Raman spectra of methane hydrate up to 86 GPa

High-pressure Raman studies of methane hydrate were performed using a diamond anvil cell in the pressure range of 0.1–86 GPa at room temperature. Raman spectra of the methane molecules revealed that new softened intramolecular vibration mode of ν ₁ appeared at 17 GPa and that the splitting of vibration mode of ν ₃ occurred at 15 GPa. The appearance of these two modes indicates that an intermolecular attractive interaction increases between the methane molecules and the host water molecules and between the neighboring methane molecules. These interactions might result in the exceptional stability of a high-pressure structure, a filled ice Ih structure (FIIhS) for methane hydrate, up to 40 GPa. At 40 GPa, a clear change in the slope of the Raman shift versus pressure occurred, and above 40 GPa the Raman shift of the vibration modes increased monotonously up to 86 GPa. A previous XRD study showed that the FIIhS transformed into another new high-pressure structure at 40 GPa. The change in the Raman spectra at 40 GPa may be induced by the transition of the structure.     

Stage-V copepodites of Calanus sinicus and Calanus jashnovi (Copepoda: Calanoida) in mesopelagic zone of Sagami Bay as identified with genetic markers, with special reference to their vertical distribution

We applied genetic makers to identify Calanus species occurring in Sagami Bay, Japan, in order to investigate their vertical distribution in the upper 1000 m. First, interspecific genetic distances of three gene loci, mitochondrial small ribosomal RNA (srRNA), nuclear internal transcribed spacers 1 (ITS1) and 2 (ITS2), were estimated from morphologically distinguishable adult females of Calanus sinicus, Calanus jashnovi and Calanus pacificus that were collected from Sagami Bay, the Kuroshio Extension and the Oyashio region, respectively. The highest levels of interspecific genetic distance were observed in srRNA, followed by ITS1 and ITS2. The intraspecific genetic distances within C. sinicus were much lower than the interspecific genetic distances, indicating that DNA sequences in these loci are consistent with the morphological differences. This information was used as a criterion for species identification based on DNA sequence variation, and allowed us to identify the fifth copepodites (CVs) or younger stages of these species. Next, the vertical distribution of Calanus species was investigated in Sagami Bay in May 2006, on the basis of a stratified sampling in the upper 1000 m. By applying the genetic markers, 23 individuals comprising all copepodite stages were allocated into either C. sinicus or C. jashnovi, and the small- and large-sized CVs were identified as C. sinicus and C. jashnovi, respectively. The total abundance of C. sinicus was highest at 0-50 m and decreased with depth. On the contrary, CV individuals of C. sinicus were abundant not only in 0-50 m but also below 200 m with minimum occurrences in 150-200 m depth. C. jashnovi was much less abundant than C. sinicus and comprised of only CIV and CV which occurred in the upper 100 m and deeper than 50 m depths, respectively. The abundance of C. sinicus in the 1000-m water column of Sagami Bay was at a level comparable to that in shelf waters, suggesting the importance of off-shelf individuals in the biological production and organic transport in the respective areas.     

Coastal aquifer system in late Pleistocene to Holocene deposits at Horonobe in Hokkaido,Japan

The groundwater flow systems and chemistry in the deep part of the coastal area of Japan have attracted attention over recent decades due to government projects such as geological disposal of radioactive waste. However, the continuous groundwater flow system moving from the shallow to deep parts of the sedimentary soft rock has not yet been characterized. Therefore, the Cl^–, δD and δ¹⁸O values of the pore water in the Horonobe coastal area in Hokkaido, Japan, were measured to 1,000 m below the ground surface, and a vertical profile of the pore-water chemistry was constructed to assist in elucidating groundwater circulation patterns in the coastal area. The results show that the groundwater flow regime may be divided into five categories based on groundwater age and origin: (1) fresh groundwater recharged by modern rainwater, (2) fresh groundwater recharged by paleo rainwater during the last glacial age, (3) low-salinity groundwater recharged during the last interglacial period, (4) mixed water in a diffusion zone, and (5) connate water consisting of paleo seawater. These results suggest that the appearance of hydrological units is not controlled by the boundaries of geological formations and that paleo seawater is stored in younger Quaternary sediments.     

Delayed impact of new volcanic ejecta on ground water quality

We observed long-term changes in the concentrations of dissolved ions in ground water caused by leachate from new volcanic ejecta deposited on the ground surface of the volcanic Miyakejima Island, Japan. Water samples were collected from nine wells and two rain collectors over a period of more than 10 years, and samples of runoff water were collected periodically. The samples were analyzed for temperature, pH, alkalinity, Cl⁻, and SO₄²⁻; some of the samples were also analyzed for δ¹³C. Because the leachate from the volcanic ejecta contained sulfate, we recorded an increase in SO₄²⁻ concentrations in the (unconfined) well water. The increase in SO₄²⁻ was initially detected between less than 1.4 and 5.2 years after the eruption, showing peak concentrations from 2.4 to 6.4 years after the eruption. This delayed response reflects the transit time of downward-moving SO₄²⁻ in the vadose zone, corresponding to an apparent movement rate of 0.4 to 7.2 cm/d. The rate relates to the mean recharge, represented as a fraction of local mean rainfall, and is calculated using the Cl⁻ balance method. The magnitude of the recorded increases reflects the volume of volcanic mudflow on the ground surface within the basin. For the management of ground water after an eruption, it is therefore important to know the chemical properties of the volcanic ejecta and the spatial distribution of mudflow to estimate the magnitude of the effect of ejecta on ground water quality.     

