What makes a planet habitable?

This work reviews factors which are important for the evolution of habitable Earth-like planets such as the effects of the host star dependent radiation and particle fluxes on the evolution of atmospheres and initial water inventories. We discuss the geodynamical and geophysical environments which are necessary for planets where plate tectonics remain active over geological time scales and for planets which evolve to one-plate planets. The discoveries of methane–ethane surface lakes on Saturn’s large moon Titan, subsurface water oceans or reservoirs inside the moons of Solar System gas giants such as Europa, Ganymede, Titan and Enceladus and more than 335 exoplanets, indicate that the classical definition of the habitable zone concept neglects more exotic habitats and may fail to be adequate for stars which are different from our Sun. A classification of four habitat types is proposed. Class I habitats represent bodies on which stellar and geophysical conditions allow Earth-analog planets to evolve so that complex multi-cellular life forms may originate. Class II habitats includes bodies on which life may evolve but due to stellar and geophysical conditions that are different from the class I habitats, the planets rather evolve toward Venus- or Mars-type worlds where complex life-forms may not develop. Class III habitats are planetary bodies where subsurface water oceans exist which interact directly with a silicate-rich core, while class IV habitats have liquid water layers between two ice layers, or liquids above ice. Furthermore, we discuss from the present viewpoint how life may have originated on early Earth, the possibilities that life may evolve on such Earth-like bodies and how future space missions may discover manifestations of extraterrestrial life.     

On the identification of the C60+ interstellar features

The identity of the carriers of the diffuse interstellar bands (DIBs) is one of the most fascinating puzzles of modern spectroscopy. Over the last few years the number of known DIBs has grown substantially. In this paper we discuss the two recently discovered near-infrared weak interstellar features which have already been proposed as fingerprints of the buckminsterfullerene We present and discuss measurements of the two related DIBs within a larger sample of reddened targets, observed with different spectrometers, telescopes and site conditions. We provide additional arguments in favour of the interstellar origin of the two bands. We find evidence around the 9577-Å DIB of far-wing structures, which may affect broad-band measurements. We estimate corrections and errors for telluric and stellar blends, and show that the cores of the two DIBs are well correlated with a ratio near unity within 20 per cent. Finally, we discuss their relation to the laboratory spectra of and the search for two expected weaker transitions.     

Detection and characterization of oxidizing acids in the Atacama Desert using the Mars Oxidation Instrument

We have performed field experiments to further develop and validate the Mars Oxidation Instrument (MOI) as well as measurement strategies for the in situ characterization of oxidation mechanisms, kinetics, and carbon cycling on Mars. Using the Atacama Desert as a test site for the current dry conditions on Mars, we characterized the chemical reactivity of surface and near-surface atmosphere in the dry core of the Atacama. MOI is a chemiresistor-based sensor array that measures the reaction rates of chemical films that are sensitive to particular types of oxidants or that mimic chemical characteristics of pre-biotic and biotic materials. With these sensors, the chemical reactivity of a planetary environment is characterized by monitoring the resistance of the film as a function of time. Our instrumental approach correlates reaction rates with dust abundance, UV flux, humidity, and temperature, allowing discrimination between competing hypotheses of oxidant formation and organic decomposition. The sensor responses in the Atacama are consistent with an oxidative attack by strong acids triggered by dust accumulation, followed by transient wetting due to an increase in relative humidity during the night. We conclude that in the Atacama Desert, and perhaps on Mars, low pH resulting from acid accumulation, combined with limited water availability and high oxidation potential, can result in oxidizing acid reactions on dust and soil surfaces during low-moisture transient wetting events (i.e. thin films of water). These soil acids are expected to play a significant role in the oxidizing nature of the soils, the formation of mineral surface coatings, and the chemical modification of organics in the surface material.     

Chemical Processes in Cometary Comae

Recent developments in the chemical modelling of cometary comae aredescribed. We discuss the cyanide chemistry and present new HCNobservations of the recent comet C/2002 C1 (Ikeya–Zhang). Theconnection between interstellar and cometary organic molecules isdiscussed from the perspective of recent theories of interstellargas-grain chemistry.     

