Mapping ambivalence: Exploring the geographies of community change and rails-to-trails development using photo-based Q method and PPGIS

As the literature on trail development suggests, recreational trail projects can generate conflicts and controversies, particularly when built on abandoned rail corridors through developed areas. These conflicts are often understood as “not in my back yard” (NIMBY) reactions, suggesting a spatial proximity to conflict which increases as one draws closer to the proposed trail. This research seeks to understand local residents’ perceptions and reactions to recreational trail development in the City of Delaware (Ohio, USA). It addresses two spatially infused questions: Does the potential for conflict related to trail development increase as people live closer to a potential trail (the NIMBY factor)? Can important qualitative factors about favorable and unfavorable land uses including potential recreational trail sites be defined using a participatory methodology and then represented in GIS? The study used a mixed-method approach to collect and analyze qualitative data from a group of local residents. Each participant was interviewed and asked to sort 19 pictures related to trail development. After each of the sorts, participants were asked to explain why they ranked the pictures the way they did. Results of the picture sorts were then analyzed using Q method and mapped with GIS. The results show that spatial proximity matters in the context of trail development and potential NIMBY reactions to trails. Significant differences were found in the picture sorts that reveal the importance of proximity and location, although in a manner contrary to the assumptions in the writings on rails-to-trails. Through combining qualitative methods, Q analysis and PPGIS analysis, the research shows that qualitative place-based studies are capable of generating insights about the complexities of situated geographic change such as recreational trail development.     

Cesstibtantite—a geologic introduction to the inverse pyrochlores

Summary The crystal structure of cesstibtantite has been solved from diffractometer data collected on samples from Leshaia, Russia and the Tanco pegmatite, Manitoba. Cesstibtantite from the Leshaia pegmatite (type locality) hasa 10.515(2) Å, space groupFd3m, composition Cs_0.31(Sb_0.57Na_0.31Pb_0.02Bi_0.01)_O.91(Ta_1.88Nb_0.12)₂(O_5.69[OH, F]_0.31)₆(OH, F)_0.69, Z 8; its structure was refined toR 3.8,wR 4.3% using 96 observed (F > 3[F]) reflections (MoK). Cesstibtantite from the Tanco pegmatite hasa 10.496(1) Å, space groupFd3m, composition (Cs_0.22K_0.01)_0.23(Na_0.45Sb_0.39Pb_0.14· Ca_0.06Bi_0.02)_1.06(Ta_1.95Nb_0.05)₂(O_5.78[OH,F]_0.22)₆(OH,F)_0.55,Z 8; its structure was refined toR 3.9w R 3.7% using 104 observed reflections. Cesstibtantite differs from the normal pyrochlores in that it contains significant amounts of very large cations such as Cs. As these cations are too large (^VIII[r] > 1.60 Å) for the conventional [8]-coordinated A site, they occupy the [18]-coordinated site, which normally contains monovalent anions. Natural cesstibtantite samples are non-ideal in that both Cs and monovalent anions occur at the site; thus cesstibtantite is intermediate to thenormal pyrochlores (with only monovalent anions at the site) and theinverse pyrochlores (with only large cations at the site).

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Cesstibtantit—eine geologische Einfiihrung in die inversen Pyrochlore

Zusammenfassung Die Kristallstruktur von Cesstibtantit wurde auf der Basis von Diffraktometerdaten von Proben von Leshaia, Russland and dem Tanco Pegmatit, Manitoba, gelöst. Cesstibtantit aus dem Leshaia Pegmatit (Typlokalität) hat a 10.515(2) Å, RaumgruppeFd3m, die Zusammensetzung CS_0.31(Sb_0.57Na_0.31Pb_0.02Bi_0.01)_0.91(Ta_1.88Nb_0.12)₂· (O_5.69OH, F_0.31)₆(OH, F)_0.69 Z 8; die Struktur wurde aufR 3.8,wR 4.3% verfeinert unter Benützung von 96 beobachteten Reflexen. Cesstibtantit vom Tanco Pegmatit hat a 10.496(1) Å, RaumgruppeFd3m, die Zusammensetzung (Cs_0.22K_0.01)_0.23(Na_0.45· Sb_0.39Pb_0.14Ca_0.06Bi_0.02)_1.06(Ta_1.95Nb_0.05)₂(O_5.78OH,F_0.22)₆(OH,F)_0.55,Z 8; seine Struktur wurde aufR 3.9wR 3.7% auf der Basis von 104 beobachteten Rettexen verfeinert. Cesstibtantit unterscheidet sich von normalen Pyrochloren insofern, als er signifikante Mengen von sehr großen Kationen, wie z.B. Cs enthält. Da these Kationen zu groß sind (^VIII r 1.60 Å) für eine konventionelle [8]-koordinierteA Stelle, nehmen she die [18]-koordinierten Positionen ein, welche normalerweise monovalente Anionen enthalten. Natürliche Cesstibtantitproben sind nicht ideal insofern als sowohl Cs als auch monovalente Anionen in der Position vorkommen. Somit ist Cesstibtantit intermediär zu den normalen Pyrochloren (mit nur monovalenten Anionen auf der Position) and den inversen Pyrochloren (mit ausschließlichen großen Kationen an der Position).

