Spatial Modeling of Geometallurgical Properties: Techniques and a Case Study

High-resolution spatial numerical models of metallurgical properties constrained by geological controls and more extensively by measured grade and geomechanical properties constitute an important part of geometallurgy. Geostatistical and other numerical techniques are adapted and developed to construct these high-resolution models accounting for all available data. Important issues that must be addressed include unequal sampling of the metallurgical properties versus grade assays, measurements at different scale, and complex nonlinear averaging of many metallurgical parameters. This paper establishes techniques to address each of these issues with the required implementation details and also demonstrates geometallurgical mineral deposit characterization for a copper–molybdenum deposit in South America. High-resolution models of grades and comminution indices are constructed, checked, and are rigorously validated. The workflow demonstrated in this case study is applicable to many other deposit types.     

Do sedentary behavior and physical activity spatially cluster? Analysis of a population-based sample of Boston adolescents

Sedentary behavior and lack of physical activity are key modifiable behavioral risk factors for chronic health problems, such as obesity and diabetes. Little is known about how sedentary behavior and physical activity among adolescents spatially cluster. The objective was to detect spatial clustering of sedentary behavior and physical activity among Boston adolescents. Data were used from the 2008 Boston Youth Survey Geospatial Dataset, a sample of public high school students who responded to a sedentary behavior and physical activity questionnaire. Four binary variables were created: (1) TV watching (>2 h/day), (2) video games (>2 h/day), (3) total screen time (>2 h/day); and (4) 20 min/day of physical activity (≥5 days/week). A spatial scan statistic was utilized to detect clustering of sedentary behavior and physical activity. One statistically significant cluster of TV watching emerged among Boston adolescents in the unadjusted model. Students inside the cluster were more than twice as likely to report >2 h/day of TV watching compared to respondents outside the cluster. No significant clusters of sedentary behavior and physical activity emerged. Findings suggest that TV watching is spatially clustered among Boston adolescents. Such findings may serve to inform public health policy-makers by identifying specific locations in Boston that could provide opportunities for policy intervention. Future research should examine what is linked to the clusters, such as neighborhood environments and network effects.     

Biodegradation and environmental behavior of biodiesel mixtures in the sea: An initial study

Biodiesel, a mixture of fatty acid methyl esters (FAMEs) derived from animal fats or vegetable oils, is rapidly moving towards the mainstream as an alternative source of energy. However, the behavior of biodiesel, or blends of biodiesel with fossil diesel, in the marine environment have yet to be fully understood. Hence, we performed a series of initial laboratory experiments and simple calculations to evaluate the microbial and environmental fate of FAMEs. Aerobic seawater microcosms spiked with biodiesel or mixtures of biodiesel and fossil diesel revealed that the FAMEs were degraded at roughly the same rate as n-alkanes, and more rapidly than other hydrocarbon components. The residues extracted from these different microcosms became indistinguishable within weeks. Preliminary results from physical-chemical calculations suggest that FAMEs in biodiesel mixtures will not affect the evaporation rates of spilled petroleum hydrocarbons but may stabilize oil droplets in the water column and thereby facilitate transport.     

Climate,Not Atmospheric Deposition,Drives the Biogeochemical Mass-Balance of a Mountain Watershed

Watershed mass-balance methods are valuable tools for demonstrating impacts to water quality from atmospheric deposition and chemical weathering. Owen Bricker, a pioneer of the mass-balance method, began applying mass-balance modeling to small watersheds in the late 1960s and dedicated his career to expanding the literature and knowledge of complex watershed processes. We evaluated long-term trends in surface-water chemistry in the Loch Vale watershed, a 660-ha. alpine/subalpine catchment located in Rocky Mountain National Park, CO, USA. Many changes in surface-water chemistry correlated with multiple drivers, including summer or monthly temperature, snow water equivalent, and the runoff-to-precipitation ratio. Atmospheric deposition was not a significant causal agent for surface-water chemistry trends. We observed statistically significant increases in both concentrations and fluxes of weathering products including cations, SiO₂, SO₄ ^2?, and ANC, and in inorganic N, with inorganic N being primarily of atmospheric origin. These changes are evident in the individual months June, July, and August, and also in the combined June, July, and August summer season. Increasingly warm summer temperatures are melting what was once permanent ice and this may release elements entrained in the ice, stimulate chemical weathering with enhanced moisture availability, and stimulate microbial nitrification. Weathering rates may also be enhanced by sustained water availability in high snowpack years. Rapid change in the flux of weathering products and inorganic N is the direct and indirect result of a changing climate from warming temperatures and thawing cryosphere.     