Analysis and survival of amino acids in Martian regolith analogs

Abstract— We have investigated the native amino acid composition of two analogs of Martian soil, JSC Mars‐1 and Salten Skov. A Mars simulation chamber has been built and used to expose samples of these analogs to temperature and lighting conditions similar to those found at low latitudes on the Martian surface. The effects of the simulated conditions have been examined using high‐performance liquid chromatography (HPLC). Exposure to energetic ultraviolet (UV) light in vacuum appears to cause a modest increase in the concentration of certain amino acids within the materials, which is interpreted as resulting from the degradation of microorganisms. The influence of low temperatures shows that the accretion of condensed water on the soils leads to the destruction of amino acids, supporting the idea that reactive chemical processes involving H₂O are at work within the Martian soil. We discuss the influence of UV radiation, low temperatures, and gaseous CO₂ on the intrinsic amino acid composition of Martian soil analogs and describe, with the help of a simple model, how these studies fit within the framework of life detection on Mars and the practical tasks of choosing and using Martian regolith analogs in planetary research.     

Organic astrochemistry: observations of interstellar ketene

We have observed emission from both ortho and para spin states of ketene (CH₂CO) towards several deeply-embedded protostars. The low CH₂CO fractional abundances (∼10⁻¹⁰) and the rotation temperatures (∼20 K) are consistent with emission from the cooler envelope. We compare our results with previous studies and discuss possible production pathways to interstellar ketene. We suggest that, if low observed excitation temperatures of CH₂CO, CH₃CHO and H₂CO are indicative of their absence from the hot core region, then this may be due to the extensive hydrogenation of pre-existing grain mantles prior to evaporation into the inner envelope, leading to lower abundances of these compounds and to mantles rich in alcohols.     

Amino acid composition,petrology, geochemistry, 14C terrestrial age and oxygen isotopes of the Shişr 033 CR chondrite

Abstract— We have analyzed Shi?r 033, a CR chondrite from the Omani desert, using several different analytical techniques designed to study the degree of terrestrial alteration of this meteorite and also its petrologic classification. Bulk chemical analyses (including organic carbon and mean total H₂O content) are consistent with a CR classification. Additionally, oxygen isotope analysis on a bulk sample indicates that Shi?r 033 is of type CR2. Amino acid analysis using liquid chromatography with UV fluorescence detection (HPLC‐FD) and liquid chromatography‐time of flight‐mass spectrometry (LC‐ToF‐MS) show that the absolute and the relative amino acid content of Shi?r 033 is distinct from other carbonaceous chondrites. Oxygen isotope analysis of a phyllosilicate‐rich dark inclusion shows that this inclusion is closer to CV3 or CO3 chondrites. The effects of terrestrial weathering in Shi?r 033 are evident from the dark inclusion carbon isotopic data, bulk chemistry (through the elevated concentrations of Sr and Ba), and amino acid data, which suggests extensive amino acid contamination of the meteorite from the fall site soil. Nevertheless, Shi?r 033 contains a small fraction of indigenous components, as indicated by the presence of the extraterrestrial amino acid α‐aminoisobutyric acid (AIB) that was not detected in the Shi?r soils. Finally, the terrestrial age of Shi?r 033 was determined and is discussed in the context of high levels of contamination.     

Simulating Martian regolith in the laboratory

Regolith and dust cover the surfaces of the Solar Systems solid bodies, and thus constitute the visible surface of these objects. The topmost layers also interact with space or the atmosphere in the case of Mars, Venus and Titan. Surface probes have been proposed, studied and flown to some of these worlds. Landers and some of the mechanisms they carry, e.g. sampling devices, drills and subsurface probes (“moles”) will interact with the porous surface layer. The absence of true extraterrestrial test materials in ample quantities restricts experiments to the use of soil or regolith analogue materials. Several standardized soil simulants have been developed and produced and are commonly used for a variety of laboratory experiments. In this paper we intend to give an overview of some of the most important soil simulants, and describe experiments (penetrometry, thermal conductivity, aeolian transport, goniometry, spectroscopy and exobiology) made in various European laboratory facilities.     

Evolution of Southern Star-Forming Regions

We present ISO observations of bright, high-mass southern starforming regions with the Short Wavelength Spectrometer (SWS) and Long Wavelength Spectrometer (LWS). The selected targets show a range of pre-main sequence evolutionary phases. Whereas some objects still show interstellar ice features, the most evolved objects are coincident with ultra-compact HII regions and show strong emission lines from atomic species and polycyclic aromatic hydrocarbons (PAHs). We discuss the ISO spectra between 2.5 - 200 μm of selected southern star-forming regions in the context of their evolution. This revised version was published online in August 2006 with corrections to the Cover Date.     

New strategies to detect life on Mars

If we are to find unequivocal evidence for life on Mars, we will need new ways to search for it. Jeff L Bada and the MOD team describe the innovative strategy developed for the ExoMars mission.