Epikarst communities: biodiversity hotspots and potential water tracers

There is an exceptionally rich aquatic fauna in the epikarst, the skin of karst. High species richness in the epikarst, coupled with its special vulnerability as the first point of entry of nearly all toxic spills, makes its protection especially important. The epikarst fauna may also be an useful tool in tracing the potential route of pollutants. Copepods in epikarst have extremely local distributions, and their body size is such that they are largely at the mercy of directional flows. In a series of caves in southwest Slovenia and West Virginia, a significant fraction of the copepod species occur in less than 100 m of linear extent. This suggests a pattern of highly restricted lateral flow under normal conditions and the distribution of copepods could potentially be used to trace water movement. Under high flow conditions as would often be the case with toxic spill, mounding of water may increase the lateral radius of flow. Nevertheless, copepods may be useful tracers.     

Experimental and thermodynamic study of heterogeneous and homogeneous equilibria in the system NaAlSiO4-SiO2

Internally consistent thermodynamic datasets available at present call for a further improvement of the data for nepheline (Holland and Powell 1988; Berman 1991). Because nepheline is a common rock-forming mineral, an attempt has been made to improve on the present state of knowledge of its thermodynamic properties. To achieve that goal, two heterogeneous reactions involving nepheline, albite, jadeite and a-quartz in the system NaAlSiO₄-SiO₂ have been reversed bylong duration runs in the range 460 ≤ T(°C) ≤ 960 and 10 ≤ P(kbar) ≤ 22. Given sufficiently long run times, thealbite run products approach internal equilibrium with respect to their Al,Si order-disorder states. Using appropriate thermochemical, thermophysical, and volumetric data, Landau expansion for albite, and the relevant reaction reversals, a refined thermodynamic dataset (Δ_fH_i⁰ and S_i⁰) has been derived for nepheline, jadeite, a-quartz, albite, and monalbite. Our refined data agree very well with theircalorimetric counterparts, but have smaller uncertainties. The refined dataset for Δ_fH_i⁰ and S_i⁰, including their uncertainties and correlation, help generate the NaAlSiO₄-SiO₂ phase diagram including 2a confidence interval for eachP-T curve (Fig. 5). Editorial responsibility: W. Schreyer     

Fifteen days of continuous activity survey at Stromboli volcano, Italy, in late September 2000: Doppler radar, seismicity, infrared, soil humidity, and mapping of the crater region

The intention of our study was to gain new insight into the complex interplay between different types of eruption of the Stromboli volcano by combining detailed field observation with different geophysical methods. We recorded more than 600 eruptions by use of continuous Doppler radar measurements. We detected the onset of the seismic precursor and the beginning of the visible eruption by use of seismic and infrared data. Two soil samples per day were used to monitor the effect of humidity on the eruptive style. We mapped the crater region as a reference base for the long-term morphological changes of the active region and for the exact positions of our measurement systems. Two distinct types of eruption were distinguished from each other on the basis of seismic and radar data - short, wide-angle Strombolian explosions and pulsating, sharp angle fountain-like eruptions. Data and visual observations imply that weather conditions significantly effect volcanic activity. We also interpret the intensification of eruptive activity during our field study as replenishment of the reservoir with a new batch of magma in late September 2000.     

Molecular analysis of petroleum derived compounds that adsorb onto gas hydrate surfaces

Field observations have shown that some streams of water, gas and crude oil do not form gas hydrate plugs during petroleum production even when operating within thermodynamic conditions for hydrate formation. Also, when studied under controlled laboratory conditions, some oils are found to form hydrate dispersed systems whereas others form plugs. Oils with low tendency to form hydrate plugs are believed to contain natural hydrate plug inhibiting components (NICs) that adsorb onto the hydrate surface, making them less water-wet and preventing the particles from agglomerating into large hydrate clusters. The molecular structure of the NICs is currently unknown. In this work, hydrate adsorbing components were extracted from crude oils using freon hydrates as an extraction phase. The fractions were found to be enriched in polar material, and more polar material is associated with hydrates generated in biodegraded crude oils than in non-biodegraded oils. Various fractionation schemes and analytical techniques have been applied in the search for molecular characterisation. The average molecular weights were found to be approximately 500 g/mole. GC–MS chromatograms show a large UCM (Unresolved Complex Mixture). Thus, GC–MS has a limited potential for identification of compounds. A commercial biosurfactant was used as a model compound in the search for similar structures in the extracts. The results from analysis of the hydrate adsorbing components suggest that the type and structure are more important for hydrate morphology than the amount of material adsorbed.     

