Sedimentary evolution of a Late Pleistocene temperate red algal reef (Coralligène) on Rhodes,Greece: correlation with global sea‐level fluctuations

Autochthonous red algal structures known as coralligène de plateau occur in the modern warm‐temperate Mediterranean Sea at water depths from 20 to 120 m, but fossil counterparts are not so well‐known. This study describes, from an uplifted coastal section at Plimiri on the island of Rhodes, a 450 m long by 10 m thick Late Pleistocene red algal reef (Coralligène Facies), interpreted as being a coralligène de plateau, and its associated deposits. The Coralligène Facies, constructed mainly by Lithophyllum and Titanoderma, sits unconformably upon the Plio‐Pleistocene Rhodes Formation and is overlain by a Maerl Facies (2 m), a Mixed Siliciclastic‐Carbonate Facies (0·2 m) and an Aeolian Sand Facies (2·5 m). The three calcareous facies, of Heterozoan character, are correlated with established members in the Lindos Acropolis Formation in the north of the island, while the aeolian facies is assigned to the new Plimiri Aeolianite Formation. The palaeoenvironmental and genetic‐stratigraphic interpretations of these mixed siliciclastic‐carbonate temperate water deposits involved consideration of certain characteristics associated with siliciclastic shelf and tropical carbonate shelf models, such as vertical grain‐size trends and the stratigraphic position of zooxanthellate coral growths. Integration of these results with electron spin resonance dates of bivalve shells indicates that the Coralligène Facies was deposited during Marine Isotope Stage 6 to 5e transgressive event (ca 135 to 120 ka), in water depths of 20 to 50 m, and the overlying Maerl Facies was deposited during regression from Marine Isotope Stage 5e to 5d (ca 120 to 110 ka), at water depths of 25 to 40 m. The capping Aeolian Sand Facies, involving dual terrestrial subunits, is interpreted as having formed during each of the glacial intervals Marine Isotope Stages 4 (71 to 59 ka) and 2 (24 to 12 ka), with soil formation during the subsequent interglacial periods of Marine Isotope Stages 3 and 1, respectively. Accumulation rates of about 0·7 mm year^?1 are estimated for the Coralligène Facies and minimum accumulation rates of 0·2 mm year^?1 are estimated for the Maerl Facies. The existence of older red algal reefs in the Plimiri region during at least Marine Isotope Stages 7 (245 to 186 ka) and 9 (339 to 303 ka) is inferred from the occurrence of reworked coralligène‐type lithoclasts in the basal part of the section and from the electron spin resonance ages of transported bivalve shells.     

THE KALMAN FILTER AS A PREDICTION ERROR FILTER*

In mathematical statistical filtering the deconvolution problem can be solved by two different methods:

• 1 by inverse filtering
• 2 by calculating the prediction error.

Both methods are well known in the theory of Wiener filters. If, however, the generating process of the signal is known and can be described by a set of linear first order differential equations, then the Kalman filter can also be used to solve the deconvolution problem. In the case of the inverse filtering method this was shown by Bayless and Brigham (1970). But, while their method can only be used if the original signal is a colored random process, this paper shows that in the case of a white process the prediction error filtering method is a more appropriate approach. The method is extremely efficient and simple. This can be demonstrated by an example which maybe of special interest for seismic exploration.     

Search for extinct aluminum‐26 and titanium‐44 in nanodiamonds from the Allende CV3 and Murchison CM2 meteorites

