Effects of Seawater Acidification on Early Development of Clam Cyclina sinensis

Anthropogenic emission of atmospheric carbon dioxide(CO_2) has led to a rapid increase in atmospheric CO_2 concentration. Increasing atmospheric CO_2 can reduce seawater pH and carbonate ions, which may adversely affect the survival of the larvae of calcareous animals. Cyclina sinensis is a commercially and ecologically important species in several Asian countries. Living in coast shallow waters, this species has experienced the coastal environmental changes frequently throughout its life cycle. In this study, we simulated possible future seawater pH values including 8.2, 7.8 and 7.4 and examined the effects of ocean acidification on the early development of C. sinensis. Clam embryos were incubated for 48 h(2 d) in control and high-CO_2 seawater to compare embryogenesis, larval growth and swimming behavior. Fertilization rate was quite sensitive to pH, and moderate acidification could induce a significant decrease in fertilization rate. However, only extreme acidification could bring significant negative effect to hatching rate, body size, and average path velocity of trochophora. Moreover, with seawater acidification, C. sinensis needs much more time to reach the same developmental stage, which increases the risk of larva survival. Together with recent studies demonstrating negative impacts of high CO_2 on fertilization and larva swimming behavior, the results imply a future decrease of C. sinensis populations in oceans if its acclimation to the predicted environmental alteration does not occur.     

湿地水文过程与植被响应研究进展与案例分析

生态水文学是20世纪90年代兴起的一门研究生态过程和生态格局水文机制的新学科。湖泊湿地作为中国5大类天然湿地类型之一,湖泊湿地生态水文学的研究业已成为生态水文学的研究的一个重要对象和分支,其核心在于研究湖泊湿地生态系统中多时空尺度的水文与生物格局、过程的耦合特征及其相互作用。论文首先概述了湖泊湿地生态水文学的研究进展,包括其基本理论,内涵、外延及其主要研究内容;凝练了湖泊湿地生态水文学研究的方法体系、思路及框架;针对目前湖泊湿地生态水文学研究中存在的问题及薄弱环节,提出了湖泊湿地生态水文学未来研究的发展趋势和亟需加强研究的重点方向。在此基础上,以长江中游的典型通江湖泊湿地——鄱阳湖湿地为例,通过开展的湖泊湿地生态水文过程与模拟研究的典型案例,阐述了鄱阳湖湖泊湿地生态水文过程的变化及其植被响应研究的最新进展和研究成果。论文对于构建涵盖湖泊湿地水资源、湖泊湿地生态景观格局与流域管理、湖泊湿地生物多样性保育以及湿地资源可持续利用与生态管理等方向在内的战略研究体系,完善湿地生态水文研究与流域生态与管理的技术支撑体系具有重要的指导意义和实践价值。     

纺织品中偶氮染料还原液内芳香胺的电喷雾电离质谱分析

在优化的条件下,用电喷雾电离质谱(ESI-MS)检测了多种纺织品中由偶氮染料还原获得的芳香胺。当毛细管温度为100℃、鞘气流速为25单位、进样流速为10μL/min、电压为5kV时,信号的总离子流强度高且较稳定。实验分析了19种致癌芳香胺标准溶液的二级质谱,获得了相应物质的特征碎片离子;在此基础上,建立了基于ESI-MS对毛巾、棉布等样品中芳香胺进行快速定性分析的方法,具有灵敏度高、特异性好、检测速度快等优点。     

Zircon U–Pb ages, Hf and O isotopes constrain the crustal architecture of the ultrahigh-pressure Dabie orogen in China

The crustal structure of the Dabie orogen was reconstructed by a combined study of U–Pb ages, Hf and O isotope compositions of zircons from granitic gneiss from North Dabie, the largest lithotectonic unit in the orogen. The results were deciphered from metamorphic history to protolith origin with respect to continental subduction and exhumation. Zircon U–Pb dating provides consistent ages of 751 ± 7 Ma for protolith crystallization, and two group ages of 213 ± 4 to 245 ± 17 Ma and 126 ± 4 to 131 ± 36 Ma for regional metamorphism. Majority of zircon Hf isotope analyses displays negative ε_Hf(t) values of − 5.1 to − 2.9 with crust Hf model ages of 1.84 to 1.99 Ga, indicating protolith origin from reworking of middle Paleoproterozoic crust. The remaining analyses exhibit positive ε_Hf(t) values of 5.3 to 14.5 with mantle Hf model ages of 0.74 to 1.11 Ga, suggesting prompt reworking of Late Mesoproterozoic to Early Neoproterozoic juvenile crust. Zircon O isotope analyses yield δ¹⁸O values of − 3.26 to 2.79‰, indicating differential involvement of meteoric water in protolith magma by remelting of hydrothermally altered low δ¹⁸O rocks. North Dabie shares the same age of Neoproterozoic low δ¹⁸O protolith with Central Dabie experiencing the Triassic UHP metamorphism, but it was significantly reworked at Early Cretaceous in association with contemporaneous magma emplacement. The Rodinia breakup at about 750 Ma would lead to not only the reworking of juvenile crust in an active rift zone for bimodal protolith of Central Dabie, but also reworking of ancient crust in an arc-continent collision zone for the North Dabie protolith. The spatial difference in the metamorphic age (Triassic vs. Cretaceous) between the northern and southern parts of North Dabie suggests intra-crustal detachment during the continental subduction. Furthermore, the Dabie orogen would have a three-layer structure prior to the Early Cretaceous magmatism: Central Dabie in the upper, North Dabie in the middle, and the source region of Cretaceous magmas in the lower.     

