Carbon dioxide on the satellites of Saturn: Results from the Cassini VIMS investigation and revisions to the VIMS wavelength scale

Several of the icy satellites of Saturn show the spectroscopic signature of the asymmetric stretching mode of C-O in carbon dioxide (CO₂) at or near the nominal solid-phase laboratory wavelength of 4.2675 μm (2343.3 cm⁻¹), discovered with the Visible-Infrared Mapping Spectrometer (VIMS) on the Cassini spacecraft. We report here on an analysis of the variation in wavelength and width of the CO₂ absorption band in the spectra of Phoebe, Iapetus, Hyperion, and Dione. Comparisons are made to laboratory spectra of pure CO₂, CO₂ clathrates, ternary mixtures of CO₂ with other volatiles, implanted and adsorbed CO₂ in non-volatile materials, and ab initio theoretical calculations of CO₂ * nH₂O. At the wavelength resolution of VIMS, the CO₂ on Phoebe is indistinguishable from pure CO₂ ice (each molecule’s nearby neighbors are also CO₂) or type II clathrate of CO₂ in H₂O. In contrast, the CO₂ band on Iapetus, Hyperion, and Dione is shifted to shorter wavelengths (typically ∼4.255 μm (∼2350.2 cm⁻¹)) and broadened. These wavelengths are characteristic of complexes of CO₂ with different near-neighbor molecules that are encountered in other volatile mixtures such as with H₂O and CH₃OH, and non-volatile host materials like silicates, some clays, and zeolites. We suggest that Phoebe’s CO₂ is native to the body as part of the initial inventory of condensates and now exposed on the surface, while CO₂ on the other three satellites results at least in part from particle or UV irradiation of native H₂O plus a source of C, implantation or accretion from external sources, or redistribution of native CO₂ from the interior.The analysis presented here depends on an accurate VIMS wavelength scale. In preparation for this work, the baseline wavelength calibration for the Cassini VIMS was found to be distorted around 4.3 μm, apparently as a consequence of telluric CO₂ gas absorption in the pre-launch calibration. The effect can be reproduced by convolving a sequence of model detector response profiles with a deep atmospheric CO₂ absorption profile, producing distorted detector profile shapes and shifted central positions. In a laboratory blackbody spectrum used for radiance calibration, close examination of the CO₂ absorption profile shows a similar deviation from that expected from a model. These modeled effects appear to be sufficient to explain the distortion in the existing wavelength calibration now in use. A modification to the wavelength calibration for 13 adjacent bands is provided. The affected channels span about 0.2 μm centered on 4.28 μm. The maximum wavelength change is about 10 nm toward longer wavelength. This adjustment has implications for interpretation of some of the spectral features observed in the affected wavelength interval, such as from CO₂, as discussed in this paper.     

Characterization of Titan’s Ontario Lacus region from Cassini/VIMS observations

Liquid hydrocarbons were long predicted on Titan’s surface before the RADAR instrument onboard Cassini detected lakes poleward of 70°N in July 2006. Before that the Cassini Imaging Science Subsystem (ISS) observed a lake-like feature in the South Pole, named Ontario Lacus, in July 2004. Here we analyze one observation of Ontario Lacus taken by the Visual and Infrared Mapping Spectrometer (VIMS) on 2007 December 5, during the T 38 flyby. This is the best spatially resolved image of a Titan lake to date by an imaging spectrometer, and has been previously reported in Brown et al. (Brown, R.H., Soderblom, L.A., Soderblom, J.M., Clark, R.N., Jaumann, R., Barnes, J.W., Sotin, C., Buratti, B., Baines, K.H., Nicholson, P.D. [2008]. Nature 454, 607–610) and in Barnes et al. (Barnes, J.W. et al. [2009]. Icarus 201, 217–225). The observing geometry and our data processing will be explained, followed by a discussion of the main characteristics of the image. The analyzed image covers a small portion of Ontario Lacus and shows what appears from RADAR data to be a region of modest slope (“ramp”) adjacent to the dark lake itself. Our analysis of 5.0 μm spectral data suggests that the previously reported absorption feature of ethane seen at shorter wavelengths may be produced by damp sediments adjacent to the main liquid basin. The latter appears to be absorbing all of the photons incident upon it in the 5 μm spectral region and shows no discernible absorption features. A characterization of the basin composition and morphology is developed with the help of ISS and RADAR observations. The simplest model consistent with the data is an optically deep lake surrounded by a region in which ethane, propane, possibly methane, and other, less volatile hydrocarbons and nitriles are present mixed into spectroscopically neutral sediments. The dominance of relatively low vapor pressure organics outside the lake itself suggests a retreat of Ontario Lacus associated with evaporation on seasonal or longer timescales, consistent with analysis of RADAR and ISS images.     