     

Cornetite: Modulated densely-packed Cu2+ oxysalt

Summary The crystal structure of cornetite, Cu₃(PO₄)(OH)₃, orthorhombic, a = 10.854(1), b = 14.053(3), c = 7.086(2), Å, V = 1080.8(3) ų, Z = 8, space group Pbca, has been refined to an R-index of 3.9% for 1231 observed reflections (I > 3I), measured with MoK X-radiation on an automated four-circle diffractometer. The structure consists of edge sharing zig-zag chains of distorted octahedra, cross-linked by edge-sharing octahedral dimers into complex octahedral layers. Adjacent layers are corner-linked together by neighbouring octahedra and PO₄ tetrahedra into a densely-packed heteropolyhedral framework, in which the phosphate tetrahedra share edges with the octahedral dimers. The polyhedral layers exhibit a commensurate modulation that results from the interaction between local relaxation of Jahn-Teller distorted octahedra and the long-range requirements of translational periodicity.

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Cornetit: Ein moduliertes, dicht gepacktes Oxosalz des zweiwertigen Kupfers

Zusammenfassung Die Kristallstruktur des Cornetits, Cu₃(PO4)(OH)3, orthorhombisch, a = 10,854(1), b = 14,053(3), c = 7,086(2,) Å, V = 1080,8(3) ų, Z = 8, Raumgruppe Pbca, wurde mit 1231 beobachteten Röntgenreflexen (I > 3I), die mit MoK-Strahlung auf einem automatischen Vierkreis-Diffraktometer gesammelt worden waren, auf einen R-Wert von 3,9% verfeinert. Die Struktur besteht aus kantenverknüpften Zickzack-Ketten verzerrter Oktaeder, die über kantenverknüfte Oktaeder-Dimere zu komplizierten Oktaederschichten verbunden sind. Benachbarte Schichten sind über Ecken durch benachbarte Oktaeder und PO₄-Tetraeder zu einem dichtgepackten, heteropolyedrischen Gerüst verknüpft, in welchem die Phosphattetraeder mit den Oktaeder-Dimeren Kanten gemeinsam haben. Die Polyederschichten zeigen eine kommensurable Modulierung, die aus der Wechselwirkung zwischen der lokalen Relaxation von Jahn-Teller-verzerrten Oktaedern und den Forderungen der translatorischen Periodizität über größere Entfernungen resultiert.

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With 5 Figures     

Authigenic aluminium phosphate-sulphates in sandstones of the Mitterberg Formation, Northern Calcareous Alps, Austria

Complex aluminium phosphate-sulphate minerals of the hinsdalite group have been identified as early diagenetic precipitates in Late Permian sandstones of the Northern Calcareous Alps, western Austria. According to their chemical composition they can be regarded as solid solutions between woodhouseite, svanbergite, crandallite and goyazite. The model proposed for their origin involves the dissolution of detrital apatite in a low-pH environment and subsequent precipitation of aluminium phosphate-sulphate minerals, which clearly pre-date syntaxial quartz cementation of the sediment. Their occurrence probably has been overlooked in other sandstones showing diagenetic apatite dissolution. The recognition of such minerals could provide a significant insight into early phosphate diagenesis.     

Formation of 18O-depleted dolomite within a marine evaporitic sequence, Triassic Reichenhall Formation, Austria

Dark grey, bituminous dolostones interbedded with marine-derived anhydrite horizons occur in the Triassic Reichenhall Formation of western Austria. Fossils are rare and indicate a hostile, hypersaline depositional environment. The dolomites are finely crystalline, fairly stoichiometric, well ordered and non-ferroan. Closely spaced samples (94 in total) of individual dolomite units have been analysed for their carbon and oxygen isotopic composition. The data indicate surprisingly low δ¹⁸O values (-5.7 to -2.1%₀ PDB), whereas the δ¹³C values are comparable to the contemporary Triassic seawater (+0.2 to +2.6%₀ PDB). Sedimentological evidence, including (i) lack of any evidence for extensive dissolution, (ii) distinct oxygen and carbon isotope ratios of individual dolomite units, (iii) covariance of carbon and oxygen isotopes within some dolomite layers and (iv) inclusions of celestite in dolomite, indicates a nearly closed system after early diagenesis. Combining this information with water-rock interaction calculations suggests that the lightest oxygen isotope compositions are the result of freshwater influx into the basin during very early dolomite formation. A secondary factor may be dolomite recrystallization at elevated temperatures during burial.     

