Fluid-rock interaction between syenites and marbles at Stephen Cross Quarry,Québec,Canada: petrological and stable isotope data

Grenville dolomitic marbles and calc-silicates at Stephen Cross Quarry, Québec, underwent contact metamorphism and metasomatism associated with the intrusion of the Wakefield syenite at ambient pressures of 0.4GPa at 1090–1070Ma. Fluid infiltration produced exoskarns, calcite+periclase+forsterite±diopside±orthoclase assemblages in the marbles, and quartz±calcite±wollastonite±diopside±anorthite assemblages in the calc-silicates. Phase-equilibria in the CaO–MgO–Al₂O₃–SiO₂–H₂O–CO₂ system suggest that fluid infiltration occurred close to the thermal peak of contact metamorphism (715–815°C) and that the fluids hadXCO₂0.15. In the metasediments, ¹⁸O values of calcite (Cc) are as low as 8.6, suggesting that the fluids were in isotopic equilibrium with the syenites (¹⁸O =8.8–10.2). Marble ¹³C(Cc) values are-0.1 to-3.2; the lack of correlation between ¹³C(Cc) and ¹⁸O(Cc) is consistent with the infiltration of water-rich fluids. The resetting of stable isotopes and the mineralogical changes can be explained by time-integrated fluid fluxes of up to 110 m³/m² (4×10⁶ mol/m²), corresponding to actual fluxes of 3×10^-11 to 3×10^-12 m³/m²-s and intrinsic permeabilities of 10^-18 to 10^-20 m² for fluid flow lasting 0.1-1Ma. Marble ¹⁸O(Cc) values do not correlate well with distance from the syenite, and fluids were probably channelled across lithological layering. The correlation between the degree of resetting of marble ¹⁸O(Cc) values with the abundance of submillimetre-wide veins, suggests that fluid focussing may have resulted from variations in fracture density. Late, lower temperature (<500°C), fluid flow formed serpentine (Serp) and brucite (Br) from periclase and forsterite. ¹⁸O(Br) and ¹⁸O(Scrp) values correlate with ¹⁸O(Cc), suggesting that retrogression involved only limited volumes of fluid. The observation that ¹⁸O(Cc-Br) and ¹⁸O(Cc-Serp) values are higher in marbles that have lower ¹⁸O(Cc) values is interpreted as indicating that fluid flow persisted to lower temperatures in those rocks due to higher intrinsic permeabilities. Calcite in the syenite was also formed by the influx of fluids during cooling. Syenite ¹⁸O(Cc) values are approximately in isotopic equilibrium with the high-temperature silicate minerals, suggesting that again only minor volumes of fluid were involved. In detail fluid flow was prolonged and complex, creating problems for the application of quantitative fluid flow models.This paper is a contribution to IGCP 304, Lower Crustal Processes     

The evolution of groundwater in the Tyrrell catchment, south-central Murray Basin, Victoria, Australia

The Tyrell catchment lies on the western margin of the Riverine Province in the south-central Murray Basin, one of Australia’s most important groundwater resources. Groundwater from the shallow, unconfined Pliocene Sands aquifer and the underlying Renmark Group aquifer is saline (total dissolved solids up to 150,000 mg/L) and is Na-Cl-Mg type. There is no systematic change in salinity along hydraulic gradients implying that the aquifers are hydraulically connected and mixing during vertical flow is important. Stable isotopes (¹⁸O+²H) and Cl/Br ratios indicate that groundwater is entirely of meteoric origin and salts in this system have largely been derived by evapotranspiration of rainfall with only minor halite dissolution, rock weathering (mainly feldspar dissolution), and ion exchange between Na and Mg on clays. Similarity in chemistry of all groundwater in the catchment implies relative consistency in processes over time, independent of any climatic variation. Groundwater in both the Pliocene Sands and Renmark Group aquifers yield ages of up to 25 ka. The Tyrrell Catchment is arid to semi-arid and has low topography. This has resulted in relatively low recharge rates and hydraulic gradients that have resulted in long groundwater residence times.     

