Learning about learning: lessons from public engagement and deliberation on urban river restoration

This paper provides a new discussion of how people learn through deliberative processes, drawing upon empirical analysis of a novel public engagement process for urban river restoration. Such critical evaluation is rare and yet will be crucial to both theoretical development and learning about engagement practice, not least in a policy area subject to strong regulatory drivers for public participation. The analysis supports two important learning mechanisms – the use of 'gatekeepers' of knowledge, interests and values, and the privileging of narrative. It provides new evidence of instrumental and communicative learning about shared priorities and criteria for effective river restoration that evolved through the deliberative process and directly informed the restoration scheme. It is important to question whether and how such site or context-specific learning might inform other restoration schemes. Finally, the paper questions the often ignored issue of expert learning, not least the issue of the link between individual and organizational learning.     

Experimental authigenesis of phyllosilicates from feldspathic sands

Hydrothermal experiments with primary detrital components of feldspathic sands (orthoclase, albite, quartz, and calcite) were conducted to simulate possible diagenetic changes in geosynclinal sedimentary accumulations and the geothermal reservoir of the Imperial Valley area, California. Phyllosilicate and zeolite mineralization was produced at 200°C and 1 Kb Ph₂o and at 300°C and 1 and 3 Kb Ph₂o. Scanning electron microscope examination of the detrital grains shows the development of authigenic minerals and solution features. Phyllosilicate development occurred as dense surface coatings on orthoclase crystals in concentrated brines and as scattered grain clusters in dilute brines. Cation concentration is considered to be a controlling factor in phyllosilicate formation and growth. During formation the phyllosilicate crystals appear to utilize the surficial feldspar lattice structure as a preferred growth site. Electron diffraction studies indicate the crystals are a 1 Md mica similar to illite. Initial phyllosilicate formation occurs principally on orthoclase in systems containing this mineral, but is disseminated on other mineral surfaces in systems without orthoclase. This experimental development of authigenetic illite via the destruction of potassium feldspar may offer a potential mechanism to help explain the resulting mineralogy of diagenetic processes occurring in natural sediments such as in feldspathic sands and argillaceous sediments.     

Microbial biomineralization processes forming modern Ca:Mg carbonate stromatolites

Modern Ca:Mg carbonate stromatolites form in association with the microbial mat in the hypersaline coastal lagoon, Lagoa Vermelha (Brazil). The stromatolites, although showing diversified fabrics characterized by thin or crude lamination and/or thrombolitic clotting, exhibit a pervasive peloidal microfabric. The peloidal texture consists of dark, micritic aggregates of very high‐Mg calcite and/or Ca dolomite formed by an iso‐oriented assemblage of sub‐micron trigonal polyhedrons and organic matter. Limpid acicular crystals of aragonite arranged in spherulites surround these aggregates. Unlike the aragonite crystals, organic matter is present consistently in the dark, micritic carbonate comprising the peloids. This organic matter is observed as sub‐micron flat and filamentous mucus‐like structures inside the interspaces of the high‐Mg calcite and Ca dolomite crystals and is interpreted as the remains of degraded extracellular polymeric substances. Moreover, many fossilized bacterial cells are associated strictly with both carbonate phases. These cells consist mainly of 0·2 to 4 μm in diameter, sub‐spherical, rod‐like and filamentous forms, isolated or in colony‐like clusters. The co‐existence of fossil extracellular polymeric substances and bacterial bodies, associated with the polyhedrons of Ca:Mg carbonate, implies that the organic matter and microbial metabolism played a fundamental role in the precipitation of the minerals that form the peloids. By contrast, the lack of extracellular polymeric substances in the aragonitic phase indicates an additional precipitation mechanism. The complex processes that induce mineral precipitation in the modern Lagoa Vermelha microbial mat appear to be recorded in the studied lithified stromatolites. Sub‐micron polyhedral crystal formation of high‐Mg calcite and/or Ca dolomite results from the coalescence of carbonate nanoglobules around degraded organic matter nuclei. Sub‐micron polyhedral crystals aggregate to form larger ovoidal crystals that constitute peloids. Subsequent precipitation of aragonitic spherulites around peloids occurs as micro‐environmental water conditions around the peloids change.     

A Barometer for Garnet Amphibolites and Garnet Granulites

new barometer based on the equilibrium: has been calibrated with experiments conducted in the piston-cylinderapparatus. Reversed equilibria have been obtained using well-calibrated2-54 cm NaCl furnace assemblies, Ag₈₀Pd₂₀capsules withf_O2 bufferedat or near iron-wustite. The equilibrium is located between10.6–10.8,12.0–12.2, 13.2–13.4 and 14.2–14.4kb, at 800, 900, 1000, and 1100?C, respectively. The barometer is applicable in both garnet-bearing amphibolitesand granulites. Its greatest potential is in garnet amphiboliteswherein multi-variant amphibole-bearing mineral assemblagesdo not define pressure and few, if any, well-calibrated barometersare available. Application of the garnet-rutile-ilmenite-plagioclase-quartzbarometer in amphibolite and granulite terranes yields geologicallyreasonable pressures that are in agreement with other well-calibratedbarometers in those terranes where comparisons can be made.     

