Variation of infiltration rate through karstic surfaces due to land use changes: A case study in Murgia (SE-Italy)

Groundwaters of the Murgia carbonate aquifer represent the main groundwater resource of the Apulia region (SE Italy). In the highlands (Alta Murgia) karst crops out in different forms and textures which have been preserved up to the 1970s: little evolved agriculture and sheep rearing produced only a marginal modification of the epikarst while a high degree of division into parcels by drystone walls helped in preserving soils from erosion. In the last years the original scenery of the Alta Murgia changed due to widespread transformations of surface karstic textures for agricultural purposes, with undeniable negative consequences on the hydrogeological balance, concerning both the infiltration and the runoff terms. Stone shattering led to flattening and deep alteration of a large part of the original karstic landscape and to demolition of drystone walls.In a study area of about 139 km² located in the Alta Murgia, the comparison of aerial photos related to the period 1950–2001 indicated that stone shattering had occurred for about 42% of the area.The hydrological behaviour of the first soil layer of experimental parcels representing both shattered stone and natural karstic surface textures was analysed by using the numerical model Hydrus-2D with the aim of estimating the variation on infiltration rate due to stone shattering. Intensive field and laboratory measurements concerned soil texture, soil water content, pressure head, saturated hydraulic conductivity, pan evaporation and meteorological parameters.     

Assessing degradation capability of aerobic indigenous microflora in PAH-contaminated brackish sediments

A study was conducted to determine polycyclic aromatic hydrocarbons (PAHs) distribution and microbial population changes in brackish sediments from an Italian lagoon included in the Ramsar List of Wetlands of International Importance. The presence and level of PAH-degrading bacteria were estimated by the most probable number (MPN) enumeration technique, whereas degradation capability towards target compounds was checked against loss of spiked PAHs (Phenanthrene, Anthracene and Fluoranthene) in MPN tubes after incubation in optimal conditions. Chemical analyses and microbiological counts suggested a potential for PAHs biodegradation by natural occurring populations of sediment microorganisms, thus indicating an "optimal range" in sediment PAHs concentrations, outside of which the natural selection of the indigenous microflora did not occur. The MPN procedure here described, provided an effective and reliable way to simultaneously determine microbial population densities and subsequent confirmation of the biodegradation capability of sediment indigenous microflora when exposed to laboratory and environmental concentrations of PAHs.     

Heavy metals in marine sediments of Taranto Gulf (Ionian Sea, Southern Italy)

Al, Cr, Cu, Fe, Hg, Mn, Ni, Pb, Ti and Zn concentrations have been determined in surface sediment samples collected in the Taranto Gulf (Ionian Sea, Southern Italy) in order to evaluate their levels and spatial distribution in this important area of the Mediterranean Sea. For various metals, the geoaccumulation index has been calculated as a criterion to assess if their concentrations represent contamination levels or can be considered as background levels. The results show that metals concentrations in sediments can be considered near the background levels found in the Mediterranean Sea.Analytical results have been elaborated by using a Geographical Information System (GIS) software to show metals accumulation areas. Using multivariate statistical analysis, we evaluate the possibility to distinguish the sampling stations, in relation to their geographical position. Results have showed metals distribution in the Taranto Gulf is principally influenced by industrial and urban wastes, located mostly in the northern coastal area of the Ionian Sea. Rivers in the Basilicata region and prevailing anticlockwise marine currents are further factors influencing metal accumulation in sediments.     

Biomarkers of Exposure and Effects for Assessing Toxicological Risk of Endocrine Disrupters in Top Predators of the Mediterranean Sea

Abstract. Endocrine Disrupting Chemicals (EDCs) have the potential to alter hormone pathways that regulate reproductive processes in wildlife and fisheries. In this research the unexplored hypothesis that Mediterranean top predator species (such as large pelagic fish and marine mammals) are potentially at risk due to EDCs is investigated. In the Mediterranean environment, top predators accumulate high concentrations of polyhalogenated aromatic hydrocarbons (PHAHs) and toxic metals, incurring high toxicological risk. Here we illustrate the need to develop sensitive biomarkers for evaluation of toxicological risk in top marine predators (Xiphias gladius, Thunnus thynnus thynnus) and non-lethal techniques, such as non-destructive biomarkers, for the hazard assessment of threatened species exposed to EDCs, such as marine mammals ( Stenella coeruleoalba, Tursiops truncatus, Delphinus delphis and Balaenoptera physalus ).     

