Rainfall intensity affects runoff responses in a semi-arid catchment

The source and hydrochemical makeup of a stream reflects the connectivity between rainfall, groundwater, the stream, and is reflected to water quantity and quality of the catchment. However, in a semi-arid, thick, loess covered catchment, temporal variation of stream source and event associated behaviours are lesser known. Thus, the isotopic and chemical hydrographs in a widely distributed, deep loess, semi-arid catchment of the northern Chinese Loess Plateau were characterized to determine the source and hydrochemical behaviours of the stream during intra-rainfall events. Rainfall and streamflow were sampled during six hydrologic events coupled with measurements of stream baseflow and groundwater. The deuterium isotope (²H), major ions (Cl⁻, SO₄²⁻, NO₃⁻, Ca²⁺, K⁺, Mg²⁺, and Na⁺) were evaluated in water samples obtained during rainfall events. Temporal variation of ²H and Cl⁻ measured in the groundwater and stream baseflow prior to rainfall was similar; however, the isotope compositions of the streamflow fluctuated significantly and responded quickly to rainfall events, likely due to an infiltration excess, overland dominated surface runoff during torrential rainfall events. Time source separation using ²H demonstrated greater than 72% on average, the stream composition was event water during torrential rainfall events, with the proportion increasing with rainfall intensity. Solutes concentrations in the stream had loglinear relationships with stream discharge, with an outling anomaly with an example of an intra-rainfall event on Oct. 24, 2015. Stream Cl⁻ behaved nonconservative during rainfall events, temporal variation of Cl⁻ indicated a flush and washout at the onset of small rainfall events, a dilution but still high concentration pattern in high discharge and old water dominated in regression flow period. This study indicates rainfall intensity affects runoff responses in a semi-arid catchment, and the stored water in the thick, loess covered areas was less connected with stream runoff. Solute transport may threaten water quality in the area, requiring further analysis of the performance of the eco-restoration project.     

Benthic foraminiferal fauna and sediment provenance of Eocene syn-rift sequences in Taiwan: implication for onset of Asian epi-continental marginal seas off China coast

Marine Geophysical Research - Early Cenozoic rift basins developed commonly on the Mesozoic basement along the SE Asia Continent. However, Eocene–Oligocene sequences were only exposed widely...     

我国海洋环境保护标准化的现状、需求和建议

海洋环境保护标准化对我国海洋环境保护事业的发展具有重要的技术支撑作用。文章从海洋环境保护标准体系、标准发布和制修订以及标准类别特征等方面,概述我国海洋环境保护标准化的发展现状;分析海洋环境保护标准化的需求,主要包括标准的适用性和有效性有待评估和提升、标准制修订的进程有待加快、监测方法标准的体例和结构有待规范和统一、海洋高新技术标准体系有待建立以及与多学科和其他行业标准有待统筹5个方面。基于此,提出促进和保障海洋环境保护标准化工作发展的4点建议,即建立海洋环境保护标准化工作专家库、健全海洋环境保护标准体系、加强多部门合作和积极参与海洋国际标准化工作。     

张掖盆地地下水硝酸盐污染与人体健康风险评价

地下水是张掖盆地的重要水资源，其硝酸盐污染尚未得到足够重视。对张掖盆地2004、2015年地下水硝酸盐浓度进行了系统分析，并采用美国环境保护署（USEPA）推荐的健康风险评价模型评估了地下水硝酸盐的健康风险。结果表明：自2004年以来张掖盆地地下水硝酸盐污染日趋严重。2015年硝酸盐浓度最高已达到283.32 mg·L^-1，17.61%的采样点硝酸盐氮浓度超过GB5749-2006《生活饮用水卫生标准》中饮用地下水限量值（20 mg·L^-1）。研究区人群经皮肤接触途径摄入硝酸盐的健康风险在可接受水平，而饮水摄入硝酸盐的健康风险较高，总风险中饮水途径引起健康风险的贡献率占99.40%，远大于皮肤接触途径。儿童经饮水摄入和皮肤接触两种途径的健康风险均显著高于成人，分别为成人的1.544倍和1.039倍。32.39%的采样点地下水硝酸盐对儿童的健康风险超出了可接受水平，14.79%的采样点地下水硝酸盐对成人的健康风险不可接受。甘州区城区、临泽县北部边缘及高台县城区周围硝酸盐浓度最高，这些区域内所有人群都面临硝酸盐引发的高健康风险，其余区域硝酸盐引发的健康风险相对较低。     

