Optical spectrum based measurement of flotation slurry contents

Monitoring and control of a flotation circuit is mainly based on the information gained by assaying the process slurry lines. In flotation plants, usually an X-ray fluorescence analyzer is used to obtain the on-line assays. This article introduces the visual and near-infrared reflectance spectroscopic analysis of the process slurries as a supplementary method which complements the on-line assay information available from an X-ray fluorescence analyzer. It is shown that the spectral information can be used to accurately predict the element contents in the slurry in between successive XRF analyses. Since the spectral measurements can be taken with high frequency as opposed to the sparse X-ray fluorescence analysis, a practically continuous on-line estimate of the slurry contents is reached. These estimates can be used in the plant control to improve the overall performance of the circuits and to yield also economical savings. Additionally, the frequent monitoring of the grades can provide means to eliminate rapid disturbances in the circuits, thus improving the stability of the process.     

Climate and Water: From Climate Models to Water Resources Management and Vice Versa

This article reviews the recent developments in the functional chain from climate models to climate scenarios, through hydrology all the way to water resources management, design and policy making. Although climate models, such as Global Circulation Models (GCMs) continue to evolve, their outputs remain crude and often even inappropriate to watershed-scale hydrological analyses. The bridging techniques are evolving, though. Many families of regionalization technologies are under progress in parallel. Perhaps the most important advances are in the field of regional weather patterns, such as ENSO (El Niño-Southern Oscillation), NAO (North Atlantic Oscillation) and many more. The gap from hydrology to water resources development is by far not that wide. The traditional and contemporary practices are well in place. In climate change studies, the bottleneck is not in this link itself but in the climatic input. The tendency seems to be towards integrated water resources assessments, where climate is only one among many changes that are expected to occur, such as demography, land cover and land use, economy, technologies, and so forth. In such a pragmatic setting a risk–analytic interpretation of those scenarios is often called for. The above-outlined continuum from climate to water is a topic where the physically based modelers, the empiricists and the pragmatists should not get restricted to their own way of thinking. The issues should develop hand in hand. Perhaps the greatest challenge is to incorporate and respect the pragmatic policy-related component to the two other branches. For this purpose, it is helpful to reverse the direction of thinking from time to time to start—instead of climate models—from practical needs and think how the climate scenarios and models help really in the difficult task of designing better water structures, outline better policies and formulate better operational rules in the water field.     

Seasonal residence and counterurbanization: the role of second homes in population redistribution in Finland

Since the late twentieth century, many developed countries have experienced population deconcentration, labelled as counterurbanization. There has been an academic discussion on the meaning, validity and universality of this concept, drivers of counterurbanization and its impacts on rural areas. To date, research on counterurbanization mostly apply static and discrete definitions of residence, migration and population, which is an increasingly simplistic view in the contemporary reality of a growing multitude of forms of mobility, often related to dual residence. Particularly large-scale quantitative studies on counterurbanization are confined by existing statistical practices. This paper attempts to overcome this obstacle and describe the transformation of the settlement system in Finland acknowledging the role of second home mobility. To achieve this goal, it introduces two alternative measures of population, seasonal and average population, and analyses their spatial dynamics between the years 1990 and 2010 based on georeferenced grid statistical data. The study finds that although registered population has been concentrating during the period in analysis, seasonal population has been increasingly dispersed due to the growing number of second homes. It shows that the counterurbanization process, though not noticed by conventional statistics, does occur in Finland, manifested by seasonal rather than permanent moves. The article concludes that various forms of mobility should be taken into account when analysing the urban–rural population dynamics and transformations of settlement systems as well as in rural development planning.     

Discussion of “Challenges in operationalizing the water–energy–food nexus”*

ABSTRACT

We greatly enjoyed reading the paper by Liu et al., which is both timely and rich in insight, as it discusses the challenges in operationalizing the water–energy–food security (WEF) nexus. The nexus approach is gaining increasing attention, both in research and in policy documents, as reflected in the number and content of published documents in the past years and highlighted by the authors.     

Weathering of phlogopite in simulated bioleaching solutions

The purpose of this study was to examine structural alterations of finely ground phlogopite, a trioctahedral mica, when exposed to acid, iron- and sulfate-rich solutions typical of bioleaching systems. Phlogopite suspensions were supplemented with ferrous sulfate and incubated with iron- and sulfur-oxidizing bacteria (Acidithiobacillus ferrooxidans) at 22 °C. As bacteria oxidized ferrous iron, ferric iron thus formed partially precipitated as K-jarosite. K-jarosite precipitation was contingent on the preceding ferrous iron oxidation by bacteria and the release of interlayer-K from phlogopite. This chemically and microbially induced weathering involved alteration of phlogopite to a mixed layer structure that included expansible vermiculite. The extent of phlogopite weathering and structure expansion varied with duration of the contact, concentration of ferrous iron and phlogopite, and the presence of monovalent cations (NH₄⁺, K⁺, or Na⁺) in the culture solution. NH₄⁺ and K⁺ ions (100 mM) added to culture suspensions precipitated as jarosite and thereby effectively prevented the loss of interlayer-K and structural alteration of phlogopite. Additional Na⁺ (100 mM) was insufficient to precipitate ferric iron as natrojarosite and therefore the precipitation was coupled with interlayer-K released from phlogopite. When ferrous iron was replaced with elemental sulfur as the substrate for A. ferrooxidans, the weathering of phlogopite was based on chemical dissolution without structural interstratification. The results demonstrate that iron oxidation and the concentration and composition of monovalent ions can have an effect on mineral weathering in leaching systems that involve contact of phlogopite and other mica minerals with acid leach solutions.     