Correlations between VIMS and RADAR data over the surface of Titan: Implications for Titan’s surface properties

We apply a multivariate statistical method to Titan data acquired by different instruments onboard the Cassini spacecraft. We have searched through Cassini/VIMS hyperspectral cubes, selecting those data with convenient viewing geometry and that overlap with Cassini/RADAR scatterometry footprints with a comparable spatial resolution. We look for correlations between the infrared and microwave ranges the two instruments cover. Where found, the normalized backscatter cross-section obtained from the scatterometer measurement, corrected for incidence angle, and the calibrated antenna temperature measured along with the scatterometry echoes, are combined with the infrared reflectances, with estimated errors, to produce an aggregate data set, that we process using a multivariate classification method to identify homogeneous taxonomic units in the multivariate space of the samples.In medium resolution data (from 20 to 100 km/pixel), sampling relatively large portions of the satellite’s surface, we find regional geophysical units matching both the major dark and bright features seen in the optical mosaic. Given the VIMS cubes and RADAR scatterometer passes considered in this work, the largest homogeneous type is associated with the dark equatorial basins, showing similar characteristics as each other on the basis of all the considered parameters.On the other hand, the major bright features seen in these data generally do not show the same characteristics as each other. Xanadu, the largest continental feature, is as bright as the other equatorial bright features, while showing the highest backscattering coefficient of the entire satellite. Tsegihi is very bright at 5 μm but it shows a low backscattering coefficient, so it could have a low roughness on a regional scale and/or a different composition. Another well-defined region, located southwest of Xanadu beyond the Tui Regio, seems to be detached from the surrounding terrains, being bright at 2.69, 2.78 and 5 μm but having a low radar brightness. In this way, other units can be found that show correlations or anti-correlations between the scatterometric response and the spectrophotometric behavior, not evident from the optical remote sensing data.     

The light curve of asteroid 2867 Steins measured by VIRTIS-M during the Rosetta fly-by

On 5 September 2008, the Rosetta spacecraft encountered the asteroid 2867 Steins on its way to the comet 67P/Churyumov-Gerasimenko. This was the first of two planned asteroid fly-bys performed by the probe, the second fly-by being with the much larger asteroid 21 Lutetia in July 2010. The VIRTIS imaging spectrometer (IFOV 0.250 mrad, overall spectral range 0.25-5.1 μm) onboard Rosetta acquired data of Steins already before the closest approach phase, when the target was spatially unresolved, in order to obtain a light curve of the asteroid in the infrared spectral range extending up to 5 μm, that was never explored before. The VIRTIS light curve campaign started at 11:30 UTC onboard time, when the spacecraft was about 221,377 km away from the target, and ended at 17:58 UTC, at a distance of 20,741 km away from Steins. During this timeframe, the solar phase angle of the asteroid was roughly constant, ranging from 38.2° to 36.3°.Assuming the most recent value derived for the rotational period of Steins (Lamy et al., 2008), the VIRTIS observations covered slightly more than one rotation of the asteroid. In this interval, VIRTIS collected 8 hyperspectral cubes where Steins was captured 119 times, both in the visual and in the infrared range. Given the low signal and the unresolved appearance of the source, for which the instrument was not designed, only a small subset of wavelengths turned out to be suitable to sample the light curve. Nevertheless, in both the VIS and NIR ranges we find a similar trend, with two different maxima and minima during one rotational period, and amplitudes consistent with the results in the visual range obtained in previous works, including the data set acquired by the OSIRIS camera onboard Rosetta. We also report the presence of a new broad feature centered at approximately 0.81-0.82 μm, which is seen in the visual data throughout the rotation of the asteroid.     

The visible and near infrared module of EChO

The Visible and Near Infrared (VNIR) is one of the modules of EChO, the Exoplanets Characterization Observatory proposed to ESA for an M-class mission. EChO is aimed to observe planets while transiting by their suns. Then the instrument had to be designed to assure a high efficiency over the whole spectral range. In fact, it has to be able to observe stars with an apparent magnitude M_v?=?9–12 and to see contrasts of the order of 10^?4–10^?5 necessary to reveal the characteristics of the atmospheres of the exoplanets under investigation. VNIR is a spectrometer in a cross-dispersed configuration, covering the 0.4–2.5 μm spectral range with a resolving power of about 330 and a field of view of 2 arcsec. It is functionally split into two channels respectively working in the 0.4–1.0 μm and 1.0–2.5 μm spectral ranges. Such a solution is imposed by the fact the light at short wavelengths has to be shared with the EChO Fine Guiding System (FGS) devoted to the pointing of the stars under observation. The spectrometer makes use of a HgCdTe detector of 512 by 512 pixels, 18 μm pitch and working at a temperature of 45 K as the entire VNIR optical bench. The instrument has been interfaced to the telescope optics by two optical fibers, one per channel, to assure an easier coupling and an easier colocation of the instrument inside the EChO optical bench.     

