To investigate the potential for enantioselective transformation and accumulation, the enantiomer distributions of seven polychlorinated biphenyl (PCB) atropisomers were measured in the sediment and biota from a sub-tropical estuary heavily contaminated with Aroclor 1268, a technical mixture of highly chlorinated PCB congeners. Enantiomer fractions (EFs) of PCBs 91, 95, 136, 149, 174, 176, and 183 in marsh sediment, invertebrate, forage and predatory fish species, and bottlenose dolphins were determined. Non-racemic EFs greater than 0.75 were found in sediments for PCBs 136 and 174, likely the result of microbial dechlorination. Although enantiomer fractions in grass shrimp (Palaemonetes spp.) mirrored those of sediment, fish species had EFs that differed significantly from sediment or grass shrimp. Similarly, bottlenose dolphins were also found to contain non-racemic quantities of PCBs 91, 136, 174, 176, and 183. Non-racemic EFs in these biota were likely a result of both uptake of non-racemic proportions of PCBs from the diet and enantioselective biotransformation. 相似文献
Erosion models have not often been applied to very steep terrain such as the gully catchments of the Chinese Loess Plateau. The purpose of this research was to evaluate the suitability of a number of transport equations for use in erosion modelling under Loess Plateau conditions. To do this the equations were programmed into the LISEM model, which was applied to the 3.5 km2 Danangou catchment in the rolling hills region of the Loess Plateau. Previous evaluations of transport equations used either flume tests or river sections, and did no spatial modelling. The results show that some equations predicted physically impossible concentrations (defined as above 1060 g/l). The results were evaluated by using two methods: 1) by comparing predicted and measured sedigraphs and sediment yield at the catchment outlet, and 2) by comparing the fraction of the catchment in which physically impossible transport capacities occurred. The results indicated that for the small grain sizes, high density flows and steep slopes of the gully catchments on the Loess Plateau the Shields parameter attained very high values. Furthermore, the transport threshold can usually be neglected in the equations. Most of the resulting equations were too sensitive to slope angle (Abrahams, Schoklitsch, Yalin, Bagnold, Low and Rickenmann), so that transport rates were overpredicted for steep slopes and underpredicted for gentle slopes. The Yang equation appeared to be too sensitive to grainsize. The Govers equation performed best, mainly because of its low slope dependency, and is therefore recommended for erosion models that simulate sediment transport by flowing water in conditions with small grain sizes and steep slopes. 相似文献
In this paper the meteorological and hydrological conditions are analyzed which trigger shallow and deeper landslides in glacio-lacustrine deposits (varved or laminated clays) in the French Alps. The hydrological system of these landslides consists of a colluvial cover which supplies water into the fissures of the underlying varved clays. From these fissures water can infiltrate more or less horizontally into the silt layers of the varved clays. A combined reservoirs model was used to simulate the water fluctuations in the colluvial cover and the fissures. Both the water level in the fissures and the residence time of water in the fissures are mainly controlled by the amount of water storage in the colluvial cover. Simulations over the last 25 years show that almost each year the fissures are completely filled with water for several months a year.
Infiltration experiments in the field show that infiltration into the varved clays occurs mainly by horizontal infiltration into the silt laminae. Calculated infiltration rates from these fissures into the silt layers show that the mean yearly residence time of water in the fissures is not sufficient to fully saturate the clay mass each year. It is therefore concluded that the triggering of the landslide movements is mainly controlled by the development of positive pore water pressures in the fissure system and that the rise of pore water pressures induced by the matrix system of the varved clays only plays a minor role. The calculations also show that drainage of the colluvial cover is a very efficient measure to stabilize the deeper landslides. 相似文献