北京主城区伪基站时空规律分析

随着公众移动通信的快速发展,伪基站的泛滥不仅破坏正常电信秩序,危害公共安全,而且严重损害群众财产权益,侵犯公民个人隐私,已成为社会一大公害。如何从垃圾短信大数据中挖掘出伪基站活动的时空规律,寻找有效的防控方案,从源头上进行打击和治理成为管理部门和研究者共同关注的焦点。本文基于北京市垃圾短信数据,利用非负矩阵分解的方法分析伪基站的时空分布规律;并利用TF-IDF构建垃圾短信分类模型,对垃圾短信进行分类,结合土地利用数据,分析伪基站在发送不同类型垃圾短信时的时空分布规律。结果显示：北京市垃圾短信多分布于路网和中心城区;白天垃圾短信数量远远多于晚上;垃圾短信的分布随时间的推移沿着路网逐渐向内收缩;发送不同类型垃圾短信的伪基站的时空分布具有一定的差异;通过非负矩阵分解得到的结果,与垃圾短信分类后得到的结果有很好的匹配。研究表明,非负矩阵分解具有实现上的简便性、分解形式和分解结果上的可解释性等优点,可以有针对性的为有关部门建言打击伪基站的有效方案,对于伪基站违法行为的治理具有一定的意义。     

Estimating the properties of weathered bedrock and pilerock interaction from the geological strength index

The effect of variable rock mass properties on pile-rock interaction poses a great challenge to the design of stabilizing piles and numerical analysis of pile-rock interaction. The paper presents a novel method to estimate the properties of weathered bedrock, which can be applied to routine design of landslide-stabilizing piles for collivial landslides. The Ercengyan landslide located in the Three Gorges Reservoir, China, is the area of interest for this study. A geological investigation and triaxial tests were conducted to estimate the basic parameters, including Geological Strength Index(GSI), uniaxial compressive strength σ_(ci) and Hoek-Brown constant m_i of intact bedrock in the study area. Hoek-Brown criterion was used to estimate mechanical properties of the weathered rock, including elastic modulus E_m, cohesion c, friction angle Φ, and normal ultimate lateral resistance p_(max). A parametric study was performed to evaluate the effect of parameterizations of GSI, σ_(ci) and m_i on the bedrock properties and p-y curves. The estimated rock mass properties were used with PLAXIS 2D software to simulate pile-rock interaction. Effect of GSI on stress at the pile-rock interface and in the rock, pile bending moment, pile shear force, and p-y curve were analysed.     

Implementation of a coupled plastic damage distinct lattice spring model for dynamic crack propagation in geomaterials

This paper studies dynamic crack propagation by employing the distinct lattice spring model (DLSM) and 3‐dimensional (3D) printing technique. A damage‐plasticity model was developed and implemented in a 2D DLSM. Applicability of the damage‐plasticity DLSM was verified against analytical elastic solutions and experimental results for crack propagation. As a physical analogy, dynamic fracturing tests were conducted on 3D printed specimens using the split Hopkinson pressure bar. The dynamic stress intensity factors were recorded, and crack paths were captured by a high‐speed camera. A parametric study was conducted to find the influences of the parameters on cracking behaviors, including initial and peak fracture toughness, crack speed, and crack patterns. Finally, selection of parameters for the damage‐plasticity model was determined through the comparison of numerical predictions and the experimentally observed cracking features.     