Abstract– We report Mg‐Al and Ca‐Ti isotopic data for meteoritic nanodiamonds separated from the Allende CV3 and Murchison CM2 meteorites. The goal of this study was to search for excesses in ²⁶Mg and ⁴⁴Ca, which can be attributed to the in situ decay of radioactive and now extinct ²⁶Al and ⁴⁴Ti, respectively. Previous work on presolar SiC and graphite had shown that ²⁶Al/²⁷Al and ⁴⁴Ti/⁴⁸Ti ratios in presolar grains can be used to discriminate between different types of stellar sources. Aluminum and Ti concentrations are low in the meteoritic nanodiamonds of this study. Murchison nanodiamonds have higher Al and Ti concentrations than the Allende nanodiamonds. This can be attributed to contamination and the presence of presolar SiC in the Murchison nanodiamond samples. ²⁶Mg/²⁴Mg and ⁴⁴Ca/⁴⁰Ca ratios are close to normal in Allende nanodiamonds with upper limits on the initial ²⁶Al/²⁷Al and ⁴⁴Ti/⁴⁸Ti ratios of approximately 1 × 10^?3. These ratios are factors of 10–1000 and, respectively, 1–1000 lower than those of presolar SiC and graphite grains from supernovae. The ²⁶Al/²⁷Al and ⁴⁴Ti/⁴⁸Ti data for nanodiamonds are compatible with an asymptotic giant branch star or solar system origin, but not with a supernova origin of a major fraction of meteoritic nanodiamonds. The latter possibility cannot be excluded, though, as the diamond separates may contain significant amounts of contaminating Al and Ti, which would lower the inferred ²⁶Al/²⁷Al and ⁴⁴Ti/⁴⁸Ti ratios considerably.     

Deciphering the depositional environment of the laminated Crato fossil beds (Early Cretaceous,Araripe Basin,North‐eastern Brazil)

The laminated limestones of the Early Cretaceous Crato Formation of the Araripe Basin (North‐eastern Brazil) are world‐famous for their exceptionally well‐preserved and taxonomically diverse fossil fauna and flora. Whereas the fossil biota has received considerable attention, only a few studies have focused on the sedimentary characteristics and palaeoenvironmental conditions which prevailed during formation of the Crato Fossil Lagerstätte. The Nova Olinda Member represents the lowermost and thickest unit (up to 10 m) of the Crato Formation and is characterized by a pronounced rhythmically bedded, pale to dark lamination. To obtain information on palaeoenvironmental conditions, sample slabs derived from three local stratigraphic sections within the Araripe Basin were studied using high‐resolution multiproxy techniques including detailed logging, petrography, μ‐XRF scanning and stable isotope geochemistry. Integration of lithological and petrographic evidence indicates that the bulk of the Nova Olinda limestone formed via authigenic precipitation of calcite from within the upper water column, most probably induced and/or mediated by phytoplankton and picoplankton activity. A significant contribution from a benthonic, carbonate‐secreting microbial mat community is not supported by these results. Deposition took place under anoxic and, at least during certain episodes, hypersaline bottom water conditions, as evidenced by the virtually undisturbed lamination pattern, the absence of a benthonic fauna and by the occurrence of halite pseudomorphs. Input of allochthonous, catchment‐derived siliciclastics to the basin during times of laminite formation was strongly reduced. The δ¹⁸O values of authigenic carbonate precipitates (between ?7·1 and ?5·1‰) point to a ¹⁸O‐poor meteoric water source and support a continental freshwater setting for the Nova Olinda Member. The δ¹³C values, which are comparatively rich in ¹³C (between ?0·1 and +1·9‰), are interpreted to reflect reduced throughflow of water in a restricted basin, promoting equilibration with atmospheric CO₂, probably in concert with stagnant conditions and low input of soil‐derived carbon. Integration of lithological and isotopic evidence indicates a shift from closed to semi‐closed conditions towards a more open lake system during the onset of laminite deposition in the Crato Formation.     

The Triassic ammonite Aristoptychites kolymensis (Kiparisova) from Botneheia, Spitsbergen

Aristoptychites kolymensis (Kiparisova) is investigated and described in detail from collections made at Botneheia, Spitsbergen, where it occurs at the top of the Botneheia Formation (Daonella Shale). It is a rather small species and the stratigraphically highest representative of the genus in Spitsbergen. Its suture line is remarkable by its possession of the additional U.-lobes between the internal lobe and the first umbilical lobe. A lobe of this kind has so far been described only once, with Arcestes (Proarcestes) bicarinatus by Schindewolf (1968), which suggests affinities between Ptychitidae and Arcestidae.     

