Subaqueous pyroclastic flows and ignimbrites: an assessment

An assessment of the literature on subaqueous pyroclastic flows and their deposits shows that the term pyroclastic flow is frequently used loosely to describe primary, hot gas-rich pyroclastic flows, mass-flows which resulted from the transformation of gassupported flows into water-supported ones, and secondary mass-flows carrying redeposited pyroclastic debris. Based on subaerial pyroclastic flows, the term pyroclastic flow should be restricted to demonstrably hot, gas-rich mass-flows of pyroclastic debris. Using this definition, very few examples of subaqueous pyroclastic deposits with evidence for hot emplacement and of having been wholly submerged have been described. In the majority of these cases, the evidence for a hot state of emplacement and for the subaqueous nature of the host depositional environment is inadequate. The only unequivocal cases of hot pyroclastic flow deposits with adequate supporting evidence are the Ordovician nearshore, shallow marine ignimbrites of Ireland and Wales, and Miocene ignimbrites of southwest Japan, resulting from the passage of subaerially erupted pyroclastic flows into shallow water. Other possible examples are near-vent dense clast deposits in the Donzurobo Formation of Japan, possible submarine intra-caldera ponded ignimbrite successions in California and Wales, and near-vent pumiceous deposits of Ramsay Island, Wales. All other purported cases are either clearly the result of water-supported mass-flow transportation and deposition (debris avalanches, debris flows, turbidity currents), or lack adequate supporting evidence regarding the heat state or the palaeoenvironment. Only the shallow marine ignimbrites of Ireland and Wales show adequate evidence of welding, but even these could have been nearly wholly exposed above sea-level when welding occurred. We conclude that when pyroclastic flows enter water they are generally disrupted explosively and/or ingest water and transform into water-supported mass-flows, and we suggest the various scenarios in which this occurs. There is no evidence to suggest that welding in wholly subaqueous environments is common.     

Possibilities to detect trends in spectral UV irradiance

Summary It is investigated how long-term UV trends can be assessed by analysing the longest time series of measured spectral UV irradiance in Europe, which have been started in the early 1990s in Thessaloniki, Greece and Sodankylä, Finland. It can be concluded that both time series do not yet show an unambiguous yearly trend in UV irradiance. The regression lines show no uniform behaviour and vary irregularly in strength and from one solar zenith angle to the next if all sky conditions are analysed. It is emphasised that these findings do not disagree with previous studies, that significant changes in UV irradiance have been observed over Europe especially in spring.Our study introduces a new method to estimate the required time series length for trend detection using the measured time series in combination with model calculations. At Sodankylä, a reduction of the total ozone column of –5.7% per decade has been observed from 1979 to 1998. A positive UV trend due to such conditions may be detected after 12 years at the earliest. For Thessalonki, a decrease in total ozone of –4.5% per decade has been observed. A corresponding increase of UV irradiance should be detectable after 15 years. It should be noted that a constant ozone trend over the whole period had to be assumed for this analysis.Since 1990 there has been a considerable variability of total ozone, but no steady decrease could be observed. Consequently, no general UV increase could be expected due to ozone changes. Even if there was a constant ozone trend over that period it is shown that even the longest European time series of UV irradiance are still too short to show distinct trends. However, this does not imply that no changes have occurred, it only shows that the large natural variability of UV irradiance has so far hindered the identification of unambiguous trends. The only way to find significant and consistent UV trends is the continuation of high-quality long-term measurements of spectral UV irradiance.     

A semi-continuous measurement of gaseous ammonia and particulate ammonium concentrations in PM<Subscript>2.5</Subscript> in the ambient atmosphere

Ammonia has a short residence time in the atmosphere and rapidly neutralizes acid gases that occur near its source, requiring a rapid measurement system for ammonia and particulate ammonium concentrations to better understand their sources, temporal variation of ammonia emissions, and the formation of secondary ammonium aerosols. A semi-continuous measurement system, consisting of a diffusion scrubber, a particle growth chamber, an air-liquid separator, and a fluorescent detector, was developed to determine both gaseous ammonia (NH₃) and particulate ammonium (NH ₄ ⁺ ) in PM_2.5 in the ambient atmosphere of Gwangju, South Korea, during the months of March, April, July, and September of 2007. During the sampling periods, the average concentrations of ammonia and ammonium were found to be 2.33?±?1.29 μg/m³ and 1.89?±?0.99 μg/m³, respectively. Although the average gaseous ammonia concentration was highest in March, the particulate ammonium concentration was higher during the warmer season, reaching 2.08?±?1.07 μg/m³ and 2.32?±?0.94 μg/m³ in April and July, respectively, while only 1.68?±?0.61 μg/m³ in March and 1.24?±?0.99 μg/m³ in September. It is proposed that the higher availability of acid species during the warmer months produced a significant amount of particulate ammonium sulfate. Diurnal fluctuation of ammonia and ammonium during the warmer months showed that their peak time occurred at approximately 10:00 am. Both ammonia and ammonium concentrations were better correlated during the warmer months than during the cooler months. Further, the data suggest that the ammonia and ammonium were measured under well dispersed conditions, and multiple sources contributed to the ammonia at the sampling site.     