Interpretation of combined infrared,submillimeter, and millimeter thermal flux data obtained during the Rosetta fly-by of Asteroid (21) Lutetia

The European Space Agency’s Rosetta spacecraft is the first Solar System mission to include instrumentation capable of measuring planetary thermal fluxes at both near-IR (VIRTIS) and submillimeter–millimeter (smm–mm, MIRO) wavelengths. Its primary mission is a 1 year reconnaissance of Comet 67P/Churyumov–Gerasimenko beginning in 2014. During a 2010 close fly-by of Asteroid 21 Lutetia, the VIRTIS and MIRO instruments provided complementary data that have been analyzed to produce a consistent model of Lutetia’s surface layer thermal and electrical properties, including a physical model of self-heating. VIRTIS dayside measurements provided highly resolved 1 K accuracy surface temperatures that required a low thermal inertia, I < 30 J/(K m² s^0.5). MIRO smm and mm measurements of polar night thermal fluxes produced constraints on Lutetia’s subsurface thermal properties to depths comparable to the seasonal thermal wave, yielding a model of I < 20 J/(K m² s^0.5) in the upper few centimeters, increasing with depth in a manner very similar to that of Earth’s Moon. Subsequent MIRO-based model predictions of the dayside surface temperatures reveal negative offsets of ～5–30 K from the higher VIRTIS-measurements. By adding surface roughness in the form of 50% fractional coverage of hemispherical mini-craters to the MIRO-based thermal model, sufficient self-heating is produced to largely remove the offsets relative to the VIRTIS measurements and also reproduce the thermal limb brightening features (relative to a smooth surface model) seen by VIRTIS. The Lutetia physical property constraints provided by the VIRTIS and MIRO data sets demonstrate the unique diagnostic capabilities of combined infrared and submillimeter/millimeter thermal flux measurements.     

Distribution of icy particles across Enceladus' surface as derived from Cassini-VIMS measurements

The surface of Enceladus consists almost completely of water ice. As the band depths of water ice absorptions are sensitive to the size of particles, absorptions can be used to map variations of icy particles across the surface. The Visual and Infrared Mapping Spectrometer (VIMS) observed Enceladus with a high spatial resolution during three Cassini flybys in 2005 (orbits EN 003, EN 004 and EN 011). Based on these data we measured the band depths of water ice absorptions at 1.04, 1.25, 1.5, and 2 μm. These band depths were compared to water ice models that represent theoretically calculated reflectance spectra for a range of particle diameters between 2 μm and 1 mm. The agreement between the experimental (VIMS) and model values supports the assumption that pure water ice characterizes the surface of Enceladus and therefore that variations in band depth correspond to variations in water ice particle diameters. Our measurements show that the particle diameter of water ice increases toward younger tectonically altered surface units with the largest particles exposed in relatively “fresh” surface material. The smallest particles were generally found in old densely cratered terrains. The largest particles (∼0.2 mm) are concentrated in the so called “tiger stripes” at the south pole. In general, the particle diameters are strongly correlated with geologic features and surface ages, indicating a stratigraphic evolution of the surface that is caused by cryovolcanic resurfacing and impact gardening.     

Saturn Satellites as Seen by Cassini Mission

In this paper we will summarize some of the most important results of the Cassini mission concerning the satellites of Saturn. The Cassini Mission was launched in October 1997 on a Titan IV-Centaur rocket from Cape Canaveral. Cassini mission was always at risk of cancelation during its development but was saved many times thanks to the great international involvement. The Cassini mission is in fact a NASA-ESA-ASI project. The main effort was made by NASA, which provided the launch facilities, the integration and several instruments; ESA provided the Huygens probe while ASI some of the key elements of the mission such as the high-gain antenna, most of the radio system and important instruments of the Orbiter, such as the Cassini Radar and the visual channel of the VIMS experiment. ASI contributed also to the development of HASI experiment on Huygens probe. The Cassini mission was the first case in which the Italian planetology community was directly involved, developing state of the art hardware for a NASA mission. Given the long duration of the mission, the complexity of the payload onboard the Cassini Orbiter and the amount of data gathered on the satellites of Saturn, it would be impossible to describe all the new discoveries made, therefore we will describe only some selected, paramount examples showing how Cassini’s data confirmed and extended ground-based observations. In particular we will describe the achievements obtained for the satellites Phoebe, Enceladus and Titan. We will also put these examples in the perspective of the overall evolution of the system, stressing out why the selected satellites are representative of the overall evolution of the Saturn system. Cassini is also an example of how powerful could be the coordination between ground-based and space observations. In fact coordinated ground-based observations of Titan were performed at the time of Huygens atmospheric probe mission at Titan on 14 January 2005, connecting the in situ observations by the probe with the general view provided by ground-based measurements. Different telescopes operating at different wavelengths were used, including radio telescopes (up to 17-tracking of the Huygens signal at 2040 MHz), eight large optical observatories studying the atmosphere and surface of Titan, and high-resolution infrared spectroscopy used to observe radiation emitted during the Huygens Probe entry (Witasse et al. J. Geophys. Res. 111:E07S01, 2006).     