Fine structure in the infrared OH-stretching bands of holmquistite and anthophyllite

The principal infrared OH-stretching bands in the orthorhombic (Mg, Fe, Mn, Li) amphiboles holmquistite and anthophyllite show fine structure due to the occurrence of two symmetrically distinct OH groups in the crystal structure. There are two distinct tetrahedral double chains in the orthorhombic amphibole structure, the A chain and the B chain. The B chain is more rotated than the A chain, and the stereochemistry around each of the OH sites suggests that the hydrogen bond to the bridging anion(s) of the B chain is stronger than the hydrogen bond to the bridging anion(s) of the A chain. This difference is sufficient to shift the frequency of the principal OH2-stretching band(s) ~5 cm ^-1 to lower frequency, and allows resolution of the two bands in the infrared spectrum. This distinction could allow detection of possible OH, F ordering between the two distinct monovalent-anion sites in the orthorhombic amphibole structure.     

Thermal and shock history of Almahata Sitta meteorite inferred from structure refinement of pyroxene and Mössbauer spectroscopy of Fe-Ni metal

The crystal structures of orthopyroxene (En_86.3Fs_8.6Wo_5.1, space group Pbca) and pigeonite (En_81.7Fs_8.8Wo_9.5, space group P2₁/c) from the Almahata Sitta ureilite (fragment#051) have been refined to R1 indices of 3.10% and 2.53%, respectively, using single-crystal X-ray diffraction data. The unit formulas were calculated from electron microprobe analysis, and the occupancies at the M1 and M2 sites were refined for both pyroxenes from the single-crystal diffraction data. The results indicate a rather disordered intracrystalline Fe²⁺-Mg cation distribution over the M1 and M2 sites, with a closure temperature of 726(±55)°C for orthopyroxene and 704(±110)°C for pigeonite, suggesting fast cooling of these pyroxenes. The Mössbauer spectrum of the Fe-Ni metal particles of Almahata Sitta ureilite (fragment#051) is dominated by two overlapping magnetic sextets that are assigned to Fe atoms in Si-bearing kamacite, and arise from two different nearest-neighbor configurations of Fe* (=Fe+Ni) and Si atoms in the bcc structure of kamacite; (8F*, 0Si) and (7Fe*, 1Si). In addition, the spectrum shows weak absorption peaks that are attributed to the presence of small amounts of cohenite [(Fe,Ni)₃C], schreibersite [(Fe,Ni)₃P], and an Fe-oxide/hydroxide phase. The fast cooling of pyroxene to the closure temperature (after equilibration at ~1200°C) and the incorporation of Si in kamacite can be interpreted as due to a shock event that took place on the meteorite parent body, consistent with the proposed formation history of ureilites parent body where a fast cooling has occurred at a later stage of its formation.     

Identification and Assessment of Confined and Perched LNAPL Conditions

Although confined and perched light nonaqueous phase liquids (LNAPLs) have previously been recognized, the majority of technical LNAPL literature focuses on unconfined LNAPL. Little information exists regarding the appropriate use of LNAPL distribution and transmissivity data to distinguish between confined, perched, and unconfined LNAPL hydrogeological scenarios. This paper describes three case histories that illustrate how the observed behavior of LNAPL can be used to identify the hydrogeologic condition of LNAPL at a given site and improved methods for calculating LNAPL drawdown based on these hydrogeologic conditions. The assessment methodology uses routinely available data such as fluid gauging, boring lo, laser‐induced fluorescence, visual observations of soil cores, and LNAPL baildown testing. Identification of the correct LNAPL hydrogeologic condition results in more accurate LNAPL conceptual site models, improved estimates of LNAPL recovery rates and volumes, more appropriate technology applications, and improved accuracy of LNAPL remediation metrics such as LNAPL transmissivity.     

Doing community geography

Community Geography offers researchers, community groups, and students opportunities to engage in action oriented applied geographical research. Creating and sustaining these research programs can be challenging, programs can involve many partners from both academic and the community, have different goals and purposes, and utilize a variety of methods to perform research. In this paper we offer a framework of three primary overarching principles for implementing CG projects; (1) Who, (2) Why, and (3) How. (1) “Who” describes who is involved in CG, including researchers, community partners, academic institutions, (2) “Why” describes the justifications and benefits of taking this approach. (3) “How” explains how CG borrows methodologies from many disciplines within geography and beyond. Our examples are not exhaustive; rather, they serve as starting points to inspire researchers interested in CG.

     

Practicing community geography in times of crisis

Community geography emphasizes the centrality of community engagement to socially transformative research. This introduction to a special issue of GeoJournal on community geography outlines how this growing subfield provides a model for collaborative action with the crises of our time, from white supremacy through climate change. As the co-editors of this special issue, we summarize the contents of these 14 articles, grouping them by the shared themes of power, institutional partnerships, pedagogy, and methods.