Evaluation of vegetative criteria for near-surface groundwater detection using multispectral mapping and GIS techniques in semi-arid Botswana

The critical need to consider all options in the search for groundwater in semi-arid areas has promoted work on the possible association of near-surface groundwater and vegetation characteristics using a combination of remote-sensing data and geographic information systems (GIS) techniques. Two vegetative criteria (dense woody cover and abundance of deep-rooting species) are identified as being indicative of near-surface groundwater, and their spatial distribution is tested against the location of aquifers in southeast Botswana. Vegetative criteria classes were combined in a GIS environment with the distribution of geomorphic units and bedrock geology to determine the degree of coincidence with assumed or known aquifers. Results indicate that the distribution of dense woody vegetation as mapped from Thematic Mapper imagery has some potential in identifying especially surficial but also bedrock near-surface groundwater sources in mostly naturally vegetated semi-arid areas. Dense woody cover classes tend to select aquifers in topographically higher areas while classes comprising some deep-rooting species tend to select low-lying aquifers such as those occurring in fossil valleys. Deep-rooting species, however, are less successful as a vegetative criterion. Although various technical refinements are suggested, this work shows that vegetative criteria mapping can however be used in conjunction with conventional geological/geophysical techniques to enhance the prospects for groundwater location in relatively undisturbed semi-arid areas.     

Measuring individual vulnerability to floods in the lower and middle Grijalva River Basin,Tabasco, Mexico

Natural Hazards - We built an easy-to-interpret individual vulnerability index to floods that is amenable for empirical testing and may be adapted to any perceived hazard or ecological setting. An...     

SN 1994W: an interacting supernova or two interacting shells?

We present a multi-epoch quantitative spectroscopic analysis of the Type IIn supernova (Type IIn SN) 1994W, an event interpreted by Chugai et al. as stemming from the interaction between the ejecta of a SN and a  0.4 M_⊙  circumstellar shell ejected 1.5 yr before core collapse. During the brightening phase, our models suggest that the source of optical radiation is not unique, perhaps associated with an inner optically thick cold dense shell and outer optically thin shocked material. During the fading phase, our models support a single source of radiation, an hydrogen-rich optically thick layer with a near-constant temperature of ∼7000 K that recedes from a radius of  4.3 × 10¹⁵  at a peak to  2.3 × 10¹⁵ cm  40 d later. We reproduce the hybrid narrow-core broad-wing line profile shapes of SN 1994W at all times, invoking an optically thick photosphere exclusively (i.e. without any external optically thick shell). In SN 1994W, slow expansion makes scattering with thermal electrons a key escape mechanism for photons trapped in optically thick line cores, and allows the resulting broad incoherent electron-scattering wings to be seen around narrow-line cores. In SNe with larger expansion velocities, the thermal broadening due to incoherent scattering is masked by the broad profile and the dominant frequency redshift occasioned by bulk motions. Given the absence of broad lines at all times and the very low ⁵⁶Ni yields, we speculate whether SN 1994W could have resulted from an interaction between two ejected shells without core collapse. The high conversion efficiency of kinetic to thermal energy may not require a SN-like energy budget for SN1994W.     

Probability distributions for carbon emissions and atmospheric response

Probability distributions for carbon burning, atmospheric CO₂, and global average temperature are produced by time series calibration of models of utility optimization and carbon and heat balance using log-linear production functions. Population growth is used to calibrate a logistically evolving index of development that influences production efficiency. Energy production efficiency also includes a coefficient that decreases linearly with decreasing carbon intensity of energy production. This carbon intensity is a piecewise linear function of fossil carbon depletion. That function is calibrated against historical data and extrapolated by sampling a set of hypotheses about the impact on the carbon intensity of energy production of depleting fluid fossil fuel resources and increasing cumulative carbon emissions. Atmospheric carbon balance is determined by a first order differential equation with carbon use rates and cumulative carbon use as drivers. Atmospheric CO₂ is a driver in a similar heat balance. Periodic corrections are included where required to make residuals between data and model results indistinguishable from independently and identically distributed normal distributions according to statistical tests on finite Fourier power spectrum amplitudes and nearest neighbor correlations. Asymptotic approach to a sustainable non-fossil energy production is followed for a global disaggregation into a tropical/developing and temperate/more-developed region. The increase in the uncertainty of global average temperature increases nearly quadratically with the increase in the temperature from the present through the next two centuries.     

