A ROSAT WFC observation of SW UMa: the EUV behaviour of dwarf novae in superoutburst explained

During re-processing and analysis of the entire ROSAT Wide Field Camera (WFC) pointed observations data base, we discovered a serendipitous, off-axis detection of the cataclysmic variable SW UMa at the onset of its 1997 October superoutburst. Although long outbursts in this SU UMa-type system are known to occur every ∼ 450 d, none had ever been previously observed in the extreme ultra-violet (EUV) by ROSAT . The WFC observations began just ≈13 hr after the optical rise was detected. With a peak count rate of ∼ 4.5 count s⁻¹ in the S1 filter, SW UMa was temporarily the third brightest object in the sky in this waveband. Over the next ≈19 hr the measured EUV flux dropped to < 2 count s⁻¹, while the optical brightness remained essentially static at m _v∼11 . Similar behaviour has also been recently reported in the EUV light curve of the related SU UMa-type binary OY Car during superoutburst, as reported by Mauche & Raymond. In contrast, U Gem-type dwarf novae show no such early EUV dip during normal outbursts. Therefore, this feature may be common in superoutbursts of SU UMa-like systems. We expand on ideas first put forward by Osaki and Mauche & Raymond and offer an explanation for this behaviour by examining the interplay between the thermal and tidal instabilities that affect the accretion discs in these systems.     

Co-diagenesis of iron and phosphorus in hydrothermal sediments from the southern East Pacific Rise: Implications for the evaluation of paleoseawater phosphate concentrations

We present a detailed study of the co-diagenesis of Fe and P in hydrothermal plume fallout sediments from ∼19°S on the southern East Pacific Rise. Three distal sediment cores from 340-1130 km from the ridge crest, collected during DSDP Leg 92, were analysed for solid phase Fe and P associations using sequential chemical extraction techniques. The sediments at all sites are enriched in hydrothermal Fe (oxyhydr)oxides, but during diagenesis a large proportion of the primary ferrihydrite precipitates are transformed to the more stable mineral form of goethite and to a lesser extent to clay minerals, resulting in the release to solution of scavenged P. However, a significant proportion of this P is retained within the sediment, by incorporation into secondary goethite, by precipitation as authigenic apatite, and by readsorption to Fe (oxyhydr)oxides. Molar P/Fe ratios for these sediments are significantly lower than those measured in plume particles from more northern localities along the southern East Pacific Rise, and show a distinct downcore decrease to a depth of ∼12 m. Molar P/Fe ratios are then relatively constant to a depth of ∼35 m. The Fe and P speciation data indicate that diagenetic modification of the sediments is largely complete by a depth of 2.5 m, and thus depth trends in molar P/Fe ratios can not solely be explained by losses of P from the sediment by diffusion to the overlying water column during early diagenesis. Instead, these sediments are likely recording changes in dissolved P concentrations off the SEPR, possibly as a result of redistribution of nutrients in response to changes in oceanic circulation over the last 10 million years. Furthermore, the relatively low molar P/Fe ratios observed throughout these sediments are not necessarily solely due to losses of scavenged P by diffusion to the overlying water column during diagenesis, but may also reflect post-depositional oxidation of pyrite originating from the volatile-rich vents of the southern East Pacific Rise. This study suggests that the molar P/Fe ratio of oxic Fe-rich sediments may serve as a proxy of relative changes in paleoseawater phosphate concentrations, particularly if Fe sulfide minerals are not an important component during transport and deposition.     

A hybrid artificial neural network-numerical model for ground water problems

Numerical models constitute the most advanced physical-based methods for modeling complex ground water systems. Spatial and/or temporal variability of aquifer parameters, boundary conditions, and initial conditions (for transient simulations) can be assigned across the numerical model domain. While this constitutes a powerful modeling advantage, it also presents the formidable challenge of overcoming parameter uncertainty, which, to date, has not been satisfactorily resolved, inevitably producing model prediction errors. In previous research, artificial neural networks (ANNs), developed with more accessible field data, have achieved excellent predictive accuracy over discrete stress periods at site-specific field locations in complex ground water systems. In an effort to combine the relative advantages of numerical models and ANNs, a new modeling paradigm is presented. The ANN models generate accurate predictions for a limited number of field locations. Appending them to a numerical model produces an overdetermined system of equations, which can be solved using a variety of mathematical techniques, potentially yielding more accurate numerical predictions. Mathematical theory and a simple two-dimensional example are presented to overview relevant mathematical and modeling issues. Two of the three methods for solving the overdetermined system achieved an overall improvement in numerical model accuracy for various levels of synthetic ANN errors using relatively few constrained head values (i.e., cells), which, while demonstrating promise, requires further research. This hybrid approach is not limited to ANN technology; it can be used with other approaches for improving numerical model predictions, such as regression or support vector machines (SVMs).     

