Improved Determination of Ethane (C2H6) Abundance in Titan's Stratosphere

Ethane spectral lines were observed in emission from Titan in August 1993, October 1995, and September 1996, at a spectral resolution of λ/Δλ≈10⁶, at wavelength 11.7−11.9 μm using the Goddard Infrared Heterodyne Spectrometer at the NASA Infrared Telescope Facility on Mauna Kea, Hawaii. The ethane mole fraction is determined to be (8.8±2.2)×10⁻⁶ (68.3% confidence limits, “1σ”), averaging the retrievals from each observing run obtained using the “recommended” thermal profile of R. V. Yelle, D. Strobel, E. Lellouch, and D. Gautier (1997, in Huygens: Science, Payload, and Mission (J.-P. Lebreton, Ed.), pp. 243-256, European Space Agency SP-1177).     

Modification of Jupiter’s stratosphere three weeks after the 2009 impact

Infrared spectroscopy sensitive to thermal emission from Jupiter’s stratosphere reveals effects persisting 23 days after the impact of a body in late July 2009. Measurements obtained on 2009 August 11 UT at the impact latitude of 56°S (planetocentric), using the Goddard Heterodyne Instrument for Planetary Wind and Composition mounted on the NASA Infrared Telescope Facility, reveal increased ethane abundance and the effects of aerosol opacity. An interval of reduced thermal continuum emission at 11.744 μm is measured ∼60-80° towards planetary east of the impact site, estimated to be at 305° longitude (System III). Retrieved stratospheric ethane mole fraction in the near vicinity of the impact site is enhanced by up to ∼60% relative to quiescent regions at this latitude. Thermal continuum emission at the impact site, and somewhat west of it, is significantly enhanced in the same spectra that retrieve enhanced ethane mole fraction. Assuming that the enhanced continuum brightness near the impact site results from thermalized aerosol debris blocking contribution from the continuum formed in the upper troposphere and indicating the local temperature, then continuum emission by a haze layer can be approximated by an opaque surface inserted at the 45-60 mbar pressure level in the stratosphere in an unperturbed thermal profile, setting an upper limit on the pressure and therefore a lower limit on the altitude of the top of the impact debris at this time. The reduced continuum brightness east of the impact site can be modeled by an opaque surface near the cold tropopause, which is consistent with a lower altitude of ejecta/impactor-formed opacity. The physical extent of the observed region of reduced continuum implies a minimum average velocity of 21 m/s transporting material prograde (planetary east) from the impact.     

Direct wind measurements from November 2007 in Venus’ upper atmosphere using ground-based heterodyne spectroscopy of CO2 at 10 μm wavelength

Between November 23 and 28, 2007, the Cologne Tuneable Heterodyne Infrared Spectrometer THIS was installed at the McMath-Pierce Solar Telescope (Kitt Peak, Arizona, USA) to determine zonal wind velocities and to estimate the subsolar-to-antisolar flow. We investigate dynamics in the upper atmosphere of Venus by measuring the Doppler shift of fully-resolved non-LTE CO₂ emission lines at 959.3917 cm^?1 (10.423 μm), which probe a narrow altitude region in Venus’ atmosphere around 110 ± 10 km (～1 μbar). The results show no significant zonal wind velocity at the equator. An increase with latitude up to 43 ± 13 m/s at a latitude of 33°N was observed. This confirms the deduction of a minor influence of Venus superrotation at an altitude of 110 km from previous measurements in May 2007 (Sornig et al., 2008). The specific observing geometry enables estimating the maximum cross terminator velocity of the subsolar-to-antisolar flow at 72 ± 47 m/s.     

Thermospheric/mesospheric temperatures on Venus: Results from ground-based high-resolution spectroscopy of CO2 in 1990/1991 and comparison to results from 2009 and between other techniques

