Geochemistry and mineralogy of arsenic in (natural) anaerobic groundwaters

Here new data from field bioremediation experiments and geochemical modeling are reported to illustrate the principal geochemical behavior of As in anaerobic groundwaters. In the field bioremediation experiments, groundwater in Holocene alluvial aquifers in Bangladesh was amended with labile water-soluble organic C (molasses) and MgSO₄ to stimulate metabolism of indigenous SO₄-reducing bacteria (SRB). In the USA, the groundwater was contaminated by Zn, Cd and SO₄, and contained <10 μg/L As under oxidized conditions, and a mixture of sucrose and methanol were injected to stimulate SRB metabolism. In Bangladesh, groundwater was under moderately reducing conditions and contained ∼10 mg/L Fe and ∼100 μg/L As. In the USA experiment, groundwater rapidly became anaerobic, and dissolved Fe and As increased dramatically (As > 1000 μg/L) under geochemical conditions consistent with bacterial Fe-reducing conditions. With time, groundwater became more reducing and biogenic SO₄ reduction began, and Cd and Zn were virtually completely removed due to precipitation of sphalerite (ZnS) and other metal sulfide mineral(s). Following precipitation of chalcophile elements Zn and Cd, the concentrations of Fe and As both began to decrease in groundwater, presumably due to formation of As-bearing FeS/FeS₂. By the end of the six-month experiment, dissolved As had returned to below background levels. In the initial Bangladesh experiment, As decreased to virtually zero once biogenic SO₄ reduction commenced but increased to pre-experiment level once SO₄ reduction ended. In the ongoing experiment, both SO₄ and Fe(II) were amended to groundwater to evaluate if FeS/FeS₂ formation causes longer-lived As removal. Because As-bearing pyrite is the common product of SRB metabolism in Holocene alluvial aquifers in both the USA and Southeast Asia, it was endeavored to derive thermodynamic data for arsenian pyrite to better predict geochemical processes in naturally reducing groundwaters. Including the new data for arsenian pyrite into Geochemist’s Workbench, its stability field completely dominates in reducing Eh–pH space and “displaces” other As-sulfides (orpiment, realgar) that have been implied to be important in previous modeling exercises and reported in rare field conditions.     

Tridiurnal variations in cosmic-ray intensity

The tridiurnal wave in cosmic-ray intensity expected from a free space anisotropy is theoretically calculated for different cosmic-ray stations which are characterized by different shapes of asymptotic cones of acceptance. The amplitude A and the time of maximum Tmax are given for latitude dependence of the form cosⁿ λ and rigidity dependence of the form $\text{R}{}^{\mathrm{\beta }}\text{exp (?(R?}\text{1}\text{R}{}_0\text{))}$, where λ and R are the latitude and rigidity respectively and n, β, R₀ are constants. The values of A and Tmax, are calculated for different values of n, β and R₀ for each station. The dependence of A and Tmax on the anisotropy parameters is studied for the proper selection of cosmic-ray stations whose data may be used in determining these parameters.Available experimental data were used to find the observed amplitudes of the tridiurnal variations at five stations using power spectrum analysis with hanning applied on the averaged trains. Minimum variance analysis of the theoretical and experimental amplitudes showed that β has a value between 1 and 2, R₀ greater than 100 GV and n smaller than 3.     

Slow arsenic poisoning of the contaminated groundwater users

This paper gives impact of Arsenic contaminated water on human health as well as overview of the extent and severity of groundwater arsenic contamination in Bangladesh. Scalp hair is the most important part of the human body to monitor the accumulation of this type of poison. Therefore, an experiment has been carried out by Neutron Activation Analysis (NAA) at Atomic Energy Research Establishment (AERE), Savar, Dhaka, Bangladesh on human hair of corresponding tube well water users of these areas to determine the total accumulation of arsenic to their body. Hair samples collected from the region where the groundwater was found highly contaminated with arsenic. The obtained results of arsenic concentration in the lower age (Hb) categories of users (below 12 years of age users) is in the range of 0.33 to 3.29 /gmg/g (ppm) and that in the Hu categories (upper 12 years of age users) is 0.47 to 6.64 μg/g (ppm). Where as maximum permissible range is 1 ppm certified from WHO. Results show that the peoples are highly affected where the groundwater is highly contaminated with arsenic and acts as the primary source of arsenic poisoning among the peoples of those areas. The results indicate that human population is affected with arsenic locally using the contaminated water for a long time.     

