云南禄丰煤岩与围岩中富勒烯（C60）物质的初步探索

中国云南煤中是否存在富勒烯还没有科学定论。本工作运用高效液相色谱方法，对中国云南禄丰晚三叠世煤岩及其围岩中是否存在天然富勒烯物质的问题进行了探索性研究；同时发展了适于从复杂地质样品中分离纯化富勒烯和定性与定量检测富勒烯的一套技术方法。结果显示，从定性角度有两个样品确实存在富勒烯。本文据此提出，富勒烯的赋存与煤岩／围岩交互相上的含煤碳质泥岩有着密切的关系。下一步研究应着重调查比煤岩与顶板和底板界面层并大力研究其中天然富勒烯的地学成因。本工作的意义还在于为今后我国加入和独立开展以富勒烯类物质（如C60／C70）及其衍生物质（如He C60 C70)作为地球化学示踪物的古地球突变大事件的研究，奠定了实验方法学基础。     

赣南营前岩体的年代学、地球化学、Sr-Nd-Hf同位素组成及其地质意义

赣南营前岩体由早期似斑状花岗闪长岩和晚期细粒黑云母花岗岩组成,在前者中普遍发育暗色基性包体。SHRIMP锆石U-Pb测年显示似斑状花岗闪长岩为172.2±3.1Ma,细粒黑云母花岗岩为168±3Ma,包体为167.6±3.3Ma。所有的岩石均为钙碱性系列,稀土元素显示LREE富集,HREE亏损,Eu负异常并不明显的特征,Nb-Ta负异常显示壳源物质的特征。晚期细粒黑云母花岗岩、早期似斑状花岗闪长岩、暗色包体的(87Sr/86Sr)i和εNd(t)值分别为0.70885～0.70965、0.71058～1.46393、0.70788～0.70923和-6.38～-5.31、-6.51～-5.17、-5.47～-4.31;锆石εHf(t)值分别为-12.4～-5.7、-9.2～-4.2、-9.4～+0.1。结合岩相学、地球化学研究,初步认为营前岩体的两期花岗质岩石源于地壳重熔,地幔底侵导致地壳熔融形成营前岩体,基性岩浆加入到未冷却的酸性岩浆中形成了目前所见到的暗色包体。结合区域上的研究资料,认为中侏罗世期间,沿"十杭"断裂带及与其相平行的一些深断裂发生了板块的撕裂,这些缝合带是岩石圈相对薄弱的地带,有利于幔源物质底侵上升以及壳幔相互作用。     

A complementary depiction of the interannual variation of atmospheric circulation associated with ENSO events: Research note

Abstract

A simple diagnostic scheme, which combines a low‐pass temporal filter (with an 18‐month cutoff time) with a regular empirical orthogonal function (EOF) analysis, is used to delineate the synchronous evolution of El Nino‐Southern Oscillation‐related (ENSO‐related) modes in various variables of the ocean‐atmosphere system. Based on the causal relation chain of diabatic heating, divergent circulation and rotational flow, the diagnostic scheme extracts ENSO modes from the following data sources: the Pacific sea surface temperature (SST), the past 14‐years (1979–1992) of data generated by the Global Data Assimilation System of the National Meteorological Center, and a 10‐year (1979–1988) general circulation model climate simulation made at the Goddard Laboratory for Atmospheres. The analysis reveals the following: (a) the eigencoefficient time series of the first eigenmodes of selected filtered variables, which explain about 40–50% of their total variance, synchronize with the filtered SST averaged over Area NINO‐3; (b) the spatial structures of the first eigenmodes resemble the ensemble departures associated with ENSO events of these variables from their long term means; and (c) the results show that the proposed scheme can be easily applied to isolate and illustrate the time evolution of ENSO modes which exist in the long term observational database as well as in climate simulations.     