Life After Death

Predictions of the death of impoverished and actively marginalized racial and ethnic communities are premature. Many core African American societies have been devastated by the state, capital, and cultural policies of the last two decades. Simultaneously, geography and the other social sciences have been mobilized in order to prevent a fuller understanding of these communities and of the need for social equity. The further development of several approaches is required to open geography and the other disciplines up for community‐building, rather than community destruction. The incorporation of research in the following areas holds out the promise of revitalizing both: human rights; the ethnic movements underlying restructuring; the social construction of regions; the reproduction of social power; building ethnic alliance; and indigenous knowledge systems.     

On the role of flux adjustments in an idealized coupled climate model

 The effect of employing flux adjustments on the climatic response of an idealized coupled model to an imposed radiative forcing is investigated with two coupled models, one of which employs flux adjustments. A linear reduction (to the planetary longwave flux) of 4 W/m² is applied over a 70 y period and held constant thereafter. Similar model responses are found (during the initial 70 y period) for global-scale diagnostics of hemispheric air temperature due to the nearly linear surface-air temperature response to the radiative forcing. Significant regional scale differences do exist, however. As the perturbation away from the present climate grows, basin-scale diagnostics (such as meridional overturning rates) begin to diverge between flux adjusted and non-flux adjusted models. Once the imposed radiative forcing is held constant, differences in global mean air temperature of up to 0.5 °C are found, with large regional-scale differences in air temperature and overturning rates within the North Atlantic and Southern Ocean. Two additional experiments with the flux adjusted model (beginning from points further along the control integration) suggest that the elimination of much of the coupling shock before the radiative forcing is applied leads to results slightly closer to the non-flux adjusted case, although large differences still persist. In particular a dipole structure indicating an enhanced warming within the Pacific sector of the Southern Ocean, and cooling within the Atlantic sector is not reproduced by the flux adjusted models. This disparity is intimately linked to the Southern Ocean overturning cell along with the flux adjustments employed as well as the drift arising from coupling shock. If a similar form of sensitivity exists in more realistic coupled models, our results suggest: (1) perturbation experiments should not be undertaken until after the coupled model control experiment is carried out for several hundred years (thereby minimizing the coupling shock); (2) care should be exercised in the interpretation of regional-scale results (over the ocean) in coupled models which employ flux adjustments; (3) care should also be taken in interpreting even global-scale diagnostics in flux adjusted models for large perturbations about the present climate. Received: 15 November 1996 / Accepted: 4 June 1997     

The effect of sea-ice extent in the North Atlantic on the stability of the thermohaline circulation in global warming experiments

Different climate models simulate different behavior of the Atlantic meridional overturning circulation (MOC) under the same global warming scenario. We propose a plausible explanation for this and argue that a proper simulation of the present-day climate in the subpolar North Atlantic is important. This is illustrated using results from idealized global warming experiments, in which both the radiative forcing scenario and the model employed are the same, with the only major difference being the initial subpolar North Atlantic climate. The initial conditions are made progressively colder, with more extensive sea-ice cover in the northern North Atlantic.The key result is that starting from conditions which are too cold in the North Atlantic and with sea-ice that is too extensive leads to an MOC that is more stable to the radiative forcing. Furthermore, under considerably underestimated sea surface temperatures in subpolar regions, the MOC can even intensify. A reduction of freshwater flux associated with the reduction of sea-ice melt is shown to be important for such unusual behavior of the MOC. Other mechanisms are also considered, but not deemed as important in explaining published inter-model differences.     

Phases greater than 90° in MT data: Analysis using dimensionality tools

An example of magnetotelluric data is discussed which has distinctive phase values out of quadrant, and for which the Z_xx element of the measured tensor is greater than the Z_xy element in both real and quadrature parts. Mohr circle plots and principal value decompositions of the real and quadrature parts of the tensor clarify its understanding. An analysis of rotational invariants of the data suggests a case of galvanic distortion of a 2D structure. Results from phase tensor analysis are included, and the example is seen to be a dramatic instance of phase tensor analysis reducing an apparently 3D example to 2D characteristics.The Mohr circles of this example do not capture the axes origin, although there are phases out of quadrant. Extra intrigue is thus added to the question, noted in Lilley, F.E.M., 1998. Magnetotelluric tensor decomposition: part I, theory for a basic procedure. Geophysics 63, 1885–1897 and arising independently in Caldwell, T.G., Bibby, H. M., Brown, C., 2004. The magnetotelluric phase tensor. Geophys. J. Int. 158, 457–469 and Bibby, H.M., Caldwell, T.G., Brown, C., 2005. Determinable and non-determinable parameters of galvanic distortion in magnetotellurics. Geophys. J. Int. 163, 915–930, whether the determinant values taken separately of the real and quadrature parts of a magnetotelluric tensor should both never be negative.For data whose Mohr circles do not capture the axes origin, simple conditions are derived regarding phase. These conditions govern whether or not it is formally possible for observed phases of Z_xy to exceed 90°, for any rotation of the observing axes.     

