Rhenium in rivers and estuaries of India: Sources,transport and behaviour

The concentration of dissolved and particulate Re have been measured in the Narmada, Tapi and the Mandovi estuaries in the Arabian Sea and the Hooghly estuary in the Bay of Bengal. Re concentration in water and particulate matter of these estuaries is highly variable. Re in river waters analysed varies from 1 to 41 pmol/kg, the lowest in the Mandovi and the highest in the Mahi river. Re concentrations in the rivers analysed except in the Mandovi river are higher than the average global riverine Re concentration of 2.1 pmol/kg. Based on this study and the available data, the contemporary global annual flux of dissolved riverine Re is estimated to be ~ 350 × 10³ mol with an average concentration of ~ 9.2 pmol/kg, much higher than the earlier estimates. Residence time of Re in the oceans based on this estimate is 175,000 years, ~ 4 times lower compared to earlier estimates. Re behaves conservatively in all the estuaries studied. Re concentrations of seawater in the Bay of Bengal and in the Arabian Sea, estimated from the data of the Hooghly and the Mandovi estuaries respectively are ~ 40 pmol/kg, similar to the open ocean Re values of the Arabian Sea measured in this study and the values reported for in other oceanic regions. However, the dissolved Re in the Gulf of Cambay is 2 to 5 times higher, consistent with the high Re measured in the Mahi estuary and in the coastal waters of the Gulf of Cambay. The source of high Re in the Gulf of Cambay seems to be anthropogenic, measurements of Re in rivers and industrial waste waters draining into the Gulf supply amount to ~ 2300 mol of Re annually. This anthropogenic supply coupled with high residence time of water in the Gulf contribute to its high Re. Re concentration in suspended sediments of the Narmada estuary varies from 1 to 2 pmol/g, and does not show any discernible trend with salinity.The contemporary global riverine Re supply to the oceans estimated in this study is ~ 2–4 times higher compared to its removal in the reducing (anoxic/suboxic) sediments, indicating non-steady state of Re in the ocean. High dissolved riverine Re flux coupled with high Re content in the Gulf of Cambay highlights the need of a detailed study of Re in the various global rivers and in oceans including coastal regions and semi enclosed basins of the world to understand its behaviour in various reservoirs and to constrain the residence time of Re in the ocean.     

Hydrobiology of some solar salt works in India

The hydrobiology of two Indian solar salt works was investigated. A salient feature was variability in physico-chemical and biological characteristics. The filamentous cyanophyceansLyngbya majuscula andOscillatoria salina and the chlorophyceanXenococcus aceervatus were the major primary producers. Significant fauna were protozoans, rotifers and copepods.Artemia was present in only one set of solar salt pans, where it was dominant. The study illustrates the importance ofArtemia in the biological management of solar salt works. This paper is dedicated to Thiru. K. Ayyaru Vandayar, Member, Governing body, A.V.V.M. Sri Pshpam College (Autonomous), Poondi, on his sixtieth birthday     

U-Pb Pan-African ages of two charnockite-granite associations from Southwestern Nigeria

U-Pb dating of zircons from two separate charnockite granite associations from S.W. Nigeria, previously considered to be of Kibaran or Archean age, yield PanAfrican emplacement ages of 631±18 Ma and 586±5 Ma respectively when all the data points of each association are regressed together. These U-Pb data on zircons do not permit a confirmation of the field-established sequence of rock emplacement within each charnockite-granite association; thus synchronous ages of 620±20 Ma (charnockite NIG 4), 634±21 Ma (charnockite NIG 7) and 621±10 Ma (granite NIG 12) are obtained for the three analyzed rocks of the Akure-Ikerre-Ado Ekiti association while those of the Idanre association yield younger but synchronous ages of 580±10 Ma (charnockite NIG 2), 593±13 Ma (charnockite NIG 3) and 587±10 Ma (granite NIG 11). The ages obtained for the rocks of the Akure-Ikerre-Ado Ekiti association very well fit the existing data on the tectonic evolution of the basement complex of Nigeria, whereas those from the Idanre area are difficult to reconcile with the current interpretation of tectonic data in this area.     