Carbonate mud sedimentation on a temperate shelf: Bass Basin, southeastern Australia

Bass Basin (66,000 km²) is unusual as a carbonate-dominated basin because calcitic carbonate muds are accumulating in relatively shallow (70–85 m) water depths in the central part of the basin (20,000 km²). The carbonate muds are produced by the primary accumulation and disintegration of nannoplankton, as well as through the biodegradation of skeletal carbonate grains accumulating on the sea floor. The muds are transported to the south of the basin to the end of tidal current transport paths, where they accumulate in the lowest-energy environment available in enclosed Bass Basin, although they are still subject to periodic reworking by storm energy. The basin margins consist of coarser, partially palimpsest, carbonate sands, whereas the central muds overlie a Late Pleistocene disequilibrium surface. In cores these muds are up to 1 m thick and thin away from the centre towards the margins. Bioturbation is important in modifying the textural character of the muds by increasing the grain size as faecal pellets, and therefore creating a sea floor not in equilibrium with modern hydrodynamic conditions. Radiocarbon dates for an early post-glacial marine transgression embayment facies in the basin gave ages of 10,290 ± 250 to 11,660 ± 300 years B.P. An age of 8700 ± 710 years B.P. was obtained for the base of the modern strait facies. These ages and facies thicknesses were used to establish Holocene sedimentation rates of < 12 cm/1000 y for the basin centre, falling to < 6 cm/1000 y towards the margins.     

Origin and palaeo‐environments of calcareous sediments in the Moshaweng dry valley,southeast Botswana

Quaternary sedimentation in the Moshaweng dry valley of southeastern Botswana is evaluated on the basis of geomorphological evolution and sedimentological analyses. Stratigraphic evidence reveals an upper surface (1095 m) containing abundant sil‐calcrete, an intermediate surface (1085 m) in which sil‐calcrete underlies nodular calcrete and lower (1075 m) surface in which sil‐calcrete and nodular calcrete are interbedded. This subdivision is reflected in the geochemical composition of the sediments which show an overall trend of decreasing SiO₂ content (and increasing CaCO₃ content) with depth from the highest to the lowest surface levels. The calcretes and sil‐calcretes represent modifications of pre‐existing detrital Kalahari Group sand and basal Kalahari pebbles which thinned over a Karoo bedrock high. Modification took place during wet periods when abundant Ca⁺⁺‐rich groundwater flowed along the structurally aligned valley system. With the onset of drier conditions, water table fluctuations led to the precipitation of nodular calcretes in the phreatic layer to a depth of about 20 m. A major geochemical change resulted in the preferential silicification of the nodular calcrete deposits. Conditions for silica mobilization may be related to drying‐induced salinity and in situ geochemical differentiation brought about by pebble dissociation towards the top of the sediment pile. As calcretization and valley formation progressed to lower levels, silica release took place on a diminishing scale. Thermoluminescence dating infers a mid‐Pleistocene age for sil‐calcrete formation suggesting that valley evolution and original calcrete precipitation are much older. Late stage dissolution of CaCO₃ from pre‐existing surface calcretes or sil‐calcretes led to the formation of pedogenic case‐hardened deposits during a time of reduced flow through the Moshaweng system possibly during the upper or late Pleistocene. Copyright © 2002 John Wiley & Sons, Ltd.     