We report temperatures in Venus’ upper mesosphere/lower thermosphere, deduced from reanalyzing very high resolution infrared spectroscopy of CO₂ emission lines acquired in 1990 and 1991. Kinetic temperatures at ～110 km altitude (0.15 Pa) are derived from the Doppler width of fully-resolved single line profiles measured near 10.4 μm wavelength using the NASA GSFC Infrared Heterodyne Spectrometer (IRHS) at the NASA IRTF on Mauna Kea, HI, close to Venus inferior conjunction and two Venus solstices. Measured temperatures range from ～200 to 240 K with uncertainty typically less than 10 K. Temperatures retrieved from similar measurement in 2009 using the Cologne Tuneable Heterodyne Infrared Spectrometer (THIS) at the NOAO McMath Telescope at Kitt Peak, AZ are 10–20 K lower. Temperatures retrieved more recently from the SOIR instrument on Venus EXpress are consistent with these results when the geometry of observation is accounted for. It is difficult to compare ground-based sub-mm retrievals extrapolated to 110 km due to their much larger field of view, which includes the night side regions not accessible to infrared heterodyne observations. Temperature variability appears to be high on day-to-day as well as longer timescales. Observed short term and long term variability may be attributed to atmospheric dynamics, diurnal variability and changes over solar activity and seasons. The Venus International Reference Atmosphere (VIRA) model predicts cooler temperatures at the sampled altitudes in the lower thermosphere/upper mesosphere and is not consistent with these measurements.     

Infrared Observations Of Dust Emission From Comet Hale-Bopp

We present infrared imaging and photometry of the bright, giant comet C/1995 O1 (Hale-Bopp). The comet was observed in an extended infrared and optical observing campaign in 1996–1997. The infrared morphology of the comet was observed to change from the 6 to 8 jet “porcupine” structure in 1996 to the “pinwheel” structure seen in 1997; this has implications for the position of the rotational angular momentum vector. Long term light curves taken at 11.3 μm indicate a dust production rate that varies with heliocentric distance as ∶ r^−1.4. Short term light curves taken at perihelion indicate a rotational periodicity of 11.3 hours and a projected dust outflow speed of ∶ 0.4 km s⁻¹. The spectral energy distribution of the dust on October 31, 1996 is well modeled by a mixture of 70% silicaceous and 30% carbonaceous non-porous grains, with a small particle dominated size distribution like that seen for comet P/Halley (McDonnell et al., 1991), an overall dust production rate of 2 × 10⁵ kg s⁻¹, a dust-to-gas ratio of ∶5, and an albedo of 39%. This revised version was published online in July 2006 with corrections to the Cover Date.     

Comparison of HIPWAC and Mars Express SPICAM observations of ozone on Mars 2006-2008 and variation from 1993 IRHS observations

Ozone is a tracer of photochemistry in the atmosphere of Mars and an observable used to test predictions of photochemical models. We present a comparison of retrieved ozone abundances on Mars using ground-based infrared heterodyne measurements by NASA Goddard Space Flight Center’s Heterodyne Instrument for Planetary Wind And Composition (HIPWAC) and space-based Mars Express Spectroscopy for the Investigation of the Characteristics of the Atmosphere of Mars (SPICAM) ultraviolet measurements. Ozone retrievals from simultaneous measurements in February 2008 were very consistent (0.8 μm-atm), as were measurements made close in time (ranging from <1 to >8 μm-atm) during this period and during opportunities in October 2006 and February 2007. The consistency of retrievals from the two different observational techniques supports combining the measurements for testing photochemistry-coupled general circulation models and for investigating variability over the long-term between spacecraft missions. Quantitative comparison with ground-based measurements by NASA/GSFC’s Infrared Heterodyne Spectrometer (IRHS) in 1993 reveals 2-4 times more ozone at low latitudes than in 2008 at the same season, and such variability was not evident over the shorter period of the Mars Express mission. This variability may be due to cloud activity.     

Temporal Behavior of Stratospheric Ammonia Abundance and Temperature Following the SL9 Impacts