Mo isotope fractionation during adsorption to Fe (oxyhydr)oxides

Molybdenum (Mo) isotopes have great potential as a paleoredox indicator, but this potential is currently restricted by an incomplete understanding of isotope fractionations occurring during key (bio)geochemical processes. To address one such uncertainty we have investigated the isotopic fractionation of Mo during adsorption to a range of Fe (oxyhydr)oxides, under variable Mo/Fe-mineral ratios and pH. Our data confirm that Fe (oxyhydr)oxides can readily adsorb Mo, highlighting the potential importance of this removal pathway for the global Mo cycle. Furthermore, adsorption of Mo to Fe (oxyhydr)oxides is associated with preferential uptake of the lighter Mo isotopes. Fractionations between the solid and dissolved phase (Δ⁹⁸Mo) increase at higher pH, and also vary with mineralogy, increasing in the order magnetite (Δ⁹⁸Mo = 0.83 ± 0.60‰) < ferrihydrite (Δ⁹⁸Mo = 1.11 ± 0.15‰) < goethite (Δ⁹⁸Mo = 1.40 ± 0.48‰) < hematite (Δ⁹⁸Mo = 2.19 ± 0.54‰). Small differences in isotopic fractionation are also seen at varying Mo/Fe-mineral ratios for individual minerals. The observed isotopic behaviour is consistent with both fractionation during adsorption to the mineral surface (a function of vibrational energy) and adsorption of different Mo species/structures from solution. The different fractionation factors determined for different Fe (oxyhydr)oxides suggests that these minerals likely exert a major control on observed natural Mo isotope compositions during sediment deposition beneath suboxic through to anoxic (but non-sulfidic) bottom waters. Our results confirm that Mo isotopes can provide important information on the spatial extent of different paleoredox conditions, providing they are used in combination with other techniques for evaluating the local redox environment and the mineralogy of the depositing sediments.     

A Spitzer survey of young stellar objects in the Rosette Molecular Cloud

We present results from a survey of the Rosette Molecular Cloud (RMC) using both the Infrared Array Camera (IRAC) and Multiband Imaging Photometer for Spitzer (MIPS) onboard the Spitzer Space Telescope . We have mapped a region of active star formation covering an area approximately 1° by 1.5° including several previously known clusters. Spectral energy distributions (SEDs) fitted to our data combined with that from Two Micron All Sky Survey (2MASS) are used to identify young stellar objects (YSOs) with infrared (IR) excesses. We find that roughly 50 per cent of the sources are forming in clustered environments and identify seven clusters of IR excess sources including four that were previously unknown. We investigate evidence for triggering of star formation due to the ionization front, identified in Brackett-α emission, associated with the young open cluster NGC 2244. Although the position of several of the clusters of IR excess sources are coincident with the ionization front, the bulk of the youngest YSOs are located far from the ionization front, in clusters located along the mid-plane of the cloud. We conclude that although triggering from the H  ii nebula is a possible origin for some of the recent star formation, the majority of the active star formation is occurring in already dense regions of the cloud not compressed by the expansion of the H  ii region.     

Source-related classification of St. Lawrence estuary sediments based on spatial distribution of adsorbed contaminants

The St. Lawrence River upper estuary is a very large and efficient mixing zone for contaminated industrial discharges originating upstream, yet elevated levels of various toxic contaminants have persistently been reported in local biota, such as eels and Beluga whales. As part of an initial assessment of the role of bottom sediments in the fate and pathways of contaminants through the estuary ecosystem, we examine the spatial distributions of particle-reactive trace and major elements in shallow-water accumulation zones. Concentrations of more than 30 elements were determined by ICP atomic emission spectrography. A number of these (Ce, Cr, Fe, La, Ni, and Zn) proved to be useful as fine sediment tracers, despite the complicating effects of intense sediment mixing and varying grain size and salinity. Prior normalization of the concentration values with reference to aluminum was necessary in most cases to minimize bias caused by grain-size variation between samples; however, there was no means of compensating for the effect of variable salinity on trace element concentrations. Through the use of a combination of two statistical approaches, linear regression and cluster analysis (ratio-matching), two distinct depositional zones for modern sediments were resolved, each associated with a different source. The largest zone covered the western end and along the south shore of the upper estuary, while the other was confined to the northeastern shore. The western zone is characterized by high-metal-content brought in by the St. Lawrence River. The northeastern zone is distinguished by the presence of lanthanide and rare earth elements (Ce, Y), indicating that its sediment source is probably the watersheds draining the monazite-bearing Grenville Province of the Canadian Shield to the north. The statistical separation of these two sediment groupings supports the conclusion that the St. Lawrence River sediment plume follows the southern shore of the estuary. The more sparsely distributed modern sediment deposits along the north shore tend to be derived from local sources.     