Geoelectric model and hydrochemistry of salinity affected lower Atrai floodplain aquifer,NW Bangladesh: An approach for irrigation management

In the salinity affected lower Atrai floodplain aquifer in the NW Bangladesh, geoelectric resistivity survey and hydrochemical analysis are carried out with an aim to identify fresh and saline groundwater zones; investigate the status of salinity; evaluate hydrochemical processes involved and suggest management approaches for irrigation. Here a two-fold aquifer system, inter-layered by silt, clay and silty-clay aquitard and aquiclude is classified as: upper aquifer — spatially affected by salinity of varying degrees; and lower aquifer — generally characterized by high salinity. The aquifer with resistivity values greater than 69 Ωm is safe for irrigation use. Concentrations of major ions vary as: Ca²⁺>Na⁺>Mg²⁺>K⁺ and HCO₃>Cl>NO₃>SO₄ ^2?. Groundwater is dominated by Na-Ca to Ca-Na, HCO₃-Cl-SO₄, Cl-SO₄-HCO₃ and Cl-SO₄ ^2? facies where Ca²⁺, Mg²⁺, SO₄ ^2?, HCO₃ ^?, Cl^? and NO₃ ^2? ion concentrations are statistically dominant and water is of Ca-Mg, HCO₃-SO₄-Cl and NO₃ types. Geochemically, groundwater is hard and saline to fresh water type. Salinity increases with depth, but spatially towards the southern part. Groundwater quality is a product of water-rock interaction, direct mixing and marine spraying, or fall-out of airborne marine salts, where silicate weathering is the primary source of bivalent cations. Sediment provenance of alkaline earth silicates and higher concentrations of alkalis are derived from sources other than precipitation. In general partially or fully salinity affected upper and lower aquifers in the area except in its eastern part are not suitable for tubewell irrigation. As groundwater demand for irrigation is increasing, the saline water has progressively invaded relatively fresher parts of the aquifer by upconning. So, special salinity control management approaches can be adopted through engineering techniques such as groundwater abstraction optimization, as also through scientific behavioral approaches like groundwater demand management, salt tolerant crops production. In this context, surface water conservation and rain water harvesting for domestic and irrigational uses are recommended in the salinity affected area.     

A Study of an Inhomogeneous Bianchi-I Model in Lyra Geometry

The inhomogeneous Bianchi-I model based on Lyra's geometry has been studied in the cosmological theory in presence of a massless inhomogeneous scalar field whose potential has a flat part. The field equations are solved using separation of variables and it is shown that one of the time part of the field equations are solvable for any arbitrary other cosmic scale function. Solutions for a particular form of cosmic scale (time part) is presented. This revised version was published online in July 2006 with corrections to the Cover Date.     

Gravitational Field of a Global Monopole in Lyra Geometry

We present an approximate solution of global monopole based on Lyra geometry retaining terms of the order 1/3 ² in the energy momentum tensor for a triplet scalar field. Also the gravitational field of the monopole solution has been considered. This revised version was published online in July 2006 with corrections to the Cover Date.     

Evolution of continental crust of the Aravalli craton,NW India,during the Neoarchaean–Palaeoproterozoic: evidence from geochemistry of granitoids

Neoarchaean–Palaeoproterozoic granitoids of the Aravalli craton, represented by four plutons with different ages, viz. Gingla (2.6–2.4 Ga), Ahar River (2562 Ma), Untala (2505 Ma), and Berach (2440 Ma) granitoids, are classified into three suites: TTG-like, Sanukitoid, and High-K Granitoid suite, all exhibiting negative Nb and Ti anomalies. The TTG-like suite is characterized by high contents of SiO₂, Na₂O, and LREEs, high (La/Yb)_N, low contents of K₂O, MgO, Cr, and Ni, and low (Dy/Yb)_N, suggesting that this suite formed by partial melting of a subducted basaltic slab without interacting with a mantle wedge. In contrast, the calc-alkaline Sanukitoid suite is marked by a high content of LILEs and mantle-compatible elements, which indicate that this suite formed by partial melting of a slab-fluid metasomatized mantle wedge in a subduction-related arc environment. On the other hand, the High-K Granitoid suite is characterized by high contents of SiO₂ and K₂O, and low contents of Na₂O, MgO, Cr, and Ni with variable Eu anomaly, along with high (La/Sm)_N and (La/Yb)_N, and low (Dy/Yb)_N and Nb/Th. Some high-K granitoids also exhibit A-type characteristics. These features indicate that the High-K Granitoid suite formed by melting of crustal rocks. Early Neoarchaean continental crust formation reflected a slab-melting-dominated magmatic process as evidenced by the TTG-like suite, whereas Palaeoproterozoic petrogenesis was governed by the interaction of slab melt with mantle wedge as demonstrated by the Sanukitoid suite. The High-K Granitoid suite formed during the waning stages of subduction. This study reveals that granitic rocks of the Aravalli craton evolved from slab melting in the Neoarchaean to melting of mantle wedge in the Palaeoproterozoic. Melting of older crust led to the formation of the High-K Granitoid suite.