Ice in the Southern Coalsack

To better understand the conditions under which ice mantles form on grains in molecular clouds, three globules in the Southern Coalsack have been searched for the presence of H₂O ice. Given the total lack of star formation in the Coalsack, it is an ideal site for studying unprocessed icy molecular mantles. In our sample of eight field stars lying behind the Coalsack we detect strong H₂O ice absorption in the lines of sight to two stars and possible weak absorption in four others. We estimate H₂O ice column densities or upper limits for these lines of sight. Compared to dark clouds such as Taurus, the Coalsack H₂O ice column densities are lower than expected given the quiescent nature of the Coalsack region. It is possible that the chemical evolution of the Coalsack may simply be at too early a stage for significant ice mantles to appear on the grains, except perhaps in the densest parts of some of the globules. Alternatively, the presence or absence of ice absorption may be related to the distribution of dust along each line of sight, specifically, the relative contributions of dense globules and a more extended diffuse component. For example, our observations are consistent with an ice threshold extinction similar to that observed in the Taurus dark cloud if extinction amounting to   A _V∼5  towards Globules 2 and 3 arises in the extended component. Globule 1 appears to have no extended component.     

Grain alignment in dense interstellar environments: spectropolarimetry of the 4.67-μm CO-ice feature in the field star Elias 16 (Taurus dark cloud)

We present spectropolarimetry of the solid CO feature at 4.67 μm along the line of sight to Elias 16, a field star background to the Taurus dark cloud. A clear increase in polarization is observed across the feature with the peak of polarization shifted in wavelength relative to the peak of absorption. This shows that dust grains in dense, cold environments (temperatures ∼20 K or less) can align and produce polarization by dichroic absorption. For a grain model, consisting of a core with a single mantle, the polarization feature is best modelled by a thick CO mantle, possibly including 10 per cent water-ice, with the volume ratio of mantle to bare grain of ∼5. Radiative torques could be responsible for the grain alignment provided the grain radius is at least 0.5 μm. This would require the grain cores to have a radius of at least 0.3 μm, much larger than grain sizes in the diffuse interstellar medium. Sizes of this order seem reasonable on the basis of independent evidence for grain growth by coagulation, as well as mantle formation, inside dense clouds.     

The 10-μm profile of molecular-cloud and diffuse ISM silicate dust

High signal-to-noise ratio spectra are presented of the 10-μm silicate absorption feature in lines of sight towards Elias 16 and 18 in the Taurus dark cloud, and towards the heavily reddened supergiant Cyg OB2 no. 12. The observations are fitted with laboratory and astronomical spectra to produce intrinsic absorption profiles. These features, which represent molecular-cloud and diffuse ISM dust respectively, are better fitted with emissivity spectra of the Trapezium and μ Cephei than they are with those of laboratory, terrestrial, or other observations of circumstellar silicates. The difference in width between the silicate band in the two environments can be almost entirely ascribed to a broad excess absorption in the long-wavelength wing of the profiles, which is much stronger in the molecular-cloud lines of sight, and possibly reflects grain growth in the denser environment. Limits are placed on the strength of fine spectral structure; if there is a crystalline silicate component in these spectra, it is most likely to be serpentine. Column-density upper limits for methanol and the photolysis product hexamethylenetetramine (HMT) are less than a few per cent of those of water ice and silicates.     

The ratio of total to selective absorption in dark clouds

Evidence relating to the value ofR=A _V/E_B-V appropriate to discrete dark clouds in the interstellar medium is discussed. The polarimetric method of evaluatingR recently proposed by Serkowski, Mathewson and Ford gives results consistent with extinction curve determinations. A value ofR～4.4 appears to apply to the most reddened stars in the ? Oph complex, suggesting the existence of an upper size limit for the grains. If the grains grow by accretion of the heavier elements from the surrounding gas, as suggested by Carrasco, Strom and Strom, then the availability of material sets a limitation on mantle growth consistent with the observed increase inR.     

Infrared photometry,extinctions andR values for some Northern Milky Way stars

Infrared wideband photometry for 21 early-type stars in the Northern Milky Way is used to determine extinction values by the colour-difference method. The mean extinction curve is similar to the van de Hulst theoretical curve No. 15, and there is no significant difference in the results for stars lying towards and away from nebulosity. None of the stars exhibit infrared excesses at 3.5 . A mean value ofR=3.15±0.15 is deduced for the ratio of total to selective extinction.R is found to be normal towards the open cluster IC 1805 for which high values have been suggested; a distance of 2.0±0.2 kpc is deduced for this cluster.Visiting astronomer, Kitt Peak National Observatory, which is operated by the Association of Universities for Research in Astronomy, Inc., under contract with the National Science Foundation.     

ISO-SWS Observations of Weak Bands of Trace Components of Ices Towards the Young Stellar Object W 33A

ISO-SWS observations of the highly obscured young stellar object W 33A reveal two broad absorption features centered at 7.24 and 7.40 μm. The position and width of these features indicates that they are due to the XH bending mode (X = C, N, or O) of molecules in the solid state. Comparison to interstellar ice analogs shows that the 7.24 μm band can be well matched by solid formic acid (HCOOH), while the 7.40 μm band can be fitted both by the formate ion (HCOO-) and acetaldehyde (CH3HCO). The laboratory spectra reveal additional strong features of these molecules which should make a more definite identification straightforward. This revised version was published online in August 2006 with corrections to the Cover Date.     

Cosmic evolution of the biogenic elements and compounds

Summary This paper traces the evolution of the biogenic elements H, C, N, O, P and S from their creation by cosmic nucleosynthesis to their inclusion in living systems on the surface of the Earth. Evidence for the presence of significant prebiotic molecules in interstellar clouds and in primitive meteorites is reviewed. The possible relevance of this discovery to the origin of life on Earth is assessed in the light of evidence suggesting that such molecules could not easily be synthesized in a primitive CO₂-dominated terrestrial atmosphere.     

Chemistry of the organic-rich hot core G327.3-0.6

We present gas-phase abundances of species found in the organic-rich hot core G327.3-0.6. The data were taken with the Swedish-ESO Submillimetre Telescope (SEST). The 1-3 mm spectrum of this source is dominated by emission features of nitrile species and saturated organics, with abundances greater than those found in many other hot cores, including Sgr B2 and OMC-1. Population diagram analysis indicates that many species (CH3CN, C2H3CN, C2H5CN, CH3OH, etc.) have hot components that originate in a compact (~2") region. Gas-phase chemical models cannot reproduce the high abundances of these molecules found in hot cores, and we suggest that they originate from processing and evaporation of icy grain mantle material. In addition, we report the first detection of vibrationally excited ethyl cyanide and the first detection of methyl mercaptan (CH3SH) outside the Galactic center.