On the mechanism of winter cyclogenesis in relation to vertical axis tilt

Summary ?This work is concerned with the behavior of the vertical trough axis tilt during the development of a Mediterranean cyclone. The period covering stages of the development of the depression is from 1200 UTC 18 January to 1200 UTC 25 January 1981. Two procedures have been used to illustrate the behavior of the vertical axis tilt with the development of our case study. In the first direct procedure we trace the centers of the cyclone for each level for each day and determine its longitude. In the second indirect procedure we compute the values and signs of the product of the perturbation of temperature and meridional velocity over the computational domain. The energetics of the depression is studied and the partition of available potential energy and kinetic energy into zonal and eddy component is adopted. The energy contents and their changes in different atmospheric levels are discussed in the course of the cyclone’s development. Received April 27, 2001; Revised December 12, 2001     

A new approach to estimate canopy evaporation and canopy interception capacity from evapotranspiration and sap flow measurements during and following wetting

Canopy interception and its evaporation into the atmosphere during irrigation or a rainfall event are important in irrigation scheduling, but are challenging to estimate using conventional methods. This study introduces a new approach to estimate the canopy interception from measurements of actual total evapotranspiration (ET) using eddy covariance and estimation of the transpiration from measurements of sap flow. The measurements were conducted over a small‐scale sprinkler‐irrigated cotton field before, during and after sprinkler irrigation. Evaporation and sap flow dynamics during irrigation show that the total ET during irrigation increased significantly because of the evaporation of free intercepted water while transpiration was suppressed almost completely. The difference between actual ET and transpiration (sap flow) during and immediately following irrigation (post irrigation) represents the total canopy evaporation while the canopy interception capacity was calculated as the difference between actual ET and transpiration (sap flow) during drying (post irrigation) following cessation of the irrigation. The canopy evaporation of cotton canopy was calculated as 0.8 mm, and the interception capacity was estimated to be 0.31 mm of water. The measurement uncertainty in both the non‐dimensional ET and non‐dimensional sap flow was shown to be very low. Copyright © 2015 John Wiley & Sons, Ltd.     

Geology and Active Tectonics of the Lalmai Hills,Bangladesh–An Overview from Chittagong Tripura Fold Belt Perspective

The Lalmai Hills is a low amplitude anticline with significant variations in landforms, situated along the western fringe of the Chittagong-Tripura Fold Belt (CTFB) and immediate east of the Indo-Burmese deformation front. This fold belt of the Bengal Basin along with more easterly Indo-Burman Range (IBR) developed as a consequence of the oblique collision between Indian and Burmese plates. This neotectonic activity is still continuing and shaping the geomorphology of the area. This study is conducted based on the geomorphological observation of the topo maps and satellite images, and through reconnaissance field work. Stream length gradient index (SL Index) and Mountain front sinuosity (S_mf) reveals the relative status of tectonic activity. Anomalous SL index values confirm the position of the sympathetic minor faults and also relate to the local stratigraphy. A 2D structural model based on the seismic section reveals thrusts controlled wedge-shape upliftment of the central part as pop-up anticlinal structure. The western thrust is the direct result of the collision of the Indian and Burmese plates, and the eastern one is the back thrust of the western fault. Low S_mf value found in the western flank signifies recent tectonics and relatively high S_mf value in the eastern flank indicates that weathering intensity is relatively greater compared to western flank. Finally, the findings not only enhanced the understanding of geomorphic evolution and active tectonics of the Lalmai Hills area but also the overall tectonic and geomorphic evolution of the western most folded part of the CTFB.     

Evaporitic sedimentation and microbial mats in a salina system (Port Fouad,Egypt)

A salina system along the Mediterranean coast of Egypt was investigated. Five sedimentary facies are described. For each facies, the evaporitic sedimentation and the biological conditions are considered. Comparisons of evaporite precipitates in the salina with ancient deposits are made.     

On the modification of the dynamics in the environment of severe thunderstorms

Summary A detailed study of widespread thunderstorm activity occurring in winter over the central and coastal parts of Egypt (Cairo 30° N, Marsa Matruh 31° N) is presented. The storm activity is associated with strong positive vorticity in the 300/200 mb layer. The maximum kinetic energy was located at the storm centre. The divergent wind component was found to be very important in energy transformation and a major cause of energy generation by cross contour flow.With 3 Figures     

On heavy metal concentrations and biogenic enrichment in microbial mat environments

Heavy metal concentrations of a recent salina on the shore of the Mediterranean Sea near Port Said (Egypt) were investigated. Samples for the heavy metal study were taken in different ponds of the salina. It was found that microbial mat dominated brine sediments concentrated and enriched heavy metal 2–3 times more than sediments lacking microbial mat developments, suggesting that cyanobacteria play a major role in this enrichment. Heavy metal enrichment by cyanobacteria was therefore also studied in the laboratory environment. This study is compared with a recent study of Solar Lake and Sabkha Gavish sediments (Sinai, Egypt). Our conclusion is that recent hypersaline environments with ambient microbial mat (potential stromatolite) developments are ideal examples of present-day environments of metal accumulations.     

An analysis of coal bump liability in a bump prone mine

Summary This paper presents an analysis of causes of bump in a deep coal mine. The analysis consists of in-mine measurement determination, analysis of physical and mechanical properties of mine materials and simulation of mine layout and mining sequence. Major factors contributing to the causes of bump have been reviewed and those that are related to this case have been identified and simulated analytically using a three-dimensional finite element method.