Palynofacies and sea-level changes in the Upper Cretaceous of the Vocontian Basin, southeast France

Upper Cretaceous platform carbonates of the Vocontian Basin (southeastern France) have been investigated in a cross-section from the proximal deposits exposed in the lower Rhône Valley to the distal part of the basin in the Southern Subalpine Ranges north of Nice. The stratigraphic interval studied in detail spans the uppermost Turonian and Coniacian.Palynofacies patterns were used to detect eustatic signals at a third-order scale and are the tool for correlation of proximal and distal platform deposits. The organic constituents observed in the studied samples have been grouped into a continental fraction, including higher plant debris (phytoclasts) and sporomorphs, and a marine fraction with dinoflagellate cysts, acritarchs, prasinophytes, and foraminiferal test linings. The main factors influencing the stratigraphic and spatial distribution of land-derived, allochthonous, and marine, relatively autochthonous, organic particles are the proximity of land, the organic productivity, the degree of biodegradation and the hydrodynamic conditions of the depositional system. Palynofacies parameters used for the sequence stratigraphic interpretation are: (1) the ratio of continental to marine constituents (CONT/MAR ratio); (2) the ratio of opaque to translucent phytoclasts (OP/TR ratio); (3) the phytoclast particle size and shape; and (4) the relative proportion and species diversity of marine plankton. Ternary diagrams illustrating significant proximality changes were used to decipher transgressive-regressive trends within the succession.High amounts of translucent phytoclasts and decreasing values of the CONT/MAR ratio occur during the phase of relative sea-level rise in the upper Turonian. The stratigraphic interval of maximum flooding around the Turonian/Coniacian boundary is marked by the highest abundance and species diversity of dinoflagellate cysts, and by high percentages of opaque, equidimensional particles within the phytoclast group. The OP/TR ratio is still high within the lower Coniacian representing the early highstand deposits, whereas the relative abundance of marine constituents is again decreasing. Sedimentary organic matter of the upper Coniacian is dominated by large, blade-shaped, mainly opaque phytoclasts, which are a characteristic palynofacies signature of late highstand deposits.The present study demonstrates the high potential of palynofacies analysis in high-resolution stratigraphy and correlation of sedimentary series of shallow epeiric seas.     

Fast static correction methods for high-frequency multichannel marine seismic reflection data: A high-resolution seismic study of channel-levee systems on the Bengal Fan

Very high-frequency marine multichannel seismic reflection data generated by small-volume air- or waterguns allow detailed, high-resolution studies of sedimentary structures of the order of one to few metres wavelength. The high-frequency content, however, requires (1) a very exact knowledge of the source and receiver positions, and (2) the development of data processing methods which take this exact geometry into account. Static corrections are crucial for the quality of very high-frequency stacked data because static shifts caused by variations of the source and streamer depths are of the order of half to one dominant wavelength, so that they can lead to destructive interference during stacking of CDP sorted traces. As common surface-consistent residual static correction methods developed for land seismic data require fixed shot and receiver locations two simple and fast techniques have been developed for marine seismic data with moving sources and receivers to correct such static shifts. The first method – called CDP static correction method – is based on a simultaneous recording of Parasound sediment echosounder and multichannel seismic reflection data. It compares the depth information derived from the first arrivals of both data sets to calculate static correction time shifts for each seismic channel relative to the Parasound water depths. The second method – called average static correction method – utilises the fact that the streamer depth is mainly controlled by bird units, which keep the streamer in a predefined depth at certain increments but do not prevent the streamer from being slightly buoyant in-between. In case of calm weather conditions these streamer bendings mainly contribute to the overall static time shifts, whereas depth variations of the source are negligible. Hence, mean static correction time shifts are calculated for each channel by averaging the depth values determined at each geophone group position for several subsequent shots. Application of both methods to data of a high-resolution seismic survey of channel-levee systems on the Bengal Fan shows that the quality of the stacked section can be improved significantly compared to stacking results achieved without preceding static corrections. The optimised records show sedimentary features in great detail, that are not visible without static corrections. Limitations only result from the sea floor topography. The CDP static correction method generally provides more coherent reflections than the average static correction method but can only be applied in areas with rather flat sea floor, where no diffraction hyperbolae occur. In contrast, the average static correction method can also be used in regions with rough morphology, but the coherency of reflections is slightly reduced compared to the results of the CDP static correction method.     

