The arsenic source term for an in-pit uranium mine tailings facility and its long-term impact on the regional groundwater

Detailed field sampling and analyses and laboratory-based diffusion-cell experiments were used in conjunction with 3-D reactive transport modeling (MODFLOW and MT3D99) to quantify the fate and long-term (10 ka) transport of As in the Rabbit Lake In-pit Tailings Management Facility (RLITMF), northern Saskatchewan, Canada. The RLITMF (300 m × 425 m × 90 m thick) was engineered to ensure solute transport within the RLITMF is dominated by diffusion. Concentrations of As in the tailings pore fluids ranged from 0.24 to 140 mg/L (n = 43). Arsenic speciation analyses indicate 90% of this arsenic exists as As⁵⁺. This observation is supported by pH–Eh measurements of pore fluids (n = 135). Geochemical analyses yielded a strong inverse correlation between the Fe/As molar ratio in the tailings solids and the corresponding concentration of dissolved As, which is attributed to the adsorption of As to secondary 2-line ferrihydrite present in the tailings. Diffusion-cell testing yielded values for the effective diffusion coefficient, sorption coefficient, and effective porosity of As in the tailings of 4.5 × 10⁻¹⁰ m²/s, 2–4 cm³/g and 0.36, respectively. Reactive transport simulations using the field and laboratory data show adsorption of As to the tailings and diffusive transport of dissolved As in the tailings should reduce the source term concentration of As to between 40% and 70% of the initial concentrations over the 10 ka simulation period. Based on these simulations, the As concentrations in the regional groundwater, 50 m down gradient of the tailings facility, should be maintained at background concentrations of 0.001 mg/L over the 10 ka period. These findings suggest the engineered in-pit disposal of U mine tailings can provide long-term protection for the local groundwater regime from As contamination.     

Japan’s urban singles: negotiating alternatives to family households and standard housing pathways

In comparison to other advanced economies, the rise of people living alone in Japan has been late and rapid, with singletons now accounting for almost half of all households in major cities. The normative and structural frameworks surrounding standard family-household formation, however, remain formidable, reducing life-course opportunities for non-family formers. This paper considers the household and housing pathways being negotiated by younger-adults living independently. In addition to various secondary data sources, we draw on qualitative interviews with 35 individuals from 28 Tokyo households in addressing manifestations of, and resistance to, atomisation and individualisation in the Japanese context. Our analysis focuses on meanings and practices of homemaking among renters and buyers in the growing sector of single-person dwellings, as well as the recent emergence of commercial shared housing . This analysis provides a contrast to discourses surrounding the “singles boom” and “the growing appeal of living alone” in Western cities.     

Natural flood management,land use and climate change trade-offs: the case of Tarland catchment,Scotland

A distributed hydrological model (WaSiM-ETH) was applied to a mesoscale catchment to investigate natural flood management as a nonstructural approach to tackle flood risks from climate change. Peak flows were modelled using climate projections (UKCP09) combined with afforestation-based land-use change options. A significant increase in peak flows was modelled from climate change. Afforestation could reduce some of the increased flow, with greatest benefit from coniferous afforestation, especially replacing lowland farmland. Nevertheless, large-scale woodland expansion was required to maintain peak flows similar to present and beneficial effects were significantly reduced for larger “winter-type” extreme floods. Afforestation was also modelled to increase low-flow risks. Land-use scenarios showed catchment-scale trade-offs across multiple objectives meant “optimal” flood risk solutions were unlikely, especially for afforestation replacing lowland farmland. Hence, combined structural/nonstructural measures may be required in such situations, with integrated catchment management to synergize multiple objectives.     