The Puerto Lápice eucrite

Abstract— Puerto Lápice is a new eucrite fall (Castilla‐La Mancha, Spain, 10 May 2007). In this paper, we report its detailed petrography, magnetic characterization, mineral and bulk chemistry, oxygen and noble gas isotope systematics, and radionuclide data. Study of four thin sections from two different specimens reveal that the meteorite is brecciated in nature, and it contains basaltic and granulitic clasts, as well as recrystallized impact melt and breccia fragments. Shock veins are ubiquitous and show evidence of at least three different shock events. Bulk chemical analyses suggest that Puerto Lápice belongs to the main group of basaltic eucrites, although it has a significantly higher Cr content. Oxygen isotopes also confirm that the meteorite is a normal member of the HED suite. Noble gas abundances show typical patterns, with dominant cosmogenic and radiogenic contributions, and indicate an average exposure age of 19 ± 2 Ma, and a Pu‐fission Xe age well within typical eucrite values. Cosmogenic radionuclides suggest a preatmospheric size of about 20–30 cm in diameter.     

Noble gas adsorption with and without mechanical stress: Not Martian signatures but fractionated air

Abstract– Sample preparation, involving physical and chemical methods, is an unavoidable step in geochemical analysis. From a noble gas perspective, the two important effects are loss of sample gas and/or incorporation of air, which are significant sources of analytical artifacts. This article reports on the effects of sample exposure to laboratory air without mechanical influence and during sample grinding. The experiments include pure adsorption on terrestrial analog materials (gibbsite and olivine) and grinding of Martian meteorites. A consistent observation is the presence of an elementally fractionated air component in the samples studied. This is a critical form of terrestrial contamination in meteorites as it often mimics the heavy noble gas signatures of known extra‐terrestrial end‐members that are the basis of important conclusions about the origin and evolution of a meteorite. Although the effects of such contamination can be minimized by avoiding elaborate sample preparation protocols, caution should be exercised in interpreting the elemental ratios (Ar/Xe, Kr/Xe), especially in the low‐temperature step extractions. The experiments can also be transferred to the investigation of Martian meteorites with long terrestrial residence times, and to Mars, where the Mars Science Laboratory mission will be able to measure noble gas signatures in the current atmosphere and in rocks and soils collected on the surface in Gale crater.     

Post‐Glacial immigration of the harbour porpoise (Phocoena phocoena) into the Baltic Sea*

At the end of the Pleistocene, environmental conditions in the Baltic Basin were affected by the melting glaciers and the resultant freshwater bodies. In contrast to various seal species, there is no subfossil evidence of the harbour porpoise (Phocoena phocoena) from the early Holocene stages of the Baltic Basin. This article is an attempt to clarify the colonization of the harbour porpoise into the Baltic Sea and to reveal the ecological background of this process. All published Holocene subfossil records from the porpoise in the Baltic region were sought and supplemented with those from museums and zoological collections; 148 records document the porpoise's occurrence. The earliest records of the harbour porpoise date from the time between 9600 and 7000 cal. yr BP and originate from the early and middle Mesolithic coastal settlements of the Maglemose and Kongemose culture during the early Littorina stage. Around 7500–5700 cal. yr BP, the porpoise is recorded frequently at many localities from late Mesolithic (Ertebølle culture) and Neolithic in the coastal areas of the western Baltic Sea, as well as for the first time in the Gulfs of Bothnia and Finland. Since 4000 cal. yr BP, P. phocoena has only been recorded in the western Baltic. We suggest that immigration and dispersion of P. phocoena into the Baltic Sea was connected with the Littorina transgression beginning around 9000 cal. yr BP. The continuous influx of seawater and the associated ecological changes led to a new, very species‐rich, fish community and adequate living conditions for the harbour porpoise.