Adsorption Kinetics,Isotherms, and Desorption of Monocrotophos and Dichlorvos on Various Indian Soils

Pesticide sorption on to the soil has a significant role in deciding the fate and behavior of pesticides in soil and aquatic environment. The present study investigates the adsorption of monocrotophos (MCP) and dichlorvos (DDVP) on the three soils of Malwa region of Punjab, India under different conditions. Batch adsorption experiments were preformed in replicates using 2 g of air‐dried soil and varying concentrations of pesticides and 20 mL of 0.01 M CaCl₂ as background electrolyte. The results revealed high adsorption of MCP and DDVP in soil B with k_f‐values 0.1261 and 0.0498 and n‐values 2.7345 and 1.831, respectively. The adsorption isotherms obtained were analyzed and the data was subjected to classical Langmuir, Freundlich, and Temkin models. The experimental data best fitted to the logarithm form of Freundlich and Temkin model. Kinetics analyses were performed using pseudo‐first order, pseudo‐second order, and intraparticle diffusion models. The regression results showed that the experimental data fitted very well with the pseudo‐second order kinetic model as correlation coefficient value is very closer to 1 and also followed the intraparticle diffusion model, whereas, diffusion is not only the rate controlling step. The percentages desorption with tap and distilled water is 32–64% for MCP and 25–48% for DDVP.     

敦煌造山带南部红柳峡混杂带基质的沉积学、地球化学和年代学特征及其大地构造意义

敦煌造山带南部红柳峡混杂带基质的研究,为认识敦煌造山带的形成和演化提供了新的依据。本文从沉积学、地球化学和年代学等方面系统讨论了该混杂带基质的特征和形成环境。结果显示,基质的岩石类型主要包括变泥质岩(云母石英片岩)和变质砂岩,普遍发生强烈变形。局部弱变形变质的基质仍保留有原生沉积构造(如T_(ab)、T_(de)、T_(bde)组合的鲍马序列),反映原岩是一套浊积岩复理石。显微岩相学特征显示,基质碎屑组分以长石、石英和岩屑为主,长石和岩屑含量较高,分别为47%和27%,反映大量火成岩物质的加入,且碎屑颗粒的分选性和磨圆度较差,说明搬运距离较近。地球化学方面,低的化学蚀变指数(CIA=49~67),反映复理石基质物源区母岩经历的风化程度较低。高的成分变化指数(ICV0.8)以及Zr/Sc-Th/Sc投图结果显示,沉积物再循环程度低,为近物源区的初次沉积。基质Sc、Cr、Co、Ni含量低,Eu/Eu*、La/Sc、Th/Sc、La/Co、Th/Co和Cr/Th等元素比值类似于来自长英质源区的沉积物,暗示其物源区母岩以中-酸性岩石为主。La/Sc-Ti/Zr和Th-ScZr/10投图结果显示,复理石基质形成于陆缘弧或活动大陆边缘构造背景。弱变形浅变质砂岩的碎屑模式表明,基质的物源来自"切割型弧-过渡型弧"源区。综上,红柳峡混杂带基质在碎屑组成方面,以再循环程度低、近物源堆积的"切割型弧-过渡型弧"源区长英质碎屑组分为主,在沉积构造方面,发育鲍马序列和深水块体搬运沉积(MTD)构造,表明基质形成于陆缘弧或活动大陆边缘的俯冲带海沟环境。碎屑锆石年代学显示三组年龄:2300Ma、1850Ma和423Ma,结合区域地质背景分析,初步认为物源碎屑可能来自混杂带北侧的三危山弧和东巴兔-蘑菇台弧的古生代花岗岩类以及俯冲折返的变质基性岩岩块。复理石基质的变质砂岩中获得的最年轻的岩浆碎屑锆石年龄为389Ma,说明该砂岩形成于中泥盆世之后,暗示敦煌造山带南部红柳峡地区洋盆尚未俯冲完毕,碰撞作用尚未开始。     

An investigation of the relationship between sub‐Saharan rainfall and global sea surface temperatures

Abstract

The relationship between sea surface temperature (SST) and rainfall index anomalies over sub‐Saharan Africa for the 15‐year period, 1970–84, has been examined. The objectively analysed monthly mean SST data were used for the global oceans between 40°S and 60°N. The rainfall data consist of annual mean rainfall indices for the Sahel and Soudan belts over north Africa.