The characteristics of the chemical flow within the Motru catchment area, south — west Romania

The present paper, with reference to the Motru catchment area, contributes to the hydrochemical studies at an international level and to the completion of the characteristics regarding the chemical flow in Romania. In this regard, it emphasizes once again the dependence between the content of dissolved salts (fixed residue — mg/l) on the one hand and the lithological conditions, human activity, flow and the surface of the catchments on the other hand. The calculation and the analysis of the chemical flow for the Motru catchment area (located in the south-west of Romania) was performed on the basis of two parameters: the average flow of dissolved chemical substances (mg/s) and specific average chemical flow (t/kmp year) recorded at the monitoring stations on the Motru River and its tributaries during the period 2005–2009. The values obtained (for example: 2.63 mg/s and 47.7 t/km² year, at the Fata Motrului station, on the Motru River, in 2009) confirm the importance of the areal factors of natural background in the analysis of chemical flow as a morpho-dynamic process and implicitly for the chemical quality of surface waters.     

On the period variability of GP andromedae

The present paper deals with the pulsation period variability of the high-amplitude δ Scuti star GP Andromedae using a data set covering a time base of 26.9 years. The possibility of a periodic component (reflecting the light-time effect induced by a hypothetic binarity) in the O-C curve is inferred. The presence of this periodicity in the period variation of GP And leads to a diminution of the discrepancy between predicted and observed relative period change rates. The hypothesis of the existence of an unseen companion is discussed. The statistical analysis of the final O-C residuals distribution, indicates their normal or close to normal character. This revised version was published online in July 2006 with corrections to the Cover Date.     

Water isotopic variability in Mallorca: a path to understanding past changes in hydroclimate

This paper reports the first results on δ¹⁸O and δ²H analysis of precipitations, cave drip waters, and groundwaters from sites in Mallorca (Balearic Islands, western Mediterranean), a key region for paleoclimate studies. Understanding the isotopic variability and the sources of moisture in modern climate systems is required to develop speleothem isotope‐based climate reconstructions. The stable isotopic composition of precipitation was analysed in samples collected between March 2012 and March 2013. The values are in the range reported by GNIP Palma station. Based on these results, the local meteoric water line (LMWL) δ²H = 7.9 (±0.3) δ¹⁸O + 10.8 (±2.5) was derived, with slightly lower slope than Global Meteoric Water Line. The results help tracking two main sources of air masses affecting the study sites: rain events with the highest δ¹⁸O values (> ?5‰) originate over the Mediterranean Sea, whereas the more depleted samples (< ?8‰) are sourced in the North Atlantic region. The back trajectory analysis and deuterium excess values, ranging from 0.4 to 18.4‰, further support our findings. To assess the isotopic variation across the island, water samples from eight caves were collected. The δ¹⁸O values range between ?6.9 and ?1.6‰. With one exception (Artà), the isotopic composition of waters in caves located along the coast (Drac, Vallgornera, Cala Varques, Tancada, and Son Sant Martí) indicates Mediterranean‐sourced moisture masses. By contrast, the drip water δ¹⁸O values for inland caves (Campanet, ses Rates Pinyades) or developed under a thick (>50 m) limestone cap (Artà) exhibit more negative values. A well‐homogenized aquifer supplied by rainwaters of both origins is clearly indicated by groundwater δ¹⁸O values, which show to be within 2.4‰ of the unweighted arithmetic mean of ?7.4‰. Although limited, the isotopic data presented here constitute the baseline for future studies using speleothem δ¹⁸O records for western Mediterranean paleoclimate reconstructions. Copyright © 2016 John Wiley & Sons, Ltd.     

Carbon Dioxide and Methane Dynamics in Three Coastal Systems of Cadiz Bay (SW Spain)