铜藻(Sargassum horneri)在营养限制胁迫后对NH4-N的超补偿吸收研究

以经济马尾藻铜藻(Sargassum horneri)为研究材料,研究了其在营养限制胁迫后对NH_4-N的超补偿吸收情况。实验分营养限制和恢复营养两个阶段进行,每个阶段均设置饥饿处理组、饱和处理组和正常对照组。铜藻在低营养限制胁迫(饥饿)下培养10天后,恢复营养盐培养3天,分别采用次溴酸盐氧化法和锌镉还原法测定培养液中的NH_4-N和NO_3-N的浓度。本文研究发现,饥饿处理组中铜藻吸收氨氮的速率远高于正常对照组和饱和处理组,在恢复培养第一天时,饥饿处理组对NH_4-N的吸收速率最高为14.94μmol/(g·h),与正常对照组及饱和处理组间差异显著。在恢复培养的后两天,三个处理组中铜藻对NH_4-N的吸收速率差异慢慢变小,直至最后几乎相同。三组对NO_3-N没有表现出较高的吸收,最高仅为6.15μmol/(g·h),结果表明:氮源包括NH_4-N和NO_3-N时,铜藻优先选择吸收NH_4-N。实验后称重测定生长速率:对照组、饥饿处理组和饱和组生长率(SGR)分别为8.48%、8.86%、8.01%,ANOVA方差分析表明,三者存在显著差异(P=0.0320.05),从而证实了铜藻也存在超补偿生长的现象。     

Assessment of alternative adsorption models and global sensitivity analysis to characterize hexavalent chromium loss from soil to surface runoff

We investigate our ability to assess transfer of hexavalent chromium, Cr(VI), from the soil to surface runoff by considering the effect of coupling diverse adsorption models with a two‐layer solute transfer model. Our analyses are grounded on a set of two experiments associated with soils characterized by diverse particle size distributions. Our study is motivated by the observation that Cr(VI) is receiving much attention for the assessment of environmental risks due to its high solubility, mobility, and toxicological significance. Adsorption of Cr(VI) is considered to be at equilibrium in the mixing layer under our experimental conditions. Four adsorption models, that is, the Langmuir, Freundlich, Temkin, and linear models, constitute our set of alternative (competing) mathematical formulations. Experimental results reveal that the soil samples characterized by the finest grain sizes are associated with the highest release of Cr(VI) to runoff. We compare the relative abilities of the four models to interpret experimental results through maximum likelihood model calibration and four model identification criteria (i.e., the Akaike information criteria [AIC and AIC_C] and the Bayesian and Kashyap information criteria). Our study results enable us to rank the tested models on the basis of a set of posterior weights assigned to each of them. A classical variance‐based global sensitivity analysis is then performed to assess the relative importance of the uncertain parameters associated with each of the models considered, within subregions of the parameter space. In this context, the modelling strategy resulting from coupling the Langmuir isotherm with a two‐layer solute transfer model is then evaluated as the most skilful for the overall interpretation of both sets of experiments. Our results document that (a) the depth of the mixing layer is the most influential factor for all models tested, with the exception of the Freundlich isotherm, and (b) the total sensitivity of the adsorption parameters varies in time, with a trend to increase as time progresses for all of the models. These results suggest that adsorption has a significant effect on the uncertainty associated with the release of Cr(VI) from the soil to the surface runoff component.     

Area usage estimation and spatiotemporal variability in distribution patterns of southern right whales,Eubalaena australis,of southern Brazil

Southern right whales—Eubalaena australis (Desmoulins, 1822)—migrate seasonally from high‐latitude feeding grounds to coastal breeding and calving grounds at lower latitudes such as the southern coast of Brazil. Understanding how these whales are distributed along the coast is important for monitoring their postwhaling recovery and defining management strategies. In this study, we applied Kernel density estimators to aerial survey data to determine main occurrence and concentration areas of right whales in southern Brazil and investigate inter‐ and intra‐annual distribution patterns between 2003 and 2012. Our results show considerable variation in area usage within and among years, and changes in the general distribution pattern of right whales in the last years of the study. Intra‐annually, higher concentration area tended to expand from July to September and decrease in November. Some areas stood out as high‐density areas for right whales: Ribanceira/Ibiraquera, Itapirubá Sul/Sol, and from Arroio to Gaivota. Some evidences also suggest preferential areas for mother–calf pairs. The higher concentration area of right whales in southern Brazil was estimated at 52,541 km² and the occurrence area was 682.69 km², which is the whole study area. As right whale distribution in the region is likely expanding due to this population's current recovery, our study provides essential information for management plan of the Right Whale Environmental Protection Area.