Hydrated sulphuric acid in dense molecular clouds

We consider sulphur depletion in dense molecular clouds, and suggest hydrated sulphuric acid, H₂SO₄ ·  n H₂O, as a component of interstellar dust in icy mantles. We discuss the formation of hydrated sulphuric acid in collapsing clouds and its instability in heated regions in terms of the existing hot core models and observations. We also show that some features of the infrared spectrum of hydrated sulphuric acid have correspondence in the observed spectra of young stellar objects.     

The Asiago Extrasolar Planet Transit Search

RATS is an Italian project devoted to Hot Jupiter search with the transit method. A planet transiting in front of a host star can be mimed by several, and well defined, astrophysical phenomena (Brown, 2003). In order to recognize these false alarms we can utilize a preventive strategy to limit false alarm rates and a spectroscopic follow up to refuse no transit candidates. As preventive strategy it is important to develop an accurate target field selection, with well defined requisites, in order to maximize the solar type star numbers and to minimize the risk of possible astrophysical false alarms.     

Near-infrared spectroscopy of dark asteroids

Near-infrared (J, H and K bands) spectra of nine dark asteroids (chosen among a sample of supposed primitive objects between C and D classes) have been obtained at the Mauna Kea Observatory (Hawaii) with the 2.2-m telescope using KSPEC as spectrograph. The aim of this work was to search for evidence of the presence of organic materials in these objects as found in other planetary bodies as 5145 Pholus, and in some cometary nuclei. A careful analysis of the data has revealed flat or slightly redder spectra than the solar one for all observed asteroids. No evidence of distinct absorption features was found.     

A Block-Based Theoretical Model Suited to Gravitational Sliding

An original theoretical model has been devised to simulate mass flow over hill slopes due to gravitational sliding. The sliding mass is discretized into a sequence of contiguous blocks which are subjected to gravitational forces, to bottom friction and to surface resistance stresses that are generally negligible for subaerial flows, but are relevant for submarine slides. The blocks interact with each other while sliding down the hill flanks because of internal forces that dissipate mechanical energy and produce a momentum exchange between the individual blocks, yet conserving the total momentum of the mass. Internal forces are expressed in terms of interaction coefficients depending on the instantaneous distance between the block centers of mass, which is a measure of the deformation experienced by the blocks: the functional dependence includes three parameters, namely the interaction intensity ¯, the deformability parameter and the shape parameter , by means of which a wide range of interaction types can be fully accounted for. The time integration is performed numerically by solving the equations for the block velocities and positions at any time ti by means of the block accelerations at the previous time t_i-1, and by subsequently updating the block accelerations, which allows to proceed iteratively to the following times. The model has been tested against laboratory results available from literature and by means of several numerical experiments involving a simplified geometry both for the sliding body and the basal surface, with the purpose of clarifying the influence of the model parameters on the slide dynamics. The model improves the performance of the existing kinematic models for slides, moreover preserving an equivalent numerical simplicity. Future applications and possible improvements of this model are suggested.     

Hydrogeology of thermal waters in Viterbo area, central Italy

A conceptual hydrogeological model of the Viterbo thermal area (central Italy) has been developed. Though numerous studies have been conducted on its geological, geochemical and geothermal features, there is no generalized picture defining the origin and yield of the hydrothermal system. These latter aspects have therefore become the objectives of this research, which is based on new hydrogeological and geochemical investigations. The geological setting results in the coexistence of overlapped interacting aquifers. The shallow volcanic aquifer, characterized by fresh waters, is fed from the area around the Cimini Mountains and is limited at its base by the semiconfining marly-calcareous-arenaceous complex and low-permeability clays. To the west of Viterbo, vertical upflows of thermal waters of the sulphate-chloride-alkaline-earth type with higher gas contents, are due to the locally uplifted carbonate reservoir, the reduced thickness of the semiconfining layer and the high local geothermal gradient. The hot waters (30–60°C) are the result of deep circulation within the carbonate rocks (0.5–1.8 km) and have the same recharge area as the volcanic aquifer. The upward flow in the Viterbo thermal area is at least 0.1 m³/s. This flow feeds springs and deep wells, also recharging the volcanic aquifer from below.     

