Effects of pulp bleach plant effluents on hepatic xenobiotic biotransformation enzymes in fish: Laboratory and field studies

The present preliminary report on studies of the influence of pulp bleach plant effluents on hepatic biotransformation enzymes in fish is a part of a major characterisation of biochemical and physiological effects of effluents from pulp industries in Sweden. Our studies on the xenobiotic biotransformation enzymes demonstrate, so far, that the pulp effluents have the potential to strongly induce 7-ethoxyresorufin-O-deethylase activity (EROD) in fish liver and that fish living in the receiving water of an effluent from a pulp bleach plant have induced hepatic EROD activities as well as higher hepatic UDP glucuronyltransferase activities than those living in an unpolluted area. It is thus apparent that measures of induction of biotransformation enzymes in fish liver may be a useful approach in monitoring the presence of potential hazardous compounds released from pulp industries.     

Using rainfall-runoff modeling to interpret lake level data

Using water balance computations, the behavior of different kinds of lakes is discussed. Simple analytical expressions relating water level to hydrological conditions and lake bathymetry are given. The importance of knowing the river basin area when analyzing lake levels is stressed. A conceptual rainfall-runoff model including lake routing is used to simulate runoff and lake levels and to compute quasi-steady state conditions and long-term transient situations. It is suggested that models can be used to construct curves relating lake levels to precipitation and lake evaporation. By comparing with paleo-lake levels, the annual precipitation related to these levels can be found, provided information is available about the seasonal distribution of the precipitation.     

Impact of warmer climate on melt and evaporation for the rainfed, snowfed and glacierfed basins in the Himalayan region

The impact of warmer climate on melt and evaporation was studied for rainfed, snowfed and glacierfed basins located in the western Himalayan region. Hydrological processes were simulated under current climatic conditions using a conceptual hydrological model, which accounts for the rainfall–runoff, evaporation losses, snow and glacier melt. After simulations of daily observed streamflow (R²=0.90) for 6 years, the model was used to study the impact of warmer climate on melt and evaporation. Based on the future projected climatic scenarios in the study region, three temperature scenarios (T+1, T+2 and T+3 °C) were adopted for quantifying the effect of warmer climate. The comparison of the effect of warmer climate on different types of basins indicated that the increase in evaporation was the maximum for snowfed basins. For a T+2 °C scenario, the annual evaporation for the rainfed basins increased by about 12%, whereas for the snowfed basins it increased by about 24%. The high increase of the evaporation losses would reduce the runoff. It was found that under a warmer climate, melt was reduced from snowfed basins, but increased from glacierfed basins. For a T+2 °C scenario, annual melt was reduced by about 18% for the studied snowfed basin, while it increased by about 33% for the glacierfed basin. Thus, impact of warmer climate on the melt from the snowfed and glacierfed basins was opposite to each other. The study suggests that out of three types of basins, snowfed basins are more sensitive in terms of reduction in water availability due to a compound effect of increase in evaporation and decrease in melt. For a complex type of basin, the decrease in melt from seasonal snow may be counterbalanced by increase in melt from glaciers. However, on long-term basis, when the areal extent of glaciers will decrease due to higher melt rate, the water availability from the complex basins will be reduced.     

Multi-species chemical data assimilation with the Danish Eulerian hemispheric model: system description and verification

Satellite retrievals of atmospheric composition provide a wealth of data on a global scale. These complement results from atmospheric chemistry-transport models (CTMs), and can be combined using data assimilation. We present two assimilation schemes coupled to the Danish Eulerian Hemispheric Model (DEHM), a three-dimensional, off-line CTM with full photochemistry: a variant on the ensemble Kalman filter and the three-dimensional variational scheme. The aim of this paper is to describe the two schemes and present an initial assessment of their impacts on model skill. Retrievals of multiple atmospheric trace gases are assimilated, namely: NO₂ tropospheric column densities, CH₄ total column densities, and partial column concentrations of O₃, CO and CH₄; these data are retrieved from four satellite sensors. Data for each species are assimilated independently of one another, and other species are only adjusted indirectly via the model’s chemistry and dynamics. Assimilation results are compared with measurements from surface monitoring stations and other satellite retrievals, and preliminary validation results are presented.Reference simulations (without assimilation) grossly underestimate surface CO concentrations, and both assimilation schemes eliminate this large and systematic model bias. The assimilation improves the spatial correlation of modelled CO with surface observations, and improves the spatial correlation between forecasts and retrievals for CO, NO₂ and O₃. Results for CH₄ show a loss of skill due to a mismatch in model bias between two assimilated CH₄ data-sets. Finally, we discuss differences in methodology and results between this paper and a recent study on multi-species chemical data assimilation. Joint optimisation of initial conditions and emission rates offers a promising direction for improving modelled boundary-layer concentrations.     