Infrared emission lines of stratospheric ammonia (NH₃) were observed following the collisions of the fragments of Comet Shoemaker-Levy 9 with Jupiter in July of 1994 at the impact sites of fragments G and K. Infrared heterodyne spectra near 10.7 μm were obtained by A. Betz et al. (in Abstracts for Special Sessions on Comet Shoemaker-Levy 9, The 26th Meeting of the Division for Planetary Sciences, Washington DC, 31 Oct.-4 Nov. 1994, p. 25) using one of the Infrared Spatial Interferometer telescope systems on Mount Wilson. Lineshapes of up to three different NH₃ emission lines were measured at a resolving power of ∼10⁷ at multiple times following the impacts. We present here our radiative transfer analysis of the fully resolved spectral lineshapes of the multiple rovibrational lines. This analysis provides information on temperature structure and NH₃ abundance distributions and their temporal changes up to 18 days after impact. These results are compared to photochemical models to determine the role of photochemistry and other mechanisms in the destruction and dilution of NH₃ in the jovian stratosphere after the SL9 impacts.One day following the G impact, the inferred temperature above 0.001 mbar altitude is 283±13 K, consistent with a recent plume splashback model. Cooling of the upper stratosphere to 204 K by the fourth day and to quiescence after a week is consistent with a simple gray atmosphere radiative flux calculation and mixing with cold jovian air. During the first 4 days after impact, NH₃ was present primarily at altitudes above 1 mbar with a column density of (7.7±1.6)×10¹⁷ cm⁻² after 1 day and (3.7±0.8)×10¹⁷ cm⁻² after 4 days. (Errors represent precision.) We obtained >2.5 times more NH₃ than can be supplied by nitrogen from a large cometary fragment, suggesting a primarily jovian source for the NH₃. By 18 days postimpact, a return to quiescent upper stratospheric temperature is retrieved for the G region, with an NH₃ column density of 7.3×10¹⁷ cm⁻² or more in the lower stratosphere, possibly supplied by NH₃ upwelling across an impact-heated and turbulent tropopause, which may have been masked by initial dust and haze. Above the 1-mbar level, the maximum retrieved column density decreased to 6.5×10¹⁶ cm⁻². Comparison to photochemical models indicates that photolysis alone is not sufficient to account for the loss of NH₃ above 1 mbar by that time, even when chemical reformation of NH₃ is ignored. We speculate that the dispersion of plume material at high altitudes (above 1 mbar) is responsible for the change in the spectra observed a few days postimpact. Data on the K impact region provide qualitatively consistent results.     

Ozone abundance on Mars from infrared heterodyne spectra: I. Acquisition, retrieval, and anticorrelation with water vapor

Observations of ozone on Mars were made using the Goddard Space Flight Center's Infrared Heterodyne Spectrometer and Heterodyne Instrument for Planetary Wind and Composition at the NASA Infrared Telescope Facility. Ozone is an important observable tracer of martian photochemistry. Infrared heterodyne spectroscopy with spectral resolution ?¹⁰⁶ is the only technique that directly measures ozone in the martian atmosphere from the surface of the Earth. Ozone column abundances down to the martian surface were acquired in seven data sets taken between 1988 and 2003 at various orbital positions (LS=40°, 74°, 102°, 115°, 202°, 208°, 291°). Ozone abundances are compared with those retrieved using ultraviolet techniques, showing good agreement. Odd hydrogen (HO_X) chemistry predicts anticorrelation of ozone and water vapor abundances. Retrieved ozone abundances consistently show anticorrelation with corresponding water vapor abundances, providing strong confirmation of odd hydrogen activity. Deviation from strict anticorrelation between the observed total column densities of ozone and water vapor suggests that constituent vertical distribution is an additional, significant factor.     

Ozone abundance on Mars from infrared heterodyne spectra: II. Validating photochemical models

Ozone is an important observable tracer of martian photochemistry, including odd hydrogen (HO_x) species important to the chemistry and stability of the martian atmosphere. Infrared heterodyne spectroscopy with spectral resolution ?¹⁰⁶ provides the only ground-based direct access to ozone absorption features in the martian atmosphere. Ozone abundances were measured with the Goddard Infrared Heterodyne Spectrometer and the Heterodyne Instrument for Planetary Wind and Composition at the NASA Infrared Telescope Facility on Mauna Kea, Hawai'i. Retrieved total ozone column abundances from various latitudes and orbital positions (LS=40°, 74°, 102°, 115°, 202°, 208°, 291°) are compared to those predicted by the first three-dimensional gas phase photochemical model of the martian atmosphere [Lefèvre, F., Lebonnois, S., Montmessin, F., Forget, F., 2004. J. Geophys. Res. 109, doi:10.1029/2004JE002268. E07004]. Observed and modeled ozone abundances show good agreement at all latitudes at perihelion orbital positions (LS=202°, 208°, 291°). Observed low-latitude ozone abundances are significantly higher than those predicted by the model at aphelion orbital positions (LS=40°, 74°, 115°). Heterogeneous loss of odd hydrogen onto water ice cloud particles would explain the discrepancy, as clouds are observed at low latitudes around aphelion on Mars.