The partial pressure of CO₂ (pCO₂) and concentration of dissolved CH₄ in surface waters have been studied in three coastal systems connected to Cadiz Bay (southwestern coast of Spain) over different time scales. The concentration of CH₄ varied from 1 to 4200 nmol kg^?1 (192.1 ± 463.6 nmol kg^?1) and the saturation percent from 19 to 159,577% (6645 ± 16,921%), and pCO₂ from 315 to 3240 μatm (841.9 ± 466.3 μatm), with saturation percent values varying between 72 and 981% (220 ± 133%). The seasonal variation of pCO₂ mainly depends on the temperature. On the contrary, the annual distribution of dissolved CH₄ is associated with the precipitation regime. In addition, pCO₂ and dissolved CH₄ showed spatial variation. pCO₂ increased toward the inner part of the systems, with the proximity to the discharge points from human activities. Dissolved CH₄ is influenced by both anthropogenic inputs and natural processes such as benthic supply and exchange with the adjacent salt marshes. pCO₂ and dissolved CH₄ also varied with the tides: The highest concentrations were measured during the ebb, which suggests that the systems export CO₂ and CH₄ to the Bay and adjacent Atlantic Ocean.     

Distribution patterns of subsurface copepods and the impact of environmental parameters

The ecosystem dynamics in the vadose zone, the unsaturated layer between the surface and the groundwater table, was studied in five caves located in northwestern Romania. Hypogean and epigean copepod assemblages collected in drip water and in the associated pools were analyzed over a period of 12 and 7 months, respectively. The temporal variation of fauna in both habitats was related to a series of environmental parameters (pH, temperature, electrical conductivity, forest cover, precipitation, type of limestone, hydrographic basin, substrate and volume of the pools). Canonical Correspondence Analysis was used to explore the relationships. Over the year, total abundances in pools were much lower than the abundances observed in drips and showed steep raising values in December only. It is shown that forest cover might be one of the most important driving factor influencing the copepod diversity and abundance. Occurrence of epigean species underground was influenced by precipitation and drip rates. The occurrence of hypogean species was related to electrical conductivity, as an indicator of residence time of water in the vadose zone. Pools on limestone harbored a more diverse and abundant fauna than those with clay sediments. Pools with calcite precipitation were preferred by hypogean species.     

Y Leonis: light curve solution revised and search for photometric variations of the primary minima

The interest in the study of the Algol binary system Y Leonis is justified not only by its light curve having a very deep primary minimum, and pulsating character of its primary component, but also by the complex behavior of its O–C curve which is featured by the presence of long and short time scale modulations. Taking into account the previously inferred K spectral type of the secondary component, one may expect that one of the involved periodicities could be related to magnetic cycles of this star. We gave the Wilson-Devinney solution of the eclipse light curve using our observational data obtained during 2009. The long- and short-term photometric variability of Y Leo is approached both through literature data and new CCD data. Even though these data are scarce, they revealed significant variability in the maximum and minimum brightness of this binary system at long time-scale. The nature of the rapid photometric variations during the deepest phase of primary minima can hardly be explained only by weak δ Scuti pulsations of the primary component which is still visible in partial eclipses.     

Volcanic gases and sublimates from Showashinzan

Volcanic gases from Showashinzan are qualitatively the same as those liberated from igneous rocks when they are heated in vacuum. Their main components are H₂O, CO₂, and H₂. Then follow HCl, HF, N₂, SO₂, H₂S, S, CH₄, CO, Ar, Si, B, Mg, Na, K, Ca, Al, Fe, P, Br, NH₃, As, Zn, Sr, Ba, Cu, Pb, Sn, Sb, Bi, Ge, Ag, Cr, Ni, Mo, Rn, Ra, etc. They come through fumaroles of high temperature (～750°C.). Metallic compounds deposit as sublimates around the outlet of fumaroles. They are fractionated there according to their thermodynamic properties. When the temperature of gases falls, heavy metal elements deposit before reaching the surface of the earth. Ra is among them. Owing to the contribution of Ra thus depositted, Rn content of vapor is larger in low temperature fumaroles than in high temperature ones. Chemical compounds of H, C, N, O, and S vary their composition according to the condition of temperature and pressure. Sulfur exists as SO₂ more than H₂S. As the temperature of gases falls, SO₂ and H₂ decrease and H₂S increases. Mutual relation among them is ruled by the chemical equilibrium: SO₂+3H₂=H₂S+2H₂O. The structure of Showashinzan is not simple. Some deviations from the general rule are explained in connection with ground water.