Preboreal climatic oscillations recorded by pollen and foraminifera in the southern Adriatic Sea

Core SA03-1 from the southern Adriatic Sea (EC-Eurostrataform project) provides new information about climate changes and palaeocirculation in the Adriatic region during the last deglaciation. The results of an integrated study based on pollen and foraminifera records of the part of the core spanning the late Pleistocene–early Holocene transition (including the late Younger Dryas, the Preboreal and the beginning of the Boreal) are presented. The major vegetation changes and the short-term oscillations occurred during the early Holocene warming in the southern Adriatic basin on the basis of a high-resolution pollen record are documented. Vegetation changes are correlated to short-term oscillations detected in the foraminifera record during the same interval. The two independent terrestrial and marine proxies indicate at least three short-term cold and dry oscillations occurring at 11.2–11, 10.8–10.4 and 10 cal ka BP, according to the age–depth model adopted in this study. Finally, adopting an event-stratigraphy approach, the comparison of these results with two western Mediterranean records of Preboreal short-term oscillations suggest the occurrence of synchronous bio-events in the Mediterranean basin.     

Kinetic study of the dehydroxylation of chrysotile asbestos with temperature by in situ XRPD

 The kinetics of the dehydroxylation of chrysotile was followed in situ at high temperature using real-time conventional and synchrotron powder diffraction (XRPD). This is the first time kinetics parameters have been calculated for the dehydroxylation of chrysotile. The value of the order of the reaction mechanism calculated using the Avrami model indicates that the rate-limiting step of the reaction is a one-dimensional diffusion with an instantaneous nucleation or a deceleratory rate of nucleation of the reaction product. Hence, the rate-limiting step is the one-dimensional diffusion of the water molecules formed in the interlayer region by direct condensation of two hydrogen atoms and an oxygen atom. The calculated apparent activation energy of the reaction in the temperature range 620–750 °C is 184 kJ mol⁻¹. The diffusion path is along the axis of the fibrils forming the fibers. The amorphous or short-range ordered dehydroxylate of chrysotile is extremely unstable because forsterite readily nucleates in the Mg-rich regions. Moreover, it is less stable than the dehydroxylate of kaolinite, the so-called metakaolinite, which forms mullite at about 950 °C. This difference is interpreted in terms of the different nature of the two ions Mg²⁺ and Al³⁺ and their function as glass modifier and glass-forming ion, respectively. Received: 10 April 2002 / Accepted: 7 January 2003 Acknowledgements This work is part of a COFIN project (04 Scienze della Terra, NR 17, 2000) supported by MURST. Dr Dapiaggi is kindly acknowledged for help during the data collection at the Dipartimento di Scienze della Terra, University of Milan.     

Litho-asthenospheric structures of northern Italy as inferred from teleseismic P-wave tomography

Regional three-dimensional inversions of teleseismic P-wave travel time residuals recorded by high-frequency regional and local seismic networks operating along the Western Alps and surrounding regions were carried out and lithosphere and upper mantle P-wave velocity models down to 300 km were obtained.

Residuals of more than 500 teleseismic events, recorded by 98 fixed and temporary seismic stations, have been inverted.

The comparison between real residuals and the ones obtained from tomographic model indicates that the method is able to solve the feature of the regional heterogeneities.

Where the resolution is good, coherent lithospheric and upper mantle structures are imaged. In the shallower layers, high- and low-velocity anomalies follow the structural behaviour of the Alpine-Apenninic chains showing the existence of very strong velocity contrasts. In the deepest layers, velocity contrast decreases however two deep-seated high-velocity structures are observed. The most extended in depth and approximately trending NE-SW has been interpreted as a wreck of the oldest subduction responsible of the Alpine orogenesis. The second one, connected to the northwestern sector of the Apenninic chain, appears to vanish at depths greater than 180 km and is probably due to still active Apenninic roots.

Cross-sections depict the spatial trend of perturbations and in particular outline the sub-vertical character of the Alpine and Apenninic anomalies. Under the Ligurian Sea, the 3-D inversion confirms the uplift of the asthenosphere in agreement with the tectonic evolution of the basin.     

Multi-criteria Evaluation of Bran Use to Promote Circularity in the Cereal Production Chain

Natural Resources Research - A reliable and realistic subsurface resource spatial modeling is a common and critical task for geosciences projects (mining, petroleum and environmental) because the...     

Reply to Comment on “Impact of groundwater withdrawals on the interaction of multi-layered aquifers in the Viterbo geothermal area (central Italy)”: report published in Hydrogeology Journal (2013) 21:1339–1353, by Antonella Baiocchi,Francesca Lotti and Vincenzo Piscopo

Hydrogeology Journal -