Rare Earth, Major and Trace Elements in the Kunimiyama Ferromanganese Deposit in the Northern Chichibu Belt, Central Shikoku, Japan

Abstract. Rare earth, major and trace element geochemistry is reported for the Kunimiyama stratiform ferromanganese deposit in the Northern Chichibu Belt, central Shikoku, Japan. The deposit immediately overlies greenstones of mid-ocean ridge basalt (MORB) origin and underlies red chert. The ferromanganese ores exhibit remarkable enrichments in Fe, Mn, P, V, Co, Ni, Zn, Y and rare earth elements (excepting Ce) relative to continental crustal abundance. These enriched elements/ Fe ratios and Post-Archean Average Australian Shale-normalized REE patterns of the ferromanganese ores are generally analogous to those of modern hydrothermal ferromanganese plume fall-out precipitates deposited on MOR flanks. However in more detail, Mn and Ti enrichments in the ferromanganese ores are more striking than the modern counterpart, suggesting a significant contribution of hydrogenetic component in the Kunimiyama ores. Our results are consistent with the interpretation that the Kunimiyama ores were umber deposits that primarily formed by hydrothermal plume fall-out precipitation in the Panthalassa Ocean during the Early Permian and then accreted onto the proto-Japanese island arc during the Middle Jurassic. The presence of strong negative Ce anomaly in the Kunimiyama ores may indicate that the Early Permian Panthalassa seawater had a more striking negative Ce anomaly due to a more oxidizing oceanic condition than today.     

Carbonates in fractures of Martian meteorite Allan Hills 84001: Petrologic evidence for impact origin

Abstract— Carbonates in Martian meteorite Allan Hills 84001 occur as grains on pyroxene grain boundaries, in crushed zones, and as disks, veins, and irregularly shaped grains in healed pyroxene fractures. Some carbonate disks have tapered Mg-rich edges and are accompanied by smaller, thinner and relatively homogeneous, magnesite microdisks. Except for the microdisks, all types of carbonate grains show the same unique chemical zoning pattern on MgCO₃-FeCO₃-CaCO₃ plots. This chemical characteristic and the close spatial association of diverse carbonate types show that all carbonates formed by a similar process. The heterogeneous distribution of carbonates in fractures, tapered shapes of some disks, and the localized occurrence of Mg-rich microdisks appear to be incompatible with growth from an externally derived CO₂-rich fluid that changed in composition over time. These features suggest instead that the fractures were closed as carbonates grew from an internally derived fluid and that the microdisks formed from a residual Mg-rich fluid that was squeezed along fractures. Carbonate in pyroxene fractures is most abundant near grains of plagioclase glass that are located on pyroxene grain boundaries and commonly contain major or minor amounts of carbonate. We infer that carbonates in fractures formed from grain boundary carbonates associated with plagioclase that were melted by impact and dispersed into the surrounding fractured pyroxene. Carbonates in fractures, which include those studied by McKay et al. (1996), could not have formed at low temperatures and preserved mineralogical evidence for Martian organisms.     

Dynamics of pelagic variables in two contrasting coastal systems in the western Hokkaido coast off Otaru port,Japan

Human impact on adjacent coastal waters, leading to alteration in nutritional environment and hence affecting phytoplankton biomass (Chlorophyll a), will probably be enhanced by the nearby presence of ports. The main goal of this study is to assess the influence of nearby presence of port on phytoplankton biomass build-up and the physical–chemical environmental characteristics in two contrasting coastal systems (Otaru port, S-IN and an exposed coastal area, S-OUT) in the western Hokkaido coast off Otaru port, Japan. Sampling was conducted on “bi-weekly and monthly” basis during the period of September 2006–December 2007 and data comprising 11 pelagic variables were obtained. In most instance, phytoplankton biomass, nutrients' (NH₄, NO₃, PO₄, and Si(OH)₄) concentrations and nutrients' molar ratios were higher at the Otaru port location. Physical parameters (temperature, salinity, hydrogen ion concentration (pH), photosynthetically active radiation (PAR) and dissolved oxygen, (DO)) were not significantly different (P > 0.05) between the two locations. With the exception of salinity, pH and DIC, all variables measured showed significant variation (P < 0.05) with season. While the coefficient of variation (CV) of physical parameters and phytoplankton biomass were relatively higher in Otaru port location (S-IN), the exposed coastal location (S-OUT) showed a higher variation in chemical parameters. Other variables showed different patterns between the two locations. We conclude that ports, due to its activities and restricted circulation favour high nutrient loading and phytoplankton biomass build-up in adjacent coastal systems, thus, suggesting the need for continuous field observation data in order to advance our knowledge on possible future human impact on coastal environment and the need to monitor and control port activities.     