Use of the Sr/Sr isotopic ratio as an environmental tracer: an example of the application to the Fossil Forest of the Dunarobba (FFD) sedimentary system near Aviglano Umbro (Terni—Central Italy)

A recent discovery of Pliocene tree trunks (Taxodium, Glyptostrobus or Sequoia) perfectly preserved in the fluvial lacustrine sediments deposited in the old Tiberin Lake (near the town of Dunarobba, Central Italy) has led to the study of the conditions responsible for the trunks preservation. The present work has applied Sr isotope techniques to examine and confirm fluid migration in the different sediment types which cross the entire fluvial-lacustrine sequence. Based on the ⁸⁷Sr/⁸⁶Sr ratios measured in carbonate and in silicate fractions of samples collected from a bore hole (from 0 to 120 m) it is concluded that each sedimentary level has limited communication between zones and is characterised by different isotope values. This suggests that the intrinsic properties of these clays make them a good material for isolating waste, both for direct use and for a better buffer in other formations, possibly less secure, such as salt or granite. The results obtained in the present work have demonstrated some of the potential uses of the ⁸⁷Sr/⁸⁶Sr isotopic ratio as an environmental tracer for confirming results from some of the geotechnical (such as permeability) and geochemical parameters of these host sediments.     

Modelling nitrogen and oxygen isotope fractionation during denitrification in a lacustrine redox-transition zone

The stable isotope composition (δ¹⁵N and δ¹⁸O) of nitrate was measured during Summer 1999 in the anaerobic hypolimnion of eutrophic Lake Lugano (Switzerland). Denitrification was demonstrated by a progressive nitrate depletion coupled to increasing δ¹⁵N and δ¹⁸O values for residual nitrate. Maximum δ¹⁵N and δ¹⁸O values amounted to 27.2 and 15.7‰, respectively.¹⁵N and ¹⁸O enrichment factors for denitrification (ε) were estimated using a closed-system model and a dynamic diffusion-reaction model. Using the Rayleigh equation (closed-system approach), we obtained ε values of −11.2 and −6.6‰ for nitrogen and oxygen, respectively. The average ε values derived using the diffusion-reaction model were determined to be −20.7 ± 3.8 for nitrogen and −11.0 ± 1.7 for oxygen. Both N and O isotope fractionation appeared to be lower when denitrification rates where high, possibly in association with high organic carbon availability. In addition, variations in the isotope effects may be attributed to the variable importance of sedimentary denitrification having only a small isotope effect on the water column. The combined measurement of N and O isotope ratios in nitrate revealed that coupled nitrification-denitrification in the open-water was of minor importance. This is the first study of nitrogen and oxygen isotope effects associated with microbial denitrification in a natural lake. Moreover, this study confirms the high potential of δ¹⁸O of nitrate as a valuable biogeochemical tracer in aquatic systems, complementing nitrate δ¹⁵N.     

Hydrodynamic and isotopic investigations for evaluating the mechanisms and amount of groundwater seepage through a rockslide dam

This study addresses the influence of landslide dams on surface water drainage and groundwater flow. In the study area of Scanno Lake and Sagittario River (Central Italy), a limestone rockslide‐avalanche formed a lake, which has an outlet that is occasionally active, showing infiltration into the rockslide dam. Several springs are present at the lake's base and are partly fed by seepage through the rockslide debris. Piezometric surveys, discharge measurements, pumping tests and chemical analyses are tools used to build a conceptual model of the groundwater flow and to evaluate the flow through the rockslide debris. Seasonal water isotopic signatures validate the assumed model, showing a mixing of infiltration recharge and groundwater seepage throughout the rockslide debris. Various recharge areas have been found for springs, pointing out those directly fed by the rockslide debris aquifer. Hypotheses about seasonal groundwater mixing between the regional carbonate aquifer and the rockslide debris aquifer are supported by isotope results. Seasonal changes in groundwater table level due to recharge and surface losses from seasonal outlet have been correlated with isotopic groundwater composition from the rockslide debris aquifer and the downstream springs; this relationship highlights the role of the rockslide dam body on the hydrodynamics of the studied area. Relationships between surface waters and groundwater in the area have been completely understood on the basis of water isotopic fingerprinting, finally obtaining a complete evaluation of groundwater renewable resources and its regimen. Copyright © 2010 John Wiley & Sons, Ltd.     

The evaporitic celestite-barite deposits of Neuquen,Argentina

Celestite-barite occurrences of early Cretaceous age were studied in the Extra-Andean region of Neuquén, West central Argentina. The ores are located in a Subandean Mesozoic belt and show a conspicuous stratabound character related to evaporitic facies. The study of the geologic evolution of the sedimentary sequence allows prediction of the temporal and spatial setting of the evaporitic facies. Stratigraphy is the main geologic control for the celestite-barite ores and their areal distribution depends on the structure of the region. Based on the geometry and texture of the mineralization three types of ores have been recognized: 1) celestite beds syngenetic with the evaporitic facies; 2) epigenetic stratabound ores formed by "in situ" mobilization of celestite with stalactite growth and cavity infilling; 3) epigenetic vein-type ores formed by mobilized barium enriched solutions.Lithofacies and isotopic ⁸⁷Sr/⁸⁶Sr analyses together with the geological evidence confirm an evaporitic origin for the celestite beds.