Growing up green on serpentine soils: Biogeochemistry of serpentine vegetation in the Central Coast Range of California

Serpentine soils derived from the weathering of ultramafic rocks and their metamorphic derivatives (serpentinites) are chemically prohibitive for vegetative growth. Evaluating how serpentine vegetation is able to persist under these chemical conditions is difficult to ascertain due to the numerous factors (climate, relief, time, water availability, etc.) controlling and affecting plant growth. Here, the uptake, incorporation, and distribution of a wide variety of elements into the biomass of serpentine vegetation has been investigated relative to vegetation growing on an adjacent chert-derived soil. Soil pH, electrical conductivity, organic C, total N, soil extractable elements, total soil elemental compositions and plant digestions in conjunction with spider diagrams are utilized to determine the chemical relationships of these soil and plant systems. Plant available Mg and Ca in serpentine soils exceed values assessed in chert soils. Magnesium is nearly 3 times more abundant than Ca in the serpentine soils; however, the serpentine soils are not Ca deficient with Ca concentrations as high as 2235 mg kg⁻¹. Calcium to Mg ratios (Ca:Mg) in both serpentine and chert vegetation are greater than one in both below and above ground tissues. Soil and plant chemistry analyses support that Ca is not a limiting factor for plant growth and that serpentine vegetation is actively moderating Mg uptake as well as tolerating elevated concentrations of bioavailable Mg. Additionally, results demonstrate that serpentine vegetation suppresses the uptake of Fe, Cr, Ni, Mn and Co into its biomass. The suppressed uptake of these metals mainly occurs in the plants’ roots as evident by the comparatively lower metal concentrations present in above ground tissues (twigs, leaves and shoots). This research supports earlier studies that have suggested that ion uptake discrimination and ion suppression in the roots are major mechanisms for serpentine vegetation to tolerate the chemistry of serpentine soils.     

Sedimentary development of the Louisiana continental shelf related to sea level cycles: Part II—seismic response

Cyclic sequences occur worldwide in nearly every stratigraphic sequence; they are particularly well-developed in fluvial and deltaic sediments that have been influenced by high-frequency eustatic sea-level fluctuations. The large data base for this study (including 471 deep foundation borings, thousands of line kilometers of high-resolution seismic, and sedimentological and dating analyses) represents the most complete information on high-resolution chronostratigraphy and lithostratigraphy that is available on any modern continental shelf/upper slope. These data are used to document sedimentological characteristics and high-resolution seismic responses during three complete sea-level cycles over the entire continental shelf/upper slope of offshore Louisiana. Examination of high-resolution seismic records indicates that well-defined, high-amplitude, laterally continuous reflectors correlate with rising and high stand condensed sedimentary sequences and that the deposits laid down during falling and low-stand periods (expanded sections) are characterized by a wide range of acoustic responses. Discontinuous reflectors with high-amplitude variability, continuous parallel reflectors, and chaotic and amorphous zones are common acoustic responses. The association between a particular lithofacies and a specific acoustic response on 3.5-kHz records was found to be very poor.     

Influence of relative sea level changes on the construction of the Mississippi Fan

A conceptual sea-level-driven depositional model for individual fanlobes (channel-overbank systems) of the Mississippi Fan does not permit direct application of the sequence stratigraphic principles of Vail and colleagues. Deep Sea Drilling Project Leg 96 results suggest that, during initial relative lowering of sea level, the canyon and upper fan channel were formed; excavated fine-grained slope sediments may have formed a debris flow deposit base for the fanlobe. Continued lowering produced constructional channel-levee-overbank deposits. Rising relative sea level inhibited input of coarse clastics, and channel depressions filled with muds. A blanket of (hemi)pelagics represents relative high sea level stand.     

Multiple outlier detection by evaluating redundancy contributions of observations

When applying single outlier detection techniques, such as the Tau () test, to examine the residuals of observations for outliers, the number of detected observations in any iteration of adjustment is most often more numerous than the actual number of true outliers. A new technique is proposed which estimates the number of outliers in a network by evaluating the redundancy contributions of the detected observations. In this way, a number of potential outliers can be identified and eliminated in each iteration of an adjustment. This leads to higher efficiency in data snooping of geodetic networks. The technique is illustrated with some numerical examples.     

The American whale oil industry: A look back to the future of the American petroleum industry?

The American whaling industry rose from humble beginnings off Long island to become an international giant. In its peak year, 1846, 735 ships and 70,000 people served the industry. As whale stocks and reserves decreased, whalers were forced to go farther and farther from their New England home ports. Voyages became longer, and risks on required return-on-investment became higher. The easy money of Atlantic and Pacific whaling was no more: the only remaining profitable ventures were to Arctic and Antarctic waters. Many ships returned empty, if at all. in 1871, most of the Arctic whaling fleet was crushed by early winter ice and lost. This calamity, in conjunction with the long-term diminishing whale stocks, the diversion of investment capital to more profitable ventures, and the discovery, development, and refinement of abundant petroleum crude oil, struck the death blow to the American whaling industry. By 1890, only 200 whaling vessels were at work, and by 1971, no American commercial whaling ship sailed the world's oceans.It is apparent that no single event caused the final, rapid decline. However, a single calamity, in an already stressed industry, that was self-insured and commercially interlinked, precipitated the end. Today's American petroleum industry, although adopting some principles of the American whaling industry, also has embraced other activities such as work process reengineering and customer alliances, which may preempt, or postpone, a similar catastrophic demise.     