黑龙江省金厂金矿床J0矿体流体地球化学研究

黑龙江省东宁县金厂金矿床是最新发现的特大型金矿床,目前探获黄金资源量86吨,它位于中亚造山带东端的吉黑成矿带,是与中生代中酸性岩浆活动有关的复杂成矿系统,矿化类型可能包括了斑岩型、爆破角砾岩型、浅成低温热液型.研究表明,高丽沟J0号矿体为爆破角砾岩型,热液成矿过程经历了早、中、晚3个阶段,分别形成以石英-黄铁矿、多金属硫化物-石英和碳酸盐为代表的矿物组合,中阶段矿物含自然金最多,次为早阶段矿物.初始成矿流体系统为高温、高盐度、高氧逸度、富CO2的岩浆热液;经减压沸腾,CO2等挥发分大量逸出,流体温度、盐度和氧逸度下降,导致大量金属硫化物及自然金快速沉淀;大气降水混入导致晚阶段流体低温、低盐度、贫CO2,对成矿贡献甚微.总体而言,成矿流体盐度高(11.70%～37.81%NaCl.eq),成矿作用发生在中-高温(238.3～425.7℃)的浅成环境(深633m～2736m).岩浆-流体成矿系统富CO2应发育于大陆碰撞造山带的伸展构造背景,而非大洋板块俯冲诱发的岩浆弧背景.     

注浆堵漏止水技术在基坑工程中的应用

总结了用潜孔锤成孔,注入水泥浆、水玻璃双浆液封堵基坑面以上的明水,并利用袖阀管压力注浆封堵基坑面以下暗水的设计方案与施工方法.     

河南洛宁段河金矿流体包裹体研究和矿床成因

河南省洛宁县段河石英脉型金矿主要包括石寨沟和岭东两个矿区,分别由3～4条含金石英脉构成。矿化过程从早到晚包括石英-黄铁矿、石英-多金属硫化物和石英-碳酸盐等3个阶段．其中中阶段金矿化最强,次为早阶段。各阶段石英中流体包裹体以气液两相包裹体为主．次为纯液体包裹体。激光拉曼测试表明,气液两相包裹体的液相为H2O,气相主要为Ho和CO2混合、纯H2O,次为纯CO2;纯液体包裹体为纯H2O。石寨沟矿区包裹体均一温度从早到晚依次为240．9～315．9℃．188．7～304．5℃,137．3～259．3℃：流体盐度变化依次为（6．74～12．85）wt%NaCl．eq,（2．41～8．68）wt％NaCl．eq,（2．24-7．86）wt%NaCl．eq。岭东矿区均一温度从早到晚依次为303．7-343．1℃,251．8-325．4℃,305．7～355．0℃：流体盐度变化依次为（5．11～11．70）wt％NaCl．eq,（2．74-10．11）wt％NaCl．eq,（0．53-6．74）wt％NaCl．eq。两矿区主成矿期流体均为中温、低盐度,早阶段流体为改造热液和变质热液的混合体,含一定量CO2,且流体CO2含量和盐度从早到晚逐渐降低。石寨沟矿区包裹体均一温度逐渐降低,而岭东矿区包裹体均一温度先降后升,加之岭东矿区各阶段成矿温度均高于石寨沟矿区．表明成矿流体系统主要受岩浆热驱动,岭东矿区更靠近岩体,且在晚阶段又有脉动性的岩浆加热．段河金矿区南部存在隐伏岩体。     

台风Haitang(0505)登陆过程地形影响的数值模拟试验

以2005年严重影响我国的登陆台风Haitang为研究对象,在用MM5模式成功模拟台风登陆前后路径、强度、降水以及结构特征的基础上,通过地形敏感性试验,分析了地形对台风的影响及其机理。结果表明:台风在经过台湾及其后在福建登陆期间的异常路径是地形诱生低压发生发展的结果;在降水强度上东部沿海特殊地形对台风北侧东南气流的辐合抬升使得暴雨增幅度1倍以上;地形对台风强度也有一定影响,约为4～5hPa。通过对有无地形影响时台风结构的比较发现地形影响主要在低层,使得高度场分裂两个中心,低层台风主体受山脉阻挡在位置上落后于高层。分析还发现台风登陆前夕移动方向西侧相当位温向西倾斜也可能与地形有关。     

裙带菜褐藻糖胶的分离及部分理化性质研究

以裙带菜为原材料,采用水提法从裙带菜中分离褐藻糖胶,Sevag法去蛋白,乙醇分步沉淀法进行初步纯化。结果表明裙带菜褐藻糖胶的最适提取温度为80℃,时间为8 h,加水量为1∶30,在最适条件下的提取率为1.72%,蛋白质含量为5.44%。同时本研究对部分理化性质进行了研究。结果是特性粘度为5 m pa.s,pH为8.50,含有硫酸基。