Saturn's icy satellites investigated by Cassini-VIMS: I. Full-disk properties: 350-5100 nm reflectance spectra and phase curves

Saturn's icy satellites are among the main scientific objectives of the Cassini-VIMS (Visual and Infrared Mapping Spectrometer) experiment. This paper contains a first systematic and comparative analysis of the full-disk spectral properties of Dione, Enceladus, Epimetheus, Hyperion, Iapetus, Mimas, Phoebe, Rhea and Tethys as observed by VIMS from July 2004 to June 2005. The disk integrated properties (350-5100 nm reflectance spectra and phase curves at 550-2232 nm) and images of satellites are reported and discussed in detail together with the observed geometry. In general, the spectra in the visible spectral range are almost featureless and can be classified according to the spectral slopes: from the bluish Enceladus and Phoebe to the redder Iapetus, Hyperion and Epimetheus. In the 1000-1300 nm range the spectra of Enceladus, Tethys, Mimas and Rhea are characterized by a negative slope, consistent with a surface largely dominated by water ice, while the spectra of Iapetus, Hyperion and Phoebe show a considerable reddening pointing out the relevant role played by darkening materials present on the surface. In between these two classes are Dione and Epimetheus, which have a flat spectrum in this range. The main absorption bands identified in the infrared are the 1520, 2020, 3000 nm H₂O/OH bands (for all satellites), although Iapetus dark terrains show mostly a deep 3000 nm band while the 1520 and 2020 nm bands are very faint. In this spectral range, the Iapetus spectrum is characterized by a strong reddening. The CO₂ band at 4260 nm and the Fresnel ice peak around 3100 nm are evident only on Hyperion, Phoebe and Iapetus. The phase curves at 550 and at 2232 nm are reported for all the available observations in the 0°-144° range; Rhea shows an opposition surge at visible wavelengths in the 0.5°-1.17° interval. The improvement on the retrieval of the full-disk reflectance spectra can be appreciated by a direct comparison with ground-based telescopic data available from literature. Finally, data processing strategies and recent upgrades introduced in the VIMS-V calibration pipeline (flat-field and destriping-despiking algorithm) are discussed in appendices.     

Composition of Titan''s surface from Cassini VIMS

Titan's bulk density along with Solar System formation models indicates considerable water as well as silicates as its major constituents. This satellite's dense atmosphere of nitrogen with methane is unique. Deposits or even oceans of organic compounds have been suggested to exist on Titan's solid surface due to UV-induced photochemistry in the atmosphere. Thus, the composition of the surface is a major piece of evidence needed to determine Titan's history. However, studies of the surface are hindered by the thick, absorbing, hazy and in some places cloudy atmosphere. Ground-based telescope investigations of the integral disk of Titan attempted to observe the surface albedo in spectral windows between methane absorptions by calculating and removing the haze effects. Their results were reported to be consistent with water ice on the surface that is contaminated with a small amount of dark material, perhaps organic material like tholin. We analyze here the recent Cassini Mission's visual and infrared mapping spectrometer (VIMS) observations that resolve regions on Titan. VIMS is able to see surface features and shows that there are spectral and therefore likely compositional units. By several methods, spectral albedo estimates within methane absorption windows between 0.75 and 5 μm were obtained for different surface units using VIMS image cubes from the Cassini-Huygens Titan T_a encounter. Of the spots studied, there appears to be two compositional classes present that are associated with the lower albedo and the higher albedo materials, with some variety among the brighter regions. These were compared with spectra of several different candidate materials. Our results show that the spectrum of water ice contaminated with a darker material matches the reflectance of the lower albedo Titan regions if the spectral slope from 2.71 to 2.79 μm in the poorly understood 2.8-μm methane window is ignored. The spectra for brighter regions are not matched by the spectrum of water ice or unoxidized tholin, in pure form or in mixtures with sufficient ice or tholin present to allow the water ice or tholin spectral features to be discerned. We find that the 2.8-μm methane absorption window is complex and seems to consist of two weak subwindows at 2.7 and 2.8 μm that have unknown opacities. A ratio image at these two wavelengths reveals an anomalous region on Titan that has a reflectance unlike any material so far identified, but it is unclear how much the reflectances in these two subwindows pertain to the surface.