Jitter radiation images, spectra and light curves from a relativistic spherical blastwave

We consider radiation emitted by the jitter mechanism in a Blandford–McKee self-similar blastwave. We assume the magnetic field configuration throughout the whole blastwave meets the condition for the emission of jitter radiation and we compute the ensuing images, light curves and spectra. The calculations are performed for both a uniform and a wind environment. We compare our jitter results to synchrotron results. We show that jitter radiation produces slightly different spectra than synchrotron, in particular between the self-absorption and the peak frequency, where the jitter spectrum is flat, while the synchrotron spectrum grows as  ν^1/3  . The spectral difference is reflected in the early decay slope of the light curves. We conclude that jitter and synchrotron afterglows can be distinguished from each other with good quality observations. However, it is unlikely that the difference can explain the peculiar behaviour of several recent observations, such as flat X-ray slopes and uncorrelated optical and X-ray behaviour.     

The Effects of Fault-Zone Cementation on Groundwater Flow at the Field Scale

Fault zones are an important control on fluid flow, affecting groundwater supply, contaminant migration, and carbon storage. However, most models of fault seal do not consider fault zone cementation, despite the recognition that it is common and can dramatically reduce permeability. In order to study the field-scale hydrogeologic effects of fault zone cementation, we conducted a series of aquifer pumping tests in wells installed within tens of meters of the variably cemented Loma Blanca Fault, a normal fault in the Rio Grande Rift. In the southern half of the study area, the fault zone is cemented by calcite; the cemented zone is 2-8 m wide. In the center of the study area, the cemented fault zone is truncated at a buttress unconformity that laterally separates hydrostratigraphic units with a ∼40X difference in permeability. The fault zone north of the unconformity is not cemented. Constant rate pumping tests indicate that where the fault is cemented, it is a barrier to groundwater flow. This is an important demonstration that a fault with no clay in its core and similar sediment on both sides can be a barrier to groundwater flow by virtue of its cementation; most conceptual models for the hydrogeology of faults would predict that it would not be a barrier to groundwater flow. Additionally, the lateral permeability heterogeneity across the unconformity imposes another important control on the local flow field. This permeability discontinuity acts as either a no-flow boundary or a constant head boundary, depending on the location of pumping.     

Validation of Walk Scores and Transit Scores for estimating neighborhood walkability and transit availability: a small-area analysis

We investigated the validity of Walk Scores and Transit Scores from the Walk Score website using several objective geographic information systems (GIS) measures of neighborhood walkabiltiy and transit availability based on 400- and 800-m street network buffers. Address data come from the 2008 Boston Youth Survey Geospatial Dataset, a school-based sample of public high school students in Boston, MA with complete residential address information (n = 1,292). GIS data were used to create multiple objective measures of neighborhood walkability and transit availability. We also obtained Walk Scores and Transit Scores. We calculated Spearman correlations of Walk Scores and Transit Scores with the GIS neighborhood walkability/transit availability measures as well as Spearman correlations accounting for spatial autocorrelation. Several significant correlations were observed between Walk Score and 400-m buffer GIS measures of neighborhood walkability; all significant correlations were found for the 800-m buffer. All correlations between Transit Scores and GIS measures of neighborhood transit availability were also significant (all p < 0.0001). However, the magnitude of correlations varied by the GIS measure and neighborhood definition. Relative to the 400-m buffer, correlations for the 800-m buffer were higher. This study suggests that Walk Score is a good, convenient tool to measure certain aspects of neighborhood walkability and transit availability (such as density of retail destinations, density of recreational open space, intersection density, residential density and density of subway stops). However, Walk Score works best at larger spatial scales.     

The use of reference models from a priori data to guide 2D inversion of electrical resistivity tomography data

Clay-rich till plains cover much of the UK. Such sites are attractive locations for landfills, since clay aquitards lower the risk of landfill leachate entering groundwater. However, such tills often contain sand and gravel bodies that can act as leachate flow routes. Such bodies may not be detected by conventional site investigation techniques such as drilling boreholes and trial pitting. A method of guided inversion, where a priori data are used to construct structural reference models for use in inverting electrical resistivity tomography data, was proposed as a tool to improve the detection of sand and gravel bodies within clay-rich till sequences.
Following a successful 2D guided inversion synthetic modelling study, a field study was undertaken. Wenner 2D electrical resistivity tomography lines, resistivity cone penetrometry bores and electromagnetic induction ground resistivity data were collected over a site on the East Yorkshire coast, England, where sand and gravel lenses were known to exist from cliff exposures. A number of equally valid geoelectrical models were constructed using the electromagnetic and resistivity cone data. These were used as structural reference models in the inversion of the resistivity tomography data. Blind inversion using an homogenous reference model was also carried out for comparison.
It was shown for the first time that the best solution model produced by 2D inversion of one data set with a range of structural reference models could be determined by using the l ₂ model misfit between the solution models and associated reference models (reference misfit) as a proxy for the l ₂ misfit between the solution models and the synthetic model or 'best-guess' geoelectrical model (true misfit). The 2D methodology developed here is applicable in clay-rich till plains containing sand and gravel bodies throughout the UK.