Using Mesoproterozoic sedimentary geochemistry to reconstruct basin tectonic geography and link organic carbon productivity to nutrient flux from a Northern Australian large igneous Province

The Beetaloo Sub-basin, northern Australia, is considered the main depocentre of the 1,000-km scale Mesoproterozoic Wilton package of the greater McArthur Basin – the host to one of the oldest hydrocarbon global resources. The ca. 1.40–1.31 Ga upper Roper Group and the latest Mesoproterozoic to early Neoproterozoic unnamed group of the Beetaloo Sub-basin, together, record ca. 500 million years of depositional history within the North Australia Craton. Whole-rock shale Sm–Nd and Pb isotope data from these sediments reveal sedimentary provenance and their evolution from ca. 1.35 to 0.85 Ga. Furthermore, these data, together with shale major/trace elements data from this study and pyrolysis data from previous publications, are used to develop a dynamic tectonic geography model that links the organic carbon production and burial to an enhanced weathering of nutrients from a large igneous province. The ca. 1.35–1.31 Ga Kyalla Formation of the upper Roper Group is composed of isotopically evolved sedimentary detritus that passes up, into more isotopically juvenile Pb values towards the top of the formation. The increase in juvenile compositions coincides with elevated total organic carbon (TOC) contents of these sediments. The coherently enriched juvenile compositions and TOC the upper portions of the Kyalla Formation are interpreted to reflect an increase in nutrient supply associated with the weathering of basaltic sources (e.g. phosphorous). Possible, relatively juvenile, basaltic sources include the Wankanki Supersuite in the western Musgraves and the Derim Derim–Galiwinku large igneous province (LIP). The transition into juvenile, basaltic sources directly before a supersequence-bounding unconformity is here interpreted to reflect uplift and erosion of the Derim Derim–Galiwinku LIP, rather than an influx of southern Musgrave sources. A new baddeleyite crystallisation age of 1,312.9 ± 0.7 Ma provides both a tight constraint on the age of this LIP, along with its associated magmatic uplift, as well as providing a minimum age constraint for Roper Group deposition. The unconformably overlying lower and upper Jamison sandstones are at least 300 million years younger than the Kyalla Formation and were sourced from the Musgrave Province. An up-section increase in isotopically juvenile compositions seen in these rocks is interpreted to document the progressive exhumation of the western Musgrave Province. The overlying Hayfield mudstone received detritus from both the Musgrave and Arunta regions, and its isotopic geochemistry reveals affinities with other early Neoproterozoic basins (e.g. Amadeus, Victoria and Officer basins), indicating the potential for inter-basin correlations.     

Geochemistry of Flooded Underground Mine Workings Influenced by Bacterial Sulfate Reduction

Unlike the majority of the water in the flooded mine complex of Butte Montana, which includes the highly acidic Berkeley pit lake, groundwater in the flooded West Camp underground mine workings has a circum-neutral pH and contains at least 8 μM aqueous sulfide. This article examines the geochemistry and stable isotope composition of this unusual H₂S-rich mine water, and also discusses problems related to the colorimetric analysis of sulfide in waters that contain FeS_(aq) cluster compounds. The West Camp mine pool is maintained at a constant elevation by continuous pumping, with discharge water that contains elevated Mn (90 μM), Fe (16 μM), and As (1.3 μM) but otherwise low metal concentrations. Dissolved inorganic carbon in the mine water is in chemical and isotopic equilibrium with rhodochrosite in the mineralized veins. The mine water is under-saturated with mackinawite and amorphous FeS, but is supersaturated with Cu- and Zn-sulfides. However, voltammetry studies show that much of the dissolved sulfide and ferrous iron are present as FeS_(aq) cluster molecules: as a result, the free concentration of the West Camp water is poorly constrained. Concentrations of dissolved sulfide determined by colorimetry were lower than gravimetric assays obtained by AgNO₃ addition, implying that the FeS_(aq) clusters are not completely extracted by the Methylene Blue reagent. In contrast, the clusters are quantitatively extracted as Ag₂S after addition of AgNO₃. Isotopic analysis of co-existing aqueous sulfide and sulfate confirms that the sulfide was produced by sulfate-reducing bacteria (SRB). The H₂S-rich mine water is not confined to the immediate vicinity of the extraction well, but is also present in flooded mine shafts up to 3 km away, and in samples bailed from mine shafts at depths up to 300 m below static water level. This illustrates that SRB are well established throughout the southwestern portion of the extensive (>15 km³) Butte flooded mine complex.     