Influences of the snow cover on landslide displacement in winter period: a case study in a heavy snowfall area of Japan

The displacement of a relatively small reactivated landslide in a snowy area in Japan was monitored over a long period. The displacement rate of the landslide, which was approximately of 20 mm d^?1 before the formation of snow cover, decelerated drastically during the continuous snow cover period every winter period. Possible causes included reduction in the amount of water that reached the ground surface (MR: meltwater and/or rainwater) and increase in snow load. Given that the actual displacement of the landslide was far below the predicted value based on the relationship between landslide displacement and MR immediately before the continuous snow cover period, the deceleration of landslide displacement was more likely attributable to the increase in snow load than to the reduction in MR. An investigation of the link between snow load and landslide displacement showed a negative logarithmic relationship. A dynamic analysis based on the limit equilibrium method showed that snow load increases the effective normal stress and the stability of a landslide in which the mean inclination angle of the slip surface is smaller than the internal friction angle. The stability of the actual slope was also analyzed by conducting soil tests on samples collected at the site and using the resultant parameters. The analysis also showed that the increase in snow load increases the safety factor and reduces the landslide displacement. The displacement of a relatively small landslide that has a shallow slip surface was found to be greatly influenced by snow cover.     

Effect of the contraction of Zn-O bonds on X-ray emission spectra

Physics and Chemistry of Minerals - The X-ray emission spectra were measured for tetrahedrally coordinated Zn ion in several synthetic compounds. Intensity ratios of L β and L α spectral...     

A regression model-based method for indoor positioning with compound location fingerprints

ABSTRACT

This paper proposed and evaluated an estimation method for indoor positioning. The method combines location fingerprinting and dead reckoning differently from the conventional combinations. It uses compound location fingerprints, which are composed of radio fingerprints at multiple points of time, that is, at multiple positions, and displacements between them estimated by dead reckoning. To avoid errors accumulated from dead reckoning, the method uses short-range dead reckoning. The method was evaluated using 16 Bluetooth beacons installed in a student room with the dimensions of 11 × 5 m with furniture inside. The Received Signal Strength Indicator (RSSI) values of the beacons were collected at 30 measuring points, which were points at the intersections on a 1 × 1 m grid with no obstacles. A compound location fingerprint is composed of RSSI vectors at two points and a displacement vector between them. Random Forests (RF) was used to build regression models to estimate positions from location fingerprints. The root mean square error of position estimation was 0.87 m using 16 Bluetooth beacons. This error is lower than that received with a single-point baseline model, where a feature vector is composed of only RSSI values at one location. The results suggest that the proposed method is effective for indoor positioning.     

Effects of coastal erosion on landslide activity revealed by multi-sensor observations

Coastal erosion is becoming an increasingly serious consequence of climate change. This study demonstrates the effects of coastal erosion on landslide activity while considering the amount of erosion and changes in pore water pressure. To determine the factors related to landslide slip generation, we specifically measured the displacement, deformation, pore water pressure, and amount of erosion with high temporal resolution (1 s–1 h) for a coastal landslide in Hokkaido, north-eastern Japan, for 7 months. It has been determined that landslides occur simultaneously with high pore water pressure. Toe erosion events also occurred several times, while the landslide exhibited major displacement. Because toe erosion and the increase in pore water pressure occurred simultaneously, we tried to determine which of the two contributed majorly to the landslide displacement by conducting a stability analysis that incorporates the effects of the two factors. From the actual observed data, toe erosion and the increase in pore water pressure had comparable effects on the destabilization of the studied landslide. Specifically, the time series for the safety factor shows that the landslide in the case with toe erosion was destabilized more than that in the case with no erosion, with a difference of more than 5% in the safety factor. The model with toe erosion provided a better explanation for the landslide displacement. Furthermore, the inclination data suggested that erosion took place at least 1 month before the landslide displacement. This implied that coastal erosion played a role in the preparation and ongoing displacement of the coastal landslide. Inland landslides with toes that are subject to undercutting due to river incision or artificial construction have geomorphological settings that are similar to those of the studied landslide. The knowledge obtained here can contribute to the understanding of destabilization mechanisms and terrain changes related to such landslides. © 2020 John Wiley & Sons, Ltd.