Searching for Added Value in Simulating Climate Extremes with a High-Resolution Regional Climate Model over Western Canada

We evaluate the capacity of a regional climate model to represent observed extreme temperature and precipitation events and also examine the impact of increased resolution, in an effort to identify added value in this respect. Two climate simulations of western Canada (WCan) were conducted with the Canadian Regional Climate Model (version 4) at 15 (CRCM15) and 45?km (CRCM45) horizontal resolution driven at the lateral boundaries by data from the European Centre for Medium-range Weather Forecasts (ECMWF) 40-year Reanalysis (ERA-40) for the period 1973–1995. The simulations were evaluated using the spline-interpolated dataset ANUSPLIN, a daily observational gridded surface temperature and precipitation product with a nominal resolution of approximately 10?km. We examine a range of climate extremes, comprising the 10th and 90th percentiles of daily maximum (TX) and minimum (TN) temperatures, the 90th percentile of daily precipitation (PR90), and the 27 core Climate Daily Extremes (CLIMDEX) indices.

Both simulations exhibit cold biases compared with observations over WCan, with the bias exacerbated at higher resolution, suggesting little added value for temperature overall. There are instances, however, of regional improvement in the spatial pattern of temperature extremes at the higher resolution of CRCM15 (e.g., the CLIMDEX index for the annual number of days when TX?>?25°C). The high-resolution simulations also reveal similarly localized features in precipitation (e.g., rain shadows) that are not resolved at the 45?km resolution. With regard to precipitation extremes, although both simulations generally display wet biases, CRCM15 features a reduced bias in PR90 in all seasons except winter. This improvement occurs despite the fact that spatial and interannual variability of PR90 in CRCM15 is significantly overestimated relative to both CRCM45 and ANUSPLIN. We posit that these characteristics are the result of demonstrable differences between corresponding topographical datasets used in the gridded observations and CRCM, the resulting errors propagated to physical variables tied to elevation and the beneficial effect of subsequent spatial averaging. Because topographical input is often discordant between simulations and gridded observations, it is argued that a limited form of spatial averaging may contribute added value beyond that which has already been noted in previous studies with respect to small-scale climate variability.     

<Emphasis Type="Italic">Deepwater Horizon</Emphasis> Oil Spill Impacts on Salt Marsh Fiddler Crabs (<Emphasis Type="Italic">Uca</Emphasis> spp.)

The Deepwater Horizon oil spill was the largest marine oil spill in US waters to date and one of the largest worldwide. Impacts of this spill on salt marsh vegetation have been well documented, although impacts on marsh macroinvertebrates have received less attention. To examine impacts of the oil spill on an important marsh invertebrate and ecosystem engineer, we conducted a meta-analysis on fiddler crabs (Uca spp.) using published sources and newly available Natural Resources Damage Assessment (NRDA) and Gulf of Mexico Research Initiative (GoMRI) data. Fiddler crabs influence marsh ecosystem structure and function through their burrowing and feeding activities and are key prey for a number of marsh and estuarine predators. We tested the hypothesis that the spill affected fiddler crab burrow density (crab abundance), burrow diameter (crab size), and crab species composition. Averaged across multiple studies, sites, and years, our synthesis revealed a negative effect of oiling on all three metrics. Burrow densities were reduced by 39 % in oiled sites, with impacts and incomplete recovery observed over 2010–2014. Burrow diameters were reduced from 2010 to 2011, but appeared to have recovered by 2012. Fiddler crab species composition was altered through at least 2013 and only returned to reference conditions where marsh vegetation recovered, via restoration planting in one case. Given the spatial and temporal extent of data analyzed, this synthesis provides compelling evidence that the Deepwater Horizon spill suppressed populations of fiddler crabs in oiled marshes, likely affecting other ecosystem attributes, including marsh productivity, marsh soil characteristics, and associated predators.