Desertification in Africa — A critique and an alternative approach

This article critically reviews the international debate on desertification, its status and rate as well as causes and consequences. The article rejects the commonly used concept of a degrading environment, but tries to explain the environmental problems as symptoms of a wider economic and political crisis. An alternative approach applying systems analysis of the entire socio-economic-system to the study of desertification and land degradation is discussed, with examples from the Western Sudan.     

Water flow and swelling pressure in non-saturated bentonite-based clay barriers

The water uptake of 10 and 20% bentonite—sand mixtures and of 100% pure bentonite was studied experimentally. The results were compared with calculated water content distributions to study the usefulness of the diffusion equation. The relation between the swelling pressure and the degree of saturation of a bentonite was also studied.     

Experimental evidence for an ascending microflow of geogas in the ground

A microflow of free ascending gas has been observed in 26 out of 30 tested boreholes at three different sites. The flow rates vary between 60 × 10⁻⁴ and 4 cm³/min m² horizontally projected borehole area. Sampling has been made in ground boreholes as well as in holes drilled downwards from the lowest levels in two mines. The composition of the gas varies considerably. The main components of the gas are nitrogen, argon, oxygen and methane. Traces of heavier hydrocarbons are observed. At the site of the ground holes, only traces of methane are observed. In all sampled holes the existence of free oxygen is observed. The nitrogen/argon quotient is close to the atmospheric quotient in all sampled holes, indicating a partly atmospheric origin of the gas. The existence of methane and traces of heavier hydrocarbons indicates the existence of a second source.     

Temperature dependence of calcite dissolution kinetics between 1 and 62°C at pH 2.7 to 8.4 in aqueous solutions

The kinetics of calcite dissolution in aqueous KCl-solutions far from equilibrium, between 1 and 62°C in the pH-range 2.7 to 8.4 have been investigated using a rotating disc apparatus. At neutral and alkaline pH in the mixed kinetic regime the empirical apparent activation energy (EAAE) for the surface chemical reaction rate constant is 54 ± 4 kJ mole^?1 for Carrara marble and 46 ± 4 kJ mole^?1 for Iceland spar. Under similar conditions the EAAE of the transport rate constant increases with decreasing temperature, but has a mean value of 27 ± 2 kJ mole^?1. The corresponding diffusion coefficient has a mean EAAE of 37 ± 3 kJ mole^?1 and this high EAAE is consistent with transport dependence on product diffusion in this H⁺-independent regime.In contrast, in acid solutions, where the rate approaches end-member transport control, the EAAE of the diffusion coefficient is 16 kJ mole^?1, also decreasing with increasing temperature. This is compatible with H⁺-diffusion to the surface being rate-controlling.In inhibitor-free natural systems, calcite dissolution kinetics far from equilibrium can be described in terms of three regimes: an H⁺-dependent regime (pH < 4 at 25°C), a transition regime (4 < pH < 5.5 at 25°C) and an H⁺-independent regime (pH > 5.5 at 25°C). At lower temperatures these boundaries move to higher pH values. The presence of inhibitors in natural systems may enhance surface controlled kinetics.     

The acute aquatic toxicity of some substances carried by ships

At the request of the International Maritime Organization (IMO), our laboratory has performed acute toxicity testing with 43 substances, for which insufficient or no data had been available for hazard rating concerning damage to marine living resources.     

Numerical modelling of the energy and water cycle of the Baltic Sea

Summary This paper will introduce the Baltex research programme and summarize associated numerical modelling work which has been undertaken during the last five years. The research has broadly managed to clarify the main mechanisms determining the water and energy cycle in the Baltic region, such as the strong dependence upon the large scale atmospheric circulation. It has further been shown that the Baltic Sea has a positive water balance, albeit with large interannual variations. The focus on the modelling studies has been the use of limited area models at ultra-high resolution driven by boundary conditions from global models or from reanalysis data sets. The programme has further initiated a comprehensive integration of atmospheric, land surface and hydrological modelling incorporating snow, sea ice and special lake models. Other aspects of the programme include process studies such as the role of deep convection, air sea interaction and the handling of land surface moisture. Studies have also been undertaken to investigate synoptic and sub-synoptic events over the Baltic region, thus exploring the role of transient weather systems for the hydrological cycle. A special aspect has been the strong interests and commitments of the meteorological and hydrological services because of the potentially large societal interests of operational applications of the research. As a result of this interests special attention has been put on data-assimilation aspects and the use of new types of data such as SSM/I, GPS-measurements and digital radar. A series of high resolution data sets are being produced. One of those, a 1/6 degree daily precipitation climatology for the years 1996–1999, is such a unique contribution. The specific research achievements to be presented in this volume of Meteorology and Atmospheric Physics is the result of a cooperative venture between 11 European research groups supported under the EU-Framework programmes. Received December 15, 2000 Revised March 28, 2001