Absorption spectra of Cr3+ in Al2O3 under shock compression

Unpolarized absorption spectra of single crystals of Cr³⁺ doped Al₂O₃ (synthetic ruby) have measured using a new, time-resolving, dispersive, streak photographic system over the range ～350 to ～700 nm during a series of shock loading experiments. The crystal field absorptions assigned to the transition ⁴ A _2g→⁴ T _2g were observed to shift in a series of experiments from 555±1 nm at atmospheric pressure to 503±5 nm at 46 GPa. In a single experiment at 32 GPa the ⁴ A _2g→⁴ T _1g transition was observed to shift from 405±1 to 386±5 nm. The present data extrapolate downwards in compression toward the 10 GPa data of Stephens and Drickamer (1961) although both crystal field absorption energies increase considerably less with compression than predicted by the simple ionic point charge model. The single datum observed for the Racah parameter B, 588±38 cm^?1 at 32 GPa, is consistant with previous results to 10 GPa and the trend of decreasing B, with compression expected from the divergence of the data from the point charge model due to increasing covalancy.     

A design for digital signal processing in a large field radio patrol camera

An FFT processor is being developed for the present pilot system of the large field radio patrol camera. A design of the processor is discussed.Paper presented at the IAU Third Asian-Pacific Regional Meeting, held in Kyoto, Japan, between 30 September–6 October, 1984.     

Single crystal X-ray and Mössbauer study of shocked ilmenite to 80 GPa

Shock loading experiments on single crystal ilmenite (FeTiO₃) are carried out up to peak pressures of 80 GPa using a newly built two-stage light gas gun. Shock effects are investigated by means of X-ray precission technique and Mössbauer spectroscopy. Shock effects are largely controlled by the anisotropic nature of the ilmenite structure. Considerable deformations are observed even in a pressure level of 30 GPa in the shocked crystal when the shock propagation direction is parallel to the c axis, whereas little effects are seen up to 55 GPa when the crystal is shocked parallel to the c plane (cleavage plane). The greatest deformation is introduced in the planes containing the c axis, while less remarkable effects are seen in the plane perpendicular to the c axis. Residual effects are favorably compared with the compression anomalies found in the Hugoniot measurements by King and Ahrens (1976). Mössbauer measurements also reveal that a fraction of highly disturbed regions increases with increasing shock loading pressure. These observations are explained in terms of current heterogeneous yielding model of brittle substances under shock loading, where internal fragmentation is preferentially formed so as to give c-platelet domains that are mutually misoriented with each other.     

Coupling mechanisms between equatorial waves and cumulus convection in an AGCM

In this study, we focused on the difference in appearances of the convectively coupled equatorial waves (CCEWs) in a simulation with the CCSR/NIES/FRCGC AGCM, between two experiments, one with and the other without implementation of the convective suppression scheme (CSS) in the prognostic Arakawa–Schubert cumulus parameterization. Realistic CCEW modes, i.e., Kelvin, Rossby, mixed Rossby-gravity (MRG), and n = 0 eastward inertio-gravity (EIG) wave modes, were reproduced in the with-CSS experiment, while only Rossby-wave-like signals appeared in the without-CSS experiment.By comparing the structures of the Kelvin wave mode and the Rossby wave mode in two runs, it was suggested that the structural difference between these two modes in conjunction with the difference in the controlling factor of cumulus convection determines the CCEW features. The CSS implemented here is such that cumulus convection is suppressed until the cloud-layer-averaged relative humidity exceeds the threshold of 80%. In the without-CSS model, only Rossby wave modes are coupled with the convection. This is because CAPE controls cumulus convection in this model, and the larger frictional convergence of Rossby wave mode prepares CAPE to generate favorable condition for cumulus convection. In the case of the with-CSS model, on the other hand, cumulus convection is largely controlled by the humidity in the free atmosphere. The convergence associated with the equatorial waves can produce the moisture anomaly to overcome the relative humidity threshold, and maintains the favorable condition for cumulus convection once it starts. In this case, not only Rossby waves but also Kelvin, MRG, and n = 0 EIG waves are reproduced more realistically. It is suggested that inclusion of some kind of mechanism connecting the free tropospheric moisture with the convection under the condition of abundant convective available potential energy could be a key factor for realistic coupling between large-scale atmospheric waves and convection.     

Seasonal variation of the ITCZ and its characteristics over central Africa

We investigated the seasonal march of the Intertropical Convergence Zone (ITCZ) shown by the 22 coupled general circulation models of the 20th Century Climate in Coupled Models experiment in seven regions (Africa, Indian Ocean, western Pacific, central Pacific, eastern Pacific, South America, and Atlantic Ocean). Inter-model differences in the seasonal march of the ITCZ over Africa (10?C40°E) were significantly smaller than those over other regions. This finding indicates that the seasonal march of the ITCZ over Africa is insensitive to differences in model physics and resolution and suggests that the seasonal march of the African ITCZ is controlled by robust and simple mechanisms. Motivated by this result, we tried to understand the process of the seasonal march of the ITCZ over central Africa (15?C30°E) based on an analysis of ERA-40 data. The analysis results revealed the following features of the ITCZ in this region: (1) The ITCZ itself produces large convective available potential energy that generates deep convection. (2) The abundant water vapor within the ITCZ is maintained by horizontal moisture flux. (3) Outside but near the ITCZ, shallow convection exists and may act to pre-moisten deep convection in spring and autumn. (4) The seasonal change of the ITCZ is preceded by that of the vertical moist instability in the lower free atmosphere caused by the seasonal change in insolation.