Transfer functions simulating the coprecipitation of trace elements in unsaturated soils

Transfer functions describing the coprecipitation of various trace elements (TE; As, Cd, Co, Cu, Cr, Mo, Ni, Pb, Zn), precipitating with iron(oxihydr)oxides from an aqueous solution, were developed and implemented in the computer model ‘Seeper’. ‘Seeper’ was developed to predict the progression of the concentrations of inorganic pollutants in unsaturated soils underneath contaminated areas and to evaluate the prospective contamination of the groundwater. Transfer functions provide a straight and simple relation between the coprecipitation of TE and easy to obtain standard soil parameters, without excessive repercussions on the usability and computation time of the model. Laboratory experiments were conducted to quantify coprecipitation in solutions with pH values ranging from 5 to 12 and containing various iron and TE concentrations. For the examined TE, the transfer functions describe the coprecipitated fraction as a function of the pH value and the concentration ratio between precipitated iron and a TE. The transfer functions yielded a good prediction of cadmium, cobalt, copper, molybdenum, nickel, and zinc (R ² from 0.73 to 0.83). As for arsenic, chromium, and lead the correlation was not as good albeit a significant influence of precipitating iron on the mobility of these elements was observed and represented in the corresponding transfer functions.     

AIDS mitigation through agriculture‐based interventions in rural contexts: Junior farmer field and life schools and future livelihoods in central Mozambique

This article summarizes findings from a research project on junior farmer field and life schools (JFFLS) as an agriculture‐based intervention to improve the livelihood prospects of children and orphans made vulnerable by HIV/AIDS in central Mozambique. In the sites investigated JFFLS have opened up concrete present and potential livelihood options in agriculture and beyond. More generally, the resource profile dynamics of participants are altered in ways that provide strong grounds to believe that the skills and knowledge they have gained will positively impact the trajectories of their future lives. In terms of HIV/AIDS mitigation, the findings recommend livelihood‐based interventions aimed at altering the vulnerability context of specific population groups.     

Blood metal levels and metal-influenced immune functions of harbour seals in captivity

Immunological blood parameters and the effects of environmental pollutants on the immune system are important to assess the health status of seals. Animals living permanently in seal centres are useful for development and validation of diagnostic tools for free-ranging animals. In this study, parameters of cellular immunity as well as metal concentrations in blood and metal influence on cell proliferation of seven seals from a seal centre were investigated repeatedly using multi-element analysis and a lymphocyte proliferation assay. The metal concentrations, except for tin and chromium, were in general comparable to those of free-ranging animals of the North Sea. The unstimulated and mitogen-stimulated lymphocyte proliferation showed strong intra- and inter-individual variability, which reflected variability in activation of the immune status. Furthermore, both immunosuppressive and stimulative influences of metals on lymphocytes were found. Summarising, the methods used in this investigation provided useful information on these animals, and their application to free-ranging animals can be recommended.     

Naturnahe Abwasserreinigung: Interdisziplinäre Zusammenarbeit von Naturwissenschaftler und Ingenieur

Sewage from scattered villages is often treated in septic tanks whose removal efficiency of biodegradable components amounts to about 35%. Viewed from the standpoint of water protection such a performance provides an insufficient prevention of water pollution. It is worth aspiring to more extensive sewage treatment, i.e. oxidation of organic matter and nitrogen compounds. This particularly applies to rural regions if scattered villages are situated in ecologically sensitive regions such as watersheds of small brooks. Here, it is resonable to emply natural methods of treating sewage such as constructed wetlands and lagoons up to a size of 1,000 population equivalents. Constructed wetlands and lagoons provide an excellent field of cooperation between biologist and engineer, because the complexity of the microbial communities and the influence of the physico-chemical and geological conditions upon the microorganisms are not yet well understood. Further interdisciplinary research work has to be done for instance in regard to the relationship between helophytes and bacteria in the biofilm on the rhizomes of the need or focussing upon effluent polishing of lagoons.     

Ceres’ spectral link to carbonaceous chondrites—Analysis of the dark background materials

Ceres’ surface has commonly been linked with carbonaceous chondrites (CCs) by ground‐based telescopic observations, because of its low albedo, flat to red‐sloped spectra in the visible and near‐infrared (VIS/NIR) wavelength region, and the absence of distinct absorption bands, though no currently known meteorites provide complete spectral matches to Ceres. Spatially resolved data of the Dawn Framing Camera (FC) reveal a generally dark surface covered with bright spots exhibiting reflectance values several times higher than Ceres’ background. In this work, we investigated FC data from High Altitude Mapping Orbit (HAMO) and Ceres eXtended Juling (CXJ) orbit (~140 m/pixel) for global spectral variations. We found that the cerean surface mainly differs by spectral slope over the whole FC wavelength region (0.4–1.0 μm). Areas exhibiting slopes ?1 constitute only ~3% of the cerean surface and mainly occur in the bright material in and around young craters, whereas slopes ≥?10% μm^?1 occur on more than 90% of the cerean surface; the latter being denoted as Ceres’ background material in this work. FC and Visible and Infrared Spectrometer (VIR) spectra of this background material were compared to the suite of CCs spectrally investigated so far regarding their VIS/NIR region and 2.7 μm absorption, as well as their reflectance at 0.653 μm. This resulted in a good match to heated CI Ivuna (heated to 200–300 °C) and a better match for CM1 meteorites, especially Moapa Valley. This possibly indicates that the alteration of CM2 to CM1 took place on Ceres.