An Empirical Orthogonal Function analysis of the SST data has been carried out for the Atlantic, Indian and global ocean regions. The results show that the most dominant eigenmode, EOF1, is characterized by warming over the central eastern Pacific, cooling over the eastern mid‐latitude Pacific and warming over the entire Atlantic and Indian ocean basins. The second EOF for the Atlantic Ocean SST analysis shows a dipole (north‐south see‐saw) pattern. The third EOF for the Atlantic SST analysis has the same sign over the entire Atlantic basin. Global SST EOF2 and EOF3 correspondió Atlantic SST EOF3 and EOF2, respectively.

The correlation between the sub‐Saharan annual rainfall index, which mainly represents the summer season rainfall from June to September, and SST EOFs shows that EOF1 has statistically significant monthly correlations for the Sahel and Soudan regions and that the warm El Niño‐like phases of SST EOF1 correspond to drought conditions. This result suggests that the large‐scale SST anomalies may be responsible for a significant component of the observed vacillation of sub‐Saharan rainfall. Some preliminary GLA GCM simulation results that support the above findings are also presented.     

The influence of surface roughness of deserts on the July circulation

The influence of low surface roughness of deserts on the July circulation is examined by employing numerical simulations with a GLAS GCM. Two identical sets of simulations were made with the model starting from the initial state of the atmosphere based on the NMC analysis of observations for June 15, at OOZ for the years 1979 and 1980. The first set, called the Control, had land surface roughness set to 45 cm, everywhere. The second set called the Experiment, had surface roughness set to 0.02 cm for deserts, but 45 cm everywhere else on land. All other prescribed boundary conditions were the same in both runs.A comparative analysis of these simulations showed that the rainfall in the Sahara desert was reduced significantly in both Experiments as compared to the corresponding Controls; the ITCZ (inter-tropical convergence zone) moved southward, to about 14° N, which is close to its observed location at about 10° N. This was primarily caused by the relative moisture divergence from the smoother Sahara. In other deserts, which anyway had little rainfall in the July simulation of the Control run, there was virtually no change. The differences in regional heat and moisture budgets, particularly for the Sahara desert, are significant as compared to the sample standard deviation for a set of three July simulations (i.e., Control runs for three different initial conditions). In a third simulation, in which the surface roughness was changed over all land, similar results were obtained in the Sahara desert region.The study reveals the influence of low surface-roughness of deserts on the July rainfall. For the Sahara desert, this influence is comparable to that of an increase in surface albedo. In nature, formation of deserts leads to reduction of surface roughness as the vegetation perishes and soil erosion ensues. It is inferred that the smoothness of land then causes reduction in rainfall and further promotes desertification.Sigma Data Services through contract # NASA 25900.     

Influence of aerosol-radiative forcings on the diurnal and seasonal cycles of rainfall over West Africa and Eastern Atlantic Ocean using GCM simulations

Effects of aerosol radiative forcing on the diurnal and seasonal cycles of precipitation over West Africa and eastern Atlantic Ocean are investigated for the boreal summer season: June–July–August. An eight year (2000–2007) average of GCM simulated rainfall data is compared with the corresponding TRMM rainfall data. The comparison shows that the amplitude of the diurnal cycles of rainfall over land and ocean are reasonably well simulated. Over land, the phase of the simulated diurnal cycle of precipitation peaks several hours earlier than that of the TRMM data. Corresponding differences over the ocean(s) are relatively smaller. Some of the key features of the aerosol induced model simulated field anomalies are: (a) aerosol direct radiative forcing which increases the atmospheric stability and reduces the daytime moist convection and convective precipitation; (b) the aerosol induced changes in the diurnal cycle of precipitation are out of phase with those of the TRMM data over land, but are in-phase over the ocean; (c) aerosols reduce the amplitude of the diurnal cycle of precipitation over land and enhance it over ocean. However, the phase of the diurnal cycle is not affected much by the aerosol radiative forcing both over land and ocean. During the boreal summer, aerosol radiative forcing and induced circulation and precipitation cool the Sahel and the southern part of Sahara desert more than the adjacent areas to the north and south, thereby shifting the peak meridional temperature gradient northward. Consequently, an anomalous easterly jet is found north of its climatological location. This anomalous jet is associated with increased cyclonic circulation to the south of its axis, resulting in an anomalous monsoon rain belt in the Sahel.