Dolomite formation in the dynamic deep biosphere: results from the Peru Margin

Early diagenetic dolomite beds were sampled during the Ocean Drilling Programme (ODP) Leg 201 at four reoccupied ODP Leg 112 sites on the Peru continental margin (Sites 1227/684, 1228/680, 1229/681 and 1230/685) and analysed for petrography, mineralogy, δ¹³C, δ¹⁸O and ⁸⁷Sr/⁸⁶Sr values. The results are compared with the chemistry, and δ¹³C and ⁸⁷Sr/⁸⁶Sr values of the associated porewater. Petrographic relationships indicate that dolomite forms as a primary precipitate in porous diatom ooze and siliciclastic sediment and is not replacing the small amounts of precursor carbonate. Dolomite precipitation often pre‐dates the formation of framboidal pyrite. Most dolomite layers show ⁸⁷Sr/⁸⁶Sr‐ratios similar to the composition of Quaternary seawater and do not indicate a contribution from the hypersaline brine, which is present at a greater burial depth. Also, the δ¹³C values of the dolomite are not in equilibrium with the δ¹³C values of the dissolved inorganic carbon in the associated modern porewater. Both petrography and ⁸⁷Sr/⁸⁶Sr ratios suggest a shallow depth of dolomite formation in the uppermost sediment (<30 m below the seafloor). A significant depletion in the dissolved Mg and Ca in the porewater constrains the present site of dolomite precipitation, which co‐occurs with a sharp increase in alkalinity and microbial cell concentration at the sulphate–methane interface. It has been hypothesized that microbial ‘hot‐spots’, such as the sulphate–methane interface, may act as focused sites of dolomite precipitation. Varying δ¹³C values from −15‰ to +15‰ for the dolomite are consistent with precipitation at a dynamic sulphate–methane interface, where δ¹³C of the dissolved inorganic carbon would likewise be variable. A dynamic deep biosphere with upward and downward migration of the sulphate–methane interface can be simulated using a simple numerical diffusion model for sulphate concentration in a sedimentary sequence with variable input of organic matter. Thus, the study of dolomite layers in ancient organic carbon‐rich sedimentary sequences can provide a useful window into the palaeo‐dynamics of the deep biosphere.     

Depth and controls of Ca-rhodochrosite precipitation in bioturbated sediments of the Eastern Equatorial Pacific, ODP Leg 201, Site 1226 and DSDP Leg 68, Site 503

The occurrence of early diagenetic Ca‐rhodochrosite [(Mn,Ca)CO₃] is reported in association with ‘griotte’‐type nodular limestones from basinal settings in the geological record; however, without the comparison of analogous modern examples, the controls on precipitation remain speculative. Here the findings of four layers of primary Ca‐rich rhodochrosite recovered from a modern deep‐sea setting in the Eastern Equatorial Pacific, from bioturbated sediments 300 m below sea floor, are reported (Ocean Drilling Program, Leg 201, Site 1226). The mineralogy is similar to cements in burrows recovered during Deep Sea Drilling Project Leg 68 at Eastern Equatorial Pacific Site 503 and from Ca‐rhodochrosite laminae in sediments of the central Baltic Sea. Petrographic relationships and constant oxygen isotopic compositions in the Ca‐rhodochrosite around 5‰ at all depths indicate a shallow burial depth of formation. The onset of 1‰ heavier oxygen isotope composition of Ca‐rhodochrosite at Site 503, about 30 m below the Pliocene/Pleistocene boundary, further suggests that precipitation occurs in the range of 30 m below sea floor. The approximate depth of formation allowed an approximate empirical fractionation factor for marine Ca‐rhodochrosite to be constrained that strongly differs from previously published theoretical values. Based on the approximate precipitation depth, authigenic Ca‐rhodochrosite forms within the SO₄^2?‐reduction zone. Moderately negative δ¹³C values (around ?3‰) and total organic carbon lower than 2 wt% indicate a relatively low contribution of CO₃^2? from organic C mineralization within the expanded redox zonation in the Eastern Equatorial Pacific. It is suggested that the alkalinity is increased by a rise in pH at focused sites of Mn‐reduction coupled with S^2? oxidation. High concentrations of Mn‐oxide can accumulate in layers or burrows because of Mn‐cycling in suboxic sediments as suggested for the Baltic Sea Ca‐rhodochrosites. This study demonstrates how early diagenetic precipitates document biogeochemical processes from past diagenetic systems.