Data Analysis and Modeling to Optimize Thermal Treatment Cost and Performance

The objective of in situ thermal treatment is typically to reduce the contaminant mass or average soil concentration below a specified value. Evaluation of whether the objective has been met is usually made by averaging soil concentrations from a limited number of soil samples. Results from several field sites indicate large performance uncertainty using this approach, even when the number of samples is large. We propose a method to estimate average soil concentration by fitting a log normal probability model to thermal mass recovery data. A statistical approach is presented for making termination decisions from mass recovery data, soil sample data, or both for an entire treatment volume or for subregions that explicitly considers estimation uncertainty which is coupled to a stochastic optimization algorithm to identify monitoring strategies to meet objectives with minimum expected cost. Early termination of heating in regions that reach cleanup targets sooner enables operating costs to be reduced while ensuring a high likelihood of meeting remediation objectives. Results for an example problem demonstrate that significant performance improvement and cost reductions can be achieved using this approach.     

Thermodynamically constrained averaging theory approach for modeling flow and transport phenomena in porous medium systems: 6. Two-fluid-phase flow

This work is the sixth in a series of papers on the thermodynamically constrained averaging theory (TCAT) approach for modeling flow and transport phenomena in multiscale porous medium systems. Building upon the general TCAT framework and the mathematical foundation presented in previous works, the limiting case of connected two-fluid-phase flow is considered. A constrained entropy inequality is developed based upon a set of primary restrictions. Formal approximations are introduced to deduce a general simplified entropy inequality (SEI). The SEI is used along with secondary restrictions and closure approximations consistent with the SEI to produce a general functional form of a two-phase-flow model. The general model is in turn simplified to yield a hierarchy of models by neglecting common curves and by neglecting both common curves and interfaces. The simplest case considered corresponds to a traditional two-phase-flow model. The more sophisticated models including interfaces and common curves are more physically realistic than traditional models. All models in the hierarchy are posed in terms of precisely defined variables that allow for a rigorous connection with the microscale. The explicit nature of the restrictions and approximations used in developing this hierarchy of models provides a clear means to both understand the limitations of traditional models and to build upon this work to produce more realistic models.     

Climate-induced boreal forest change: Predictions versus current observations

For about three decades, there have been many predictions of the potential ecological response in boreal regions to the currently warmer conditions. In essence, a widespread, naturally occurring experiment has been conducted over time. In this paper, we describe previously modeled predictions of ecological change in boreal Alaska, Canada and Russia, and then we investigate potential evidence of current climate-induced change. For instance, ecological models have suggested that warming will induce the northern and upslope migration of the treeline and an alteration in the current mosaic structure of boreal forests. We present evidence of the migration of keystone ecosystems in the upland and lowland treeline of mountainous regions across southern Siberia. Ecological models have also predicted a moisture-stress-related dieback in white spruce trees in Alaska, and current investigations show that as temperatures increase, white spruce tree growth is declining. Additionally, it was suggested that increases in infestation and wildfire disturbance would be catalysts that precipitate the alteration of the current mosaic forest composition. In Siberia, 7 of the last 9 yr have resulted in extreme fire seasons, and extreme fire years have also been more frequent in both Alaska and Canada. In addition, Alaska has experienced extreme and geographically expansive multi-year outbreaks of the spruce beetle, which had been previously limited by the cold, moist environment. We suggest that there is substantial evidence throughout the circumboreal region to conclude that the biosphere within the boreal terrestrial environment has already responded to the transient effects of climate change. Additionally, temperature increases and warming-induced change are progressing faster than had been predicted in some regions, suggesting a potential non-linear rapid response to changes in climate, as opposed to the predicted slow linear response to climate change.     

Doing community geography

Community Geography offers researchers, community groups, and students opportunities to engage in action oriented applied geographical research. Creating and sustaining these research programs can be challenging, programs can involve many partners from both academic and the community, have different goals and purposes, and utilize a variety of methods to perform research. In this paper we offer a framework of three primary overarching principles for implementing CG projects; (1) Who, (2) Why, and (3) How. (1) “Who” describes who is involved in CG, including researchers, community partners, academic institutions, (2) “Why” describes the justifications and benefits of taking this approach. (3) “How” explains how CG borrows methodologies from many disciplines within geography and beyond. Our examples are not exhaustive; rather, they serve as starting points to inspire researchers interested in CG.

     

Constraining Holocene lake levels and coastal dune activity in the Lake Michigan basin

Sediment cores collected from embayed lakes along the east-central coast of Lake Michigan are used to construct aeolian sand records of past coastal dune mobility, and to constrain former lake levels in the Lake Michigan basin. Time series analysis of sand cycles based on the weight-percent aeolian sand within lacustrine sediment, reveals statistically significant spectral peaks that coincide with established lake level cycles in Lake Michigan and the Gleissberg sunspot cycle of minima. Longer cycles of ~ 800 and ~ 2200 years were also identified that correspond to solar cycles. Shorter cycles between 80 and 220 years suggest a link between coastal dune mobility, climate, and lake levels in the Lake Michigan basin. Radiocarbon-dated sedimentary contacts of lacustrine sediment overlying wetland sediment record the Nipissing transgression in the Lake Michigan basin. Lake level rise closely mimics the predicted uplift of the North Bay outlet, with lake level rise slowing when outflow was transferred to the Port Huron/Sarnia outlet. The Nipissing highstand was reached after 5000 cal (4.4 ka) BP.