improvisus). Also, observed seasonal differences in the biomass of these perennial species indicated that the time of year free space becomes available might be an important determinant of the future structure of the community. Comparison between the pillar and boulder communities showed that the artificial structures were not surrogates for the natural hard substrate: pillar communities differed in that they lacked most perennial algal species and had a high biomass of B. improvisus.     

Coupling an ocean wave model to an atmospheric general circulation model

A coupled model, consisting of an ocean wave model and an atmospheric general circulation model (AGCM), is integrated under permanent July conditions. The wave model is forced by the AGCM wind stress, whereas the wind waves modify the AGCM surface fluxes of momentum, sensible and latent heat. We investigate the following aspects of the coupled model: how realistic are the wave fields, how strong is the coupling, and how sensitive is the atmospheric circulation to the spatially and temporally varying wave field. The wave climatology of the coupled model compares favorably with observational data. The interaction between the two models is largest (although weak) in the storm track in the Southern Hemisphere. Young windsea, which is associated with enhanced surface fluxes is generated mostly in the equatorward frontal area of an individual cyclone. However, the enhancement of the surface fluxes is too small to significantly modify the climatological mean atmospheric circulation.This paper was presented at the Second International Conference on Modelling of Global Climate Variability, held in Hamburg 7–11 September 1992 under the auspices of the Max Planck Institute for Meteorology. Guest Editor for these papers is L. Dümenil     

Diffusion-limited REE uptake by eclogite garnets and its consequences for Lu–Hf and Sm–Nd geochronology

Garnets from the Zermatt-Saas Fee eclogites contain narrow central peaks for Lu + Yb + Tm ± Er and at least one additional small peak towards the rim. The REE Sm + Eu + Gd + Tb ± Dy are depleted in the cores but show one prominent peak close to the rim. These patterns cannot be modeled using Rayleigh fractionation accompanied by mineral breakdown reactions. Instead, the patterns are well explained using a transient matrix diffusion model where REE uptake is limited by diffusion in the matrix surrounding the porphyroblast. Observed profiles are well matched if a roughly linear radius growth rate is used. The secondary peaks in the garnet profiles are interpreted to reflect thermally activated diffusion due to temperature increase during prograde metamorphism. The model predicts anomalously low ¹⁷⁶Lu/¹⁷⁷Hf and ¹⁴⁷Sm/¹⁴⁴Nd ratios in garnets where growth rates are fast compared to diffusion of the REE, and these results have important implications for Lu–Hf and Sm–Nd geochronology using garnet.     

Atmospheric nitrogen inputs into the North Sea: effect on productivity

The ANICE (Atmospheric Nitrogen Inputs into the Coastal Ecosystem) project addressed the atmospheric deposition of nitrogen to the North Sea, with emphasis on coastal effects. ANICE focused on quantifying the deposition of inorganic nitrogen compounds to the North Sea and the governing processes. An overview of the results from modelling and experimental efforts is presented. They serve to identify the role of the atmosphere as a source of biologically essential chemical species to the marine biota. Data from the Weybourne Atmospheric Observatory (UK) are used to evaluate the effect of short episodes with very high atmospheric nitrogen concentrations. One such episode resulted in an average deposition of 0.8 mmol N m⁻² day⁻¹, which has the potential to promote primary productivity of 5.3 mmol C m⁻² day⁻¹. This value is compared to long-term effects determined from model results. The total calculated atmospheric deposition to the North Sea in 1999 is 948 kg N km⁻¹, i.e. 0.19 mmol N m⁻² day⁻¹ which has the potential to promote primary productivity of 1.2 mmol C m⁻² day⁻¹. Detailed results for August 1999 show strong gradients across the North Sea due to adjacent areas where emissions of NO_x and NH₃ are among the highest in Europe. The average atmospheric deposition to the southern part of the North Sea in August 1999 could potentially promote primary production of 2.0 mmol C m⁻² day⁻¹, i.e. 5.5% of the total production at this time of the year in this area of the North Sea. For the entire study area the atmospheric contribution to the primary production per m² is about two-third of this value. Most of the deposition occurs during short periods with high atmospheric concentrations. This atmospheric nitrogen is almost entirely anthropogenic in origin and thus represents a human-induced perturbation of the ecosystem.     

Sampling Fauna in Stream Sediments as well as Groundwater Using One Net Sampler

Groundwater bores act as traps. Net samplers are regularly used for sampling this type of trap for fauna. To enable direct comparisons of faunal communities in groundwater bores and stream sediments, stream sediment tubes were built similar to groundwater bores and were sampled with net samplers for fauna. These stream sediment tubes consisted of a tube anchored in the stream sediment, also called interstitial space. To test the efficacy of this trap method in stream sediments, it was compared to another type of trap, Hahn's trap. Faunal communities sampled by a net in the stream sediment tubes did not differ hugely from fauna in Hahn's trap samples. Physical and chemical factors of sampled water in both the stream sediment tubes, the surrounding interstitial sediments and the second type of traps, Hahn's traps, showed that water in both the tubes and Hahn's traps was closely related to interstitial water. The net sampler is inexpensive and easy to handle. It is suggested that sampling stream tubes with nets may be an appropriate method for long‐term monitoring studies.     