Solar ultraviolet absorption by sulphur dioxide in Thessaloniki,Greece

Abstract

This work presents the climatology of the sulphur dioxide column over Thessaloniki derived from three years of observation with the Brewer spectrophotometer. The SO₂ column averages 2.5 m atm‐cm and the shielding of UV‐B by SO₂ is investigated and compared with the changes in shielding resulting from an anticipated ozone reduction. Columnar and surface SO₂ concentrations over Thessaloniki appear to be typical of those in major industrial‐urban regions of the world. It is concluded that, for urban regions, predictions of changes in UV‐B as a result of man's activities must consider projections of changes in the SO₂ column as well as ozone.     

The Phytoplankton of the Straw Board Mill Effluent Mixing Zone in Comparison with a Reference Zone and Diluted Zones of the River Dhasan,M. P. India

This paper embodies findings of twelve month on the effect of straw-board mill effluents on the distribution and diversity of phytoplankton of the river Dhasan. The phytoplankton of the three stretches (Reference Station A, Effluent Mixing Station B and Diluted Station C) of the river was sampled regularly every month and analysed qualitatively and quantitatively. Simultaneously some of the relevant chemical parameters of the water were also analysed. The result of the water were also analysed. The result of the plankton study showed that the plankton concentration was very low. It ranged from 166 organisms to 2240 organisms per litre only. The maximum and minimum numbers were recorded in February and June-July respectively at all stations. Winter was found to be the most favourable season and the rainy season the most unfavourable with regard to the population density. From the samples collected from all the stations we could recognise 54 genera of chlorophyceae, 25 genera of Bacillariophyceae, 24 genera of cyanophyceae, 3 genera of Dinophyceae and 2 genera each of euglenophyceae, chrysophyceae and xanthophyceae. The percentage composition of the various groups varied with stations, but by and large chlorophyceae and bacillariophyceae dominated in all the sampling stations. The data were subjected to ‘ANOVA’ and ‘t’ tests. The results show that the observed variations in the distribution and diversity of phytoplankton among the three stations were not significant at the 5= level except in the case of Euglenophyceae.     

断裂引起的应变量计算方法

本文介绍了断裂引起的应变量计算方法。断裂作用可导致连续应变和非连续应变。连续应变与断裂位移,断裂长度比值及断裂面上有效应力成正相关关系。影响非连续应变的因素有：断裂几何形态、断裂的旋转性、断裂规模。已经提出三种断裂旋转机制：刚性旋转,垂直剪切和斜向剪切。对于这三种机制,我们分别建立了断裂非连续应变的计算公式。这些公式与断裂的旋转角度和位移大小相关。刚性旋转时,断块内部没有任何塑性变形,因此地层的长度没有变化。它引起的非连续应变最小。垂直剪切作用使断块内地层变形,但水平方向的地层长度不变。推算的公式表明,对于相同的原始数据,它引起的非连续应变比刚性旋转机制引起的非连续应变大。斜向剪切也使断块内地层变形,但水平方向的长度也不变。在同等条件下,它引起的非连续应变比垂直剪切机制引起的非连续应变大。     

Stratospheric and total NO2 column measurements with a modified Canterbury filter photometer

A programme of ground-based stratospheric and total NO₂ column measurements was instituted at the Laboratory of Atmospheric Physics (40.5° N, 22.9° E) in August 1985. We present here the results of the first two years of measurements with a modified Canterbury filter photometer, details of which are given in the text. The stratospheric NO₂ column, obtained at twilight during low local NO₂ levels, shows the seasonal variation with monthly mean values of about 6×10^-15 molec. cm^-2 in the summertime to about 2.2×10^-15 molec. cm^-2 in the wintertime. These measurements compare well with measurements obtained with different instruments by other groups at similar latitudes (about 40° N) but in different places. Also, the asymmetry of the evening-to-morning stratospheric NO₂ over Thessaloniki was found to be on the average equal to 1.58. Total NO₂ column over Thessaloniki has a pronounced seasonal variation with amplitude of 0.68 matm. cm which can be explained partly from measured local NO₂ sources which discharge in the mixing layer and partly from photolysis of the NO₂ reservoir species.