The thermodynamic influence of subgrid orography in a global climate model

Assessments of the impacts of climate change typically require information at scales of 10 km or less. Such a resolution in global climate simulations is unlikely for at least two decades. We have developed an alternative to explicit resolution that provides a framework for meeting the needs of climate change impact assessment much sooner. We have applied to a global climate model a physically based subgrid-scale treatment of the influence of orography on temperature, clouds, precipitation, and land surface hydrology. The treatment represents subgrid variations in surface elevation in terms of fractional area distributions of discrete elevation classes. For each class it calculates the height rise/descent of air parcels traveling through the grid cell, and applies the influence of the rise/descent to the temperature and humidity profiles of the elevation class. Cloud, radiative, and surface processes are calculated separately for each elevation class using the same physical parametrizations used by the model without the subgrid orography parametrization. The simulated climate fields for each elevation class can then be distributed in post-processing according to the spatial distribution of surface elevation within each grid cell. Parallel 10-year simulations with and without the subgrid treatment have been performed. The simulated temperature, precipitation and snow water are mapped to 2.5-minute (~5 km) resolution and compared with gridded analyses of station measurements. The simulation with the subgrid scheme produces a much more realistic distribution of snow water and significantly more realistic distributions of temperature and precipitation than the simulation without the subgrid scheme. Moreover, the 250-km grid cell means of most other fields are virtually unchanged by the subgrid scheme. This suggests that the tuning of the climate model without the subgrid scheme is also applicable to the model with the scheme.     

Origin and history of hydrothermal fluids of the Reykjanes and Krafla geothermal fields,Iceland

The Reykjanes and Krafla geothermal fields are both examples of active high temperature systems and show similar assemblages of alteration minerals, but the fluid at Reykjanes is dominantly sea water whereas that at Krafla is meteoric. Oxygen isotope analyses of surface rock and of drill chip samples from different depths are presented, together with results for the Krafla fluid, which is close to local precipitation (δ ¹⁸ O = ?11.9‰, δD= ?86.8‰). Calcite in both systems is apparently in equilibrium with the present deep fluid at the present field temperature, except for the upper 250 m at Reykjanes where the fluid may be more meteoric than at depth. Feldspar gives similar results. Quartz separates at Reykjanes are anomalously lighter than coexisting feldspar and give exceptionally high quartz-fluid temperatures. It is suggested that quartz originally grew when the fluid was more nearly meteoric (? glacial period) and has not re-equilibrated. Bulk-rock ¹⁸ O depletion supports this interpretation of the history of the Reykjanes system. Quartz in the Krafla system is mostly in equilibrium at the present field conditions but anomalies occur near the boundary between the upper and lower parts of the system, suggesting that this is not entirely stable. A high fluid:rock ratio (10–100 minimum) is indicated for the Krafla field.     

Stable isotopic characterisation of francolite formation

Stable isotopic data are presented for 112 samples of francolite from 18 separate phosphate deposits. Values ofδ¹³C andδ³⁴S in most offshore deposits suggest formation within oxic or suboxic environments either by carbonate replacement or direct precipitation of francolite from water of normal marine compositions. The exceptions are concretionary francolite from Namibia, which has an isotopic composition in keeping with its formation within organic-rich sediments, and that from offshore Morocco, which has an isotopic signature of the anoxic/suboxic interface. Onshore deposits from Jordan, Mexico, South Africa and, possibly, the Permian Phosphoria Formation in the western U.S.A., are substantially depleted in¹⁸O: they appear to be too altered for deductions to be made about their environments of formation. In other onshore deposits which are unaltered, or minimally altered, the isotopic composition suggests that some formed within sulphate-reducing sediments (Sedhura, Morocco) whilst francolite from the Georgina Basin of Australia formed at the oxic/anoxic boundary, where oxidation of biogenic H₂S decreases theδ³⁴S of pore water. In general, pelletal samples show non-oxic isotopic signatures, whilst non-pelletal samples show oxic isotopic signatures, but samples from Namibia, Peru (Ica Plateau) and the Californian and Moroccan margins are exceptions to this rule. Morphology may therefore be a misleading indicator of francolite genesis as no definitive relation exists between phosphorite type and isotopic signature.     

Carbon and hydrogen isotopic compositions of the NBS 22 and NBS 21 stable isotope reference materials: An inter-laboratory comparison

Measurement of 17 laboratories on the stable isotope reference materials, NBS 22 lubricating oil and NBS 21 graphite, resulted in a revised calibration on the PDB scale. NBS 22 ¹³C/¹²C ratios of all laboratories did not demonstrate a gausssian distribution. Therefore, values which resulted from direct comparison with NBS 20 carbonate standards were selected the mean value of which is $\text{?29.81 ± 0.06?}$; this value is recommended as new value for NBS 22. The reported variations in δ¹³C for NBS 21 were consistent within the accuracies for single meaurements; the mean value is ?28.16 ± 0.01. The variations of D/H ratios of NBS 22 also were consistent with the accuracy quoted, with a mean value of ?119?.