Beryllium-10 in Australasian tektites: Constraints on the location of the source crater

By using accelerator mass spectrometry we have measured the ¹⁰Be concentrations of 86 Australasian tektites. Corrected to the time of tektite production ∼0.8 My ago, the ¹⁰Be concentrations (10⁶ atom/g) range from 59 for a layered tektite from Huai Sai, Thailand, to 280 for an australite from New South Wales, Australia. The average value is 143 ± 50. When tektites are sorted by country, their average measured ¹⁰Be concentrations increase slowly with increasing distance from Southeast Asia, the probable location of the tektite producing event, from 59 ± 9 for 6 layered tektites from Laos to 136 ± 20 for 20 splash-form tektites from Australia. The lowest ¹⁰Be concentrations for tektites fall on or within a contour centered off the shore of Vietnam, south of the Gulf of Tonkin (107°E; 17°N), but also encompassing two other locations in the area of northeastern Thailand previously proposed for the site of a single tektite-producing impact. The ¹⁰Be concentrations of layered tektites show only a weak anticorrelation (R ∼ −0.3) with the numbers of relict crystalline inclusions.Loosely consolidated, fine-grained terrestrial sediments or recently consolidated sedimentary rocks are the most likely precursor materials. Dilution of sediments with other kinds of rock raises problems in mixing and is not supported by petrographic data. Sedimentary columns that have the right range of ¹⁰Be concentrations occur off the coasts of places where sedimentation rates are high relative to those in the deep sea. A single impact into such a region, 15 to 300 m thick, could have propelled near-surface, high-¹⁰Be material farthest—to Australia—while keeping the deeper-lying, low-¹⁰Be layers closer to home. We do not rule out, however, other proposed mechanisms for tektite formation.     

CO2 solubility in dacitic melts equilibrated with H2O-CO2 fluids: Implications for modeling the solubility of CO2 in silicic melts

The solubility of CO₂ in dacitic melts equilibrated with H₂O-CO₂ fluids was experimentally investigated at 1250°C and 100 to 500 MPa. CO₂ is dissolved in dacitic glasses as molecular CO₂ and carbonate. The quantification of total CO₂ in the glasses by mid-infrared (MIR) spectroscopy is difficult because the weak carbonate bands at 1430 and 1530 cm⁻¹ can not be reliably separated from background features in the spectra. Furthermore, the ratio of CO_2,mol/carbonate in the quenched glasses strongly decreases with increasing water content. Due to the difficulties in quantifying CO₂ species concentrations from the MIR spectra we have measured total CO₂ contents of dacitic glasses by secondary ion mass spectrometry (SIMS).At all pressures, the dependence of CO₂ solubility in dacitic melts on x^fluid_CO2,total shows a strong positive deviation from linearity with almost constant CO₂ solubility at x_CO2fluid > 0.8 (maximum CO₂ solubility of 795 ± 41, 1376 ± 73 and 2949 ± 166 ppm at 100, 200 and 500 MPa, respectively), indicating that dissolved water strongly enhances the solubility of CO₂. A similar nonlinear variation of CO₂ solubility with x_CO2fluid has been observed for rhyolitic melts in which carbon dioxide is incorporated exclusively as molecular CO₂ (Tamic et al., 2001). We infer that water species in the melt do not only stabilize carbonate groups as has been suggested earlier but also CO₂ molecules.A thermodynamic model describing the dependence of the CO₂ solubility in hydrous rhyolitic and dacitic melts on T, P, f_CO2 and the mol fraction of water in the melt (x_water) has been developed. An exponential variation of the equilibrium constant K₁ with x_water is proposed to account for the nonlinear dependence of x_CO2,totalmelt on x_CO2fluid. The model reproduces the CO₂ solubility data for dacitic melts within ±14% relative and the data for rhyolitic melts within 10% relative in the pressure range 100-500 MPa (except for six outliers at low x_CO2fluid). Data obtained for rhyolitic melts at 75 MPa and 850°C show a stronger deviation from the model, suggesting a change in the solubility behavior of CO₂ at low pressures (a Henrian behavior of the CO₂ solubility is observed at low pressure and low H₂O concentrations in the melt). We recommend to use our model only in the pressure range 100-500 MPa and in the x_CO2fluid range 0.1-0.95. The thermodynamic modeling indicates that the partial molar volume of total CO₂ is much lower in rhyolitic melts (31.7 cm³/mol) than in dacitic melts (46.6 cm³/mol). The dissolution enthalpy for CO₂ in hydrous rhyolitic melts was found to be negligible. This result suggests that temperature is of minor importance for CO₂ solubility in silicic melts.