Distribution and concentrations of petroleum hydrocarbons associated with the BP/Deepwater Horizon Oil Spill,Gulf of Mexico

We examined the geographic extent of petroleum hydrocarbon contamination in sediment, seawater, biota, and seafood during/after the BP/Deepwater Horizon Oil Spill (April 20–July 15, 2010; 28.736667°N, −88.386944°W). TPH, PAHs, and 12 compound classes were examined, particularly C1-benzo(a)anthracenes/chrysenes, C-2-/C-4-phenanthrenes/anthracenes, and C3-naphthalenes. Sediment TPH, PAHs, and all classes peaked near Pensacola, Florida, and Galveston, Texas. Seawater TPH peaked off Pensacola; all of the above classes peaked off the Mississippi River, Louisiana and Galveston. Biota TPH and PAHs peaked near the Mississippi River; C-3 napthalenes peaked near the spill site. Seafood TPH peaked near the spill site, with PAHs and all classes peaking near Pensacola. We recommend that oil concentrations continued to be monitored in these media well after the spill has ceased to assist in defining re-opening dates for fisheries; closures should be maintained until hydrocarbon levels are deemed within appropriate limits.     

Early burial mud diapirism and its impact on stratigraphic architecture in the Carboniferous of the Shannon Basin,County Clare,Ireland

Delta fronts are often characterized by high rates of sediment supply that result in unstable slopes and a wide variety of soft‐sediment deformation, including the formation of overpressured and mobile muds that may flow plastically during early burial, potentially forming mud diapirs. The coastal cliffs of County Clare, western Ireland, expose Pennsylvanian (Namurian) delta‐front deposits of the Shannon Basin at large scale and in three dimensions. These deposits include decametre‐scale, internally chaotic mudstone masses that clearly impact the surrounding sedimentary strata. Evidence indicates that these were true mud (unlithified sediment) diapirs that pierced overlying strata. This study documents a well‐exposed ca 20 m tall mud diapir and its impact on the surrounding mouth‐bar deposits of the Tullig Cyclothem. A synsedimentary fault and associated rollover dome, evident from stratal thicknesses and the dip of the beds, define one edge of the diapir. These features are interpreted as recording the reactive rise of the mud diapir in response to extensional faulting along its margin. Above the diapir, heterolithic sandstones and siltstones contain evidence for the creation of localized accommodation, suggesting synsedimentary filling, tilting and erosion of a shallow sag basin accommodated by the progressive collapse of the diapir. Two other diapirs are investigated using three‐dimensional models built from ‘structure from motion’ drone imagery. Both diapirs are interpreted to have grown predominantly through passive rise (downbuilding). Stratal relationships for all three diapirs indicate that they were uncompacted and fluid‐rich mud beds that became mobilized through soft‐sediment deformation during early burial (i.e. <50 m, likely <10 m depth). Each diapir locally controlled the stratigraphic architecture in the shallow subsurface and potentially influenced local palaeocurrents on the delta. The mud diapirs studied herein are distinct from deeper ‘shale diapirs’ that have been inferred from seismic sections worldwide, now largely disputed.     

Biological control of short-term variations in the concentration of DMSP and DMS during a Phaeocystis spring bloom

In the spring of 1995, short-term variations in the concentration of particulate and dissolved dimethylsulfoniopropionate (DMSP) and dimethylsulfide (DMS) were monitored in the western Wadden Sea, a shallow coastal region in open connection with the North Sea. Significant correlations were found between abundance of Phaeocystis globosa and particulate DMSP; concentrations increased rapidly from 100 to 1650 nM in the middle of April. Highest DMS concentrations were found during the initial phase of the exponential growth of the bloom. DMS production and loss rates of DMSP and DMS were estimated experimentally during various phases of the bloom. DMS production and consumption were roughly in balance, with production only slightly exceeding consumption at the start of the bloom. Rates of production and consumption were highest during the exponential growth phase of Phaeocystis and declined in the course of the bloom (from 300–375 to less than 5 nmol dm⁻³ d⁻¹). Demethylation of DMSP increased during the bloom (from 11 to 1300 nmol dm⁻³ d⁻¹); it accounted for up to 100% of the DMSP loss at the end of the bloom. The shift from DMSP cleavage to demethylation in the course of a Phaeocystis bloom implies that DMS concentrations are not necessarily highest at the peak or towards the end of blooms.