Evolution of the oceanic sulfur cycle at the end of the Paleoproterozoic

Here, we present new measurements of ³²S, ³³S, ³⁴S, and ³⁶S in sedimentary sulfides and couple these measurements with modeling treatments to study the sulfur cycle of a late Paleoproterozoic marine basin. We target the transition in ocean chemistry from the deposition of Paleoproterozoic iron formations (Gunflint Formation, Biwabik Formation, Trommald Formation, and Mahnomen iron formations) to the inferred sulfidic ocean conditions recorded by overlying shale (Rove Formation). The data suggest that certain features of the global sulfur cycle, such as a control by sulfate reducing prokaryotes, and low (mM) concentrations of oceanic sulfate, were maintained across this transition. This suggests that the transition was associated with changes in the structure of the basin-scale sulfur cycle during deposition of these sediments. Sulfide data from the iron formations are interpreted to reflect sedimentary sulfides formed from microbial reduction of pore-water sulfate that was supplied through steady-state exchange with an overlying oceanic sulfate reservoir. The sulfide data for the euxinic Rove Formation shales reflect the operation of a sulfur cycle that included the loss of sulfide by a Rayleigh-like process. We suggest that the prevalence of large and variable heavy isotope enrichments observed in Rove Formation sulfide minerals reflect a sustained and significant net loss of sulfide from the euxinic water column, either as a result of a shallow chemocline and degassing to the atmosphere or as a result of a water column pyrite sink. The inclusion of ³⁶S measurements (in addition to ³²S, ³³S, and ³⁴S) illustrates the mass-dependent character of these sedimentary environments, ruling out contributions from the weathering of Archean sulfides and pointing to at least modest levels of sustained atmospheric oxygen (>10⁻⁵ present atmospheric levels of O₂).     

Redox sensitivity of P cycling during marine black shale formation: Dynamics of sulfidic and anoxic, non-sulfidic bottom waters

A high-resolution geochemical record of a 120 cm black shale interval deposited during the Coniacian-Santonian Oceanic Anoxic Event 3 (ODP Leg 207, Site 1261, Demerara Rise) has been constructed to provide detailed insight into rapid changes in deep ocean and sediment paleo-redox conditions. High contents of organic matter, sulfur and redox-sensitive trace metals (Cd, Mo, V, Zn), as well as continuous lamination, point to deposition under consistently oxygen-free and largely sulfidic bottom water conditions. However, rapid and cyclic changes in deep ocean redox are documented by short-term (∼15-20 ka) intervals with decreased total organic carbon (TOC), S and redox-sensitive trace metal contents, and in particular pronounced phosphorus peaks (up to 2.5 wt% P) associated with elevated Fe oxide contents. Sequential iron and phosphate extractions confirm that P is dominantly bound to iron oxides and incorporated into authigenic apatite. Preservation of this Fe-P coupling in an otherwise sulfidic depositional environment (as indicated by Fe speciation and high amounts of sulfurized organic matter) may be unexpected, and provides evidence for temporarily non-sulfidic bottom waters. However, there is no evidence for deposition under oxic conditions. Instead, sulfidic conditions were punctuated by periods of anoxic, non-sulfidic bottom waters. During these periods, phosphate was effectively scavenged during precipitation of iron (oxyhydr)oxides in the upper water column, and was subsequently deposited and largely preserved at the sea floor. After ∼15-25 ka, sulfidic bottom water conditions were re-established, leading to the initial precipitation of CdS, ZnS and pyrite. Subsequently, increasing concentrations of H₂S in the water column led to extensive formation of sulfurized organic matter, which effectively scavenged particle-reactive Mo complexes (thiomolybdates). At Site 1261, sulfidic bottom waters lasted for ∼90-100 ka, followed by another period of anoxic, non-sulfidic conditions lasting for ∼15-20 ka. The observed cyclicity at the lower end of the redox scale may have been triggered by repeated incursions of more oxygenated surface- to mid-waters from the South Atlantic resulting in a lowering of the oxic-anoxic chemocline in the water column. Alternatively, sea water sulfate might have been stripped by long-lasting high rates of sulfate reduction, removing the ultimate source for HS⁻ production.