Ejective and Sweeping Motions Above a Peatland and Their Role in Relaxed-Eddy-Accumulation Measurements and Turbulent Transport Modelling

The three turbulent velocity components, water vapour (\(\text {H}_2\text {O}\)), carbon dioxide (\(\text {CO}_{2}\)), and methane (\(\text {CH}_{4}\)) concentration fluctuations are measured above a boreal peatland and analyzed using conditional sampling and quadrant analysis. The overarching question to be addressed is to what degree lower-order cumulant expansion methods describe transport efficiency and the relative importance of ejections and sweeps to momentum, \(\text {CH}_{4}\), \(\text {CO}_{2}\) and \(\text {H}_2\text {O}\) fluxes across a range of atmospheric flow regimes. The patchy peatland surface creates distinctly different source and sink distributions for the three scalars in space and time thereby adding to the uniqueness of the set-up. The measured and modelled fractional contributions to the momentum flux show that sweep events dominate over ejections in agreement with prior studies conducted in the roughness sublayer. For scalar fluxes, ejections dominate the turbulent fluxes over sweeps. While ejective motions persist longer for momentum transport, sweeping events persist longer for all three scalars. Third-order cumulant expansions describe many of the results detailed above, and the results are surprising given the highly non-Gaussian distribution of \(\text {CH}_{4}\) turbulent fluctuations. Connections between the asymmetric contributions of sweeps and ejections and the flux-transport term arising in scalar turbulent-flux-budget closure are derived and shown to agree reasonably well with measurements. The proposed model derived here is much simpler than prior structural models used to describe laboratory experiments. Implications of such asymmetric contributions on, (i) the usage of the now proliferating relaxed-eddy-accumulation method in turbulent flux measurements, (ii) the constant-flux assumption, and (iii) gradient-diffusion closure models are presented.     

The development of a non-linear autoregressive model with exogenous input (NARX) to model climate-water clarity relationships: reconstructing a historical water clarity index for the coastal waters of the southeastern USA

Theoretical and Applied Climatology - The coastal waters of the southeastern USA contain important protected habitats and natural resources that are vulnerable to climate variability and singular...     

Estimation of winter leaf area index and sky view fraction for snow modelling in boreal coniferous forests: consequences on snow mass and energy balance

Leaf area index (LAI) and canopy coverage are important parameters when modelling snow process in coniferous forests, controlling interception and transmitting radiation. Estimates of LAI and sky view factor show large variability depending on the estimation method used, and it is not clear how this is reflected in the calculated snow processes beneath the canopy. In this study, the winter LAI and sky view fraction were estimated using different optical and biomass‐based approximations in several boreal coniferous forest stands in Fennoscandia with different stand density, age and site latitude. The biomass‐based estimate of LAI derived from forest inventory data was close to the values derived from the optical measurements at most sites, suggesting that forest inventory data can be used as input to snow hydrological modelling. Heterogeneity of tree species and site fertility, as well as edge effects between different forest compartments, caused differences in the LAI estimates at some sites. A snow energy and mass balance model (SNOWPACK) was applied to detect how the differences in the estimated values of the winter LAI and sky view fraction were reflected in simulated snow processes. In the simulations, an increase in LAI and a decrease in sky view fraction changed the snow surface energy balance by decreasing shortwave radiation input and increasing longwave radiation input. Changes in LAI and sky view fraction affected directly snow accumulation through altered throughfall fraction and indirectly snowmelt through the changed surface energy balance. Changes in LAI and sky view fraction had a greater impact on mean incoming radiation beneath the canopy than on other energy fluxes. Snowmelt was affected more than snow accumulation. The effect of canopy parameters on evaporation loss from intercepted snow was comparable with the effect of variation in governing meteorological variables such as precipitation intensity and air temperature. Copyright © 2012 John Wiley & Sons, Ltd.     

Discussion of “Challenges in operationalizing the water–energy–food nexus”*

ABSTRACT

We greatly enjoyed reading the paper by Liu et al., which is both timely and rich in insight, as it discusses the challenges in operationalizing the water–energy–food security (WEF) nexus. The nexus approach is gaining increasing attention, both in research and in policy documents, as reflected in the number and content of published documents in the past years and highlighted by the authors.