Detection of DNA damage in mussels and sea urchins exposed to crude oil using comet assay

The single-cell microgel electrophoresis assay or the comet assay was used to evaluate DNA damage of dispersed crude oil on sea urchins (Strongylocentrotus droebachiensis) and mussels (Mytilus edulis L.). Sea urchins were exposed to 0.06 and 0.25 mg/L dispersed crude oil in a continuous flow system, while the mussels were exposed to 0.015, 0.06 and 0.25 mg/L dispersed crude oil. Sea urchin coelomocytes and mussel haemocytes were sampled after 4 and 5 weeks exposure, respectively. In the sea urchin coelomocytes, there was a significant concentration-related increase in the percentage of DNA in comet tail. In mussel haemocytes, there was a significantly higher percentage of DNA in comet tail for all treatments compared to the control. The responses were concentration-related up to 0.06 mg/L oil. The two highest exposure concentrations of mussels were not significantly different from each other. These results indicate that the comet assay can be used for biomonitoring of DNA damage in marine invertebrates following oil contamination.     

Die Rheingrabenrandverwerfung im Wattkopftunnel bei Ettlingen (Nordschwarzwald)

The Wattkopftunnel, near Ettlingen (Nordschwarzwald), drives through the eastern margin of the Rheingraben. The tunnel passes cenozoic and mesozoic sediments. Early quarternary and tertiary beds are situated west of the main thrust of the Rheingraben. Fossil record indicates upper Oligocene age (Chatt) for parts of the tertiary sediments. At the eastern border of the Rheingraben, wedges of jurassic and middle triassic series are squeezed. East of the Rheingraben the tunnel drives in the lower triassic Bausandstein. The eastern margin of the Rheingraben was investigated in detail during tunneling. Faults of the Rheingraben margin are distributed in an 130 meter wide fault zone in the tunnel. Total stratigraphic separation by the normal faults reaches more than 2 000 meters. The cenozoic sequence suffered synsedimentary to early diagenetic deformation, while the mesozoic series are characterized by ruptural deformation. The fault- and joint system is directed in the rheinische Richtung (SSW-NNE). East of the Rheingraben a second direction occur, running parallel to the lower Albtal (W-E).

     

Microbial Degradation of Tar Oil Compounds under Different Redox Conditions

The microbial transformation of typical tar oil compounds such as acridine, benzo(b)thiophene, dibenzofuran, indane, and indene under different redox conditions was investigated in microcosm studies. Under aerobic conditions the inherent contamination in polluted soil as well as the added N‐, S‐, O‐ heterocyclic and homocyclic compounds were transformed predominantly apart from thiophene. 1‐Indanone was detected by RP‐HPLC‐DAD and GC‐MS as an intermediate metabolite from indane and indene. Under nitrate and sulfate reducing conditions indane, benzo(b)thiophene, and dibenzofuran were transformed in assays with the polluted soil samples from well B 65 and B 66 within 426 days, whereas they were persistent in assays with the highly polluted soil B 67. All heterocyclic and homocyclic compounds added to the non‐contaminated soil from well B 85 were not degraded under nitrate and sulfate reducing conditions, too. The results indicate that for the decision, wether natural attenuation can be implemented in the remediation of contaminated site, in addition to BTEX and PAHs especially the fate of further tar oil compounds in anoxic aquifers has to be considered.     

A hydropedological approach to simulate streamflow and soil water contents with SWAT+

Reflecting internal catchment hydrological processes in hydrological models is important for accurate predictions of the impact of climate and land-use change on water resources. Characterizing these processes is however difficult and expensive due to their dynamic nature and spatio-temporal variability. Hydropedology is a relatively new discipline focusing on the synergistic integration of hydrology, soil physics and pedology. Hydropedological interpretations of soils and soil distribution can be used to characterize key hydrological processes, especially in areas with no or limited hydrometric measurements. Here we applied a hydropedological approach to reflect flowpaths through detailed routing in SWAT+ for a 157 ha catchment (Weatherley) in South Africa. We compared the hydropedological approach and a standard (no routing) approach against measured streamflow (two weirs) and soil water contents (13 locations). The catchment was treated as ‘ungauged’ and the model was not calibrated against hydrometric measurements in order to determine the direct contribution of hydropedology on modelling efficiency. Streamflow was predicted well without calibration (NSE > 0.8; R² > 0.82) for both approaches at both weirs. The standard approach yielded slightly better streamflow predictions. The hydropedological approach resulted in considerable improvements in the simulation of soil water contents (R² increased from 0.40 to 0.49 and PBIAS decreased from 40% to 20%). The routing capacity of SWAT+ as employed in the hydropedological approach reduced the underestimation of wetland water regimes drastically and resulted in a more accurate representation of the dominant hydrological processes in this catchment. We concluded that hydropedology can be a valuable source of ‘soft data’ to reflect internal catchment structure and processes and, potentially, for realistic calibrations in other studies, especially those conducted in areas with limited hydrometric measurements.