Collapse and fragmentation of rotating magnetized clouds – I. Magnetic flux–spin relation

We discuss the evolution of the magnetic flux density and angular velocity in a molecular cloud core, on the basis of three-dimensional numerical simulations, in which a rotating magnetized cloud fragments and collapses to form a very dense optically thick core of  >5 × 10¹⁰ cm⁻³  . As the density increases towards the formation of the optically thick core, the magnetic flux density and angular velocity converge towards a single relationship between the two quantities. If the core is magnetically dominated its magnetic flux density approaches  1.5( n /5 × 10¹⁰ cm⁻³)^1/2 mG  , while if the core is rotationally dominated the angular velocity approaches  2.57 × 10⁻³ ( n /5 × 10¹⁰ cm⁻³)^1/2 yr⁻¹  , where n is the density of the gas. We also find that the ratio of the angular velocity to the magnetic flux density remains nearly constant until the density exceeds  5 × 10¹⁰ cm⁻³  . Fragmentation of the very dense core and emergence of outflows from fragments will be shown in the subsequent paper.     

Myojin Rift, Izu–Bonin Arc as the Modern Analog of Hokuroku Basin, Northeast Japan: Geotectonic Significance of the New Hydrothermal Deposit in the Back-Arc Rift

A huge hydrothermal field, named the "Hakurei Sulfide Deposit" (HSD) was discovered in the North Myojin Rift (NMR), Izu–Bonin Back-Arc Rift (BAR) during the 2003 survey cruise of R/V Hakurei-maru No.2 . This paper investigates the geotectonic features and the tectonic setting of ore deposits between the NMR and the Hokuroku Basin, which is representative of kuroko fields in Japan. The topographic features of the NMR and the Hokuroku Basin are similar. Both have a clear ring structure surrounded by faults and the east–west width is almost the same. Many kuroko deposits were formed on the extrusion centers of the five pre-mineral acidic volcanic complexes, located in a loop inside the Hokuroku Basin. In the case of the NMR, seven submarine volcanoes are also located in a loop, and the HSD formed inside the summit caldera of Bayonnaise Knoll, which is one of the seven volcanoes. These topographic similarities highlight that the NMR is a modern analog of the Hokuroku Basin. Identifying such similarities is extremely useful when prospecting kuroko deposits on land equivalents as well as on the other segments of the Izu–Bonin BAR. The probability of finding kuroko deposits on land is expected to increase when the following are identified: (i) location of back-arc rift and the volcanic front; (ii) direction of the arc–trench system and intra-rift faults (and/or fracture zone); (iii) position of submarine volcanoes surrounding a back-arc rift; and (iv) intersections of a caldera fault and intra-rift fault (and/or fracture zone) inside the summit caldera of submarine volcanoes. Within these aforementioned points a ring structure, acidic volcanic complexes that circle the circuit and submarine calderas along the volcanic front, are an important indication of submarine hydrothermal deposits.     

Low-Angle Thomson Scattering Experiment for Determination of Plasma Electron Density and Temperature

In this work we show results of measurements of the electron density n_e and temperature T_e by using small-angle Thomson scattering in a theta-pinch plasma. The method of measurement and analysis developed here is based on integration of only two ranges of the scattering profile. This method simplifies the experimental set up, because it needs only two detectors for simultaneous determination of n_e and T_e, instead of the commonly 5–7 detectors used in 90° experiments.The results obtained for low-angle scattering are compared with the measurements at 90° using single pass and multipass under the same plasma conditions.     

Evidence for recycled plate material in Pacific upper mantle unrelated to plumes

We report Sr, Nd, and Pb isotopic data of young alkaline basalt lava from a new type of volcano (petit-spot) on the northwestern Pacific Plate. Petit-spot lavas show Dupal, or extremely EM-1-like, Sr-Nd-Pb isotopic compositions. The data cannot be explained by contamination of pelagic sediment, in spite of the prediction on the basis of geological observation. We thus consider that the geochemistry of petit-spot lava indicates the existence of recycled fertile plate materials, not only the Dupal isotopic signature, in the northern hemisphere Pacific upper mantle unrelated to one or more active plumes. In consideration of published experimental results for fertile plate materials, selective melting of recycled material is a process critical in generating petit-spot lava. Moreover, the small volume of the volcano and low degree of melting in the mantle source needed to form strongly alkalic lavas suggest that petit-spot volcanism is originated from small-scale heterogeneities of recycled material. This idea consistently explains the geochemistry and noble gas isotopic composition of petit-spot lava, and also suggests small-scale heterogeneity widespread in the upper mantle of the Pacific Ocean. Together with a revised view of upper mantle heterogeneity, we propose that gross upper mantle composition is controlled by abundances and scales of regions of recycled material that correspond to differences in the relative position to the Pangea supercontinent, suggesting the link to the tectonic origin of the global scale heterogeneity.     

Reaction of forsterite with hydrogen molecules at high pressure and temperature

High pressure and temperature reactions of a mixture of forsterite and hydrogen molecules have been carried out using a laser heated diamond anvil cell at 9.8–13.2 GPa and ~1,000 K. In situ X-ray diffraction measurements showed no sign of decomposition or phase transitions of the forsterite under these experimental conditions, indicating that the olivine structure was maintained throughout all runs. However, a substantial expansion of the unit cell volume of the forsterite was observed for samples down to ~3 GPa upon quenching to ambient pressure at room temperature. The Raman spectroscopy measurements under pressure showed significant shifts of the Raman peaks of the Si–O vibration modes for forsterite and of the intramolecular vibration mode for H₂ molecules toward a lower frequency after heating. Additionally, no OH vibration modes were observed by Raman and FT-IR spectroscopic measurements. These lines of evidence show that the observed volume expansion in forsterite is not explained by the incorporation of hydrogen atoms as hydroxyl, but suggest the presence of hydrogen as molecules in the